Dielectric materials using 2D nanosheet network interlayer

Patent metadata

Field	Value
Publication number	US-10049817-B2
Application number	US-201615186755-A
Country	US
Kind code	B2
Filing date	Jun 20, 2016
Priority date	Jun 19, 2015
Publication date	Aug 14, 2018
Grant date	Aug 14, 2018

Abstract

The present disclosure provides advantageous composite films/coatings, and improved methods for fabricating such composite films/coatings. More particularly, the present disclosure provides improved methods for fabricating composite films by trapping at least a portion of a layered material (e.g., hexagonal boron nitride sheets/layers) at an interface of a phase separated system and then introducing the layered material to a polymer film. The present disclosure provides for the use of boron nitride layers to increase the properties (e.g., dielectric constant and breakdown voltage) of polymer films. The exemplary films can be produced by an advantageous climbing technique. Exemplary boron nitride films are composed of overlapping boron nitride sheets with a total thickness of about one nanometer, with the film then transferred onto a polymer film, thereby resulting in significant increases in both dielectric and breakdown properties of the polymer film.

First claim

The invention claimed is:

1. A method for fabricating a composite film comprising:
a) providing a phase separated system, the phase separated system including: (i) a first material and a second material, and (ii) an interface between the first and second materials;
b) introducing a layered material to the phase separated system;
c) inserting a substrate into the interface of the phase separated system and allowing at least a portion of the layered material to be associated with the substrate;
d) removing the substrate from the phase separated system and allowing the portion of the layered material associated with the substrate to dry; and
e) introducing a polymer to the layered material to form a composite film.

2. The method of claim 1 , wherein the layered material includes boron nitride.

3. The method of claim 2 , wherein the layered material is hexagonal boron nitride.

4. The method of claim 1 , wherein the layered material of the composite film includes individual sheets or layers of boron nitride.

5. The method of claim 1 , wherein the layered material of the composite film has a total thickness of about one nanometer.

6. The method of claim 1 , wherein the layered material of the composite film includes overlapping boron nitride sheets or layers.

7. The method of claim 1 , wherein the layered material of the composite film includes from about one sheet or layer to about nine sheets or layers of boron nitride, and wherein there are gaps in the composite film with no layered material.

8. The method of claim 1 , wherein after step e), the layered material is an interlayer of the composite film.

9. The method of claim 1 , wherein step e) includes embedding the layered material into the polymer to form the composite film.

10. The method of claim 1 , further comprising, after step e), the step of removing the composite film from the substrate.

11. The method of claim 1 , wherein the step of introducing the polymer to the layered material includes drop casting a polymer solution onto the dried layered material; and
further comprising, after step e), the steps of allowing the polymer solution to dry, and removing the dried composite film from the substrate.

12. The method of claim 1 , wherein step e) includes coating the polymer onto the layered material to form the composite film.

13. The method of claim 1 , wherein the formed composite film has a low frequency dielectric constant around 5, and an energy storage capacity around 4.9 J/cm 3 .

14. The method of claim 1 , wherein the polymer includes poly(methyl-methacrylate) or polypropylene.

15. The method of claim 1 , wherein the phase separated system is an oil and water based system.

16. The method of claim 1 , wherein the phase separated system is a system of two substantially non-mixing solvents.

17. The method of claim 1 , wherein the first material is water and the second material is heptane.

18. The method of claim 1 , wherein the step of introducing the polymer to the layered material includes hot pressing a polymer film to the dried layered material.

19. A method for fabricating a composite film comprising:
a) providing a phase separated system, the phase separated system including: (i) a first material and a second material, and (ii) an interface between the first and second materials;
b) introducing boron nitride to the phase separated system;
c) inserting a substrate into the interface of the phase separated system and allowing at least a portion of the boron nitride to be associated with the substrate; and
d) removing the substrate from the phase separated system and allowing the portion of the boron nitride associated with the substrate to dry; and
e) introducing a polymer to the dried boron nitride to form a composite film;
wherein boron nitride of the composite film includes individual sheets or layers of boron nitride;
wherein the boron nitride of the composite film has a total thickness of about one nanometer;
wherein the boron nitride of the composite film includes overlapping boron nitride sheets or layers; and
wherein after step e), the boron nitride is an interlayer of the composite film.

Assignees

• Univ Connecticut

Inventors

• Adamson Douglas H
• Cui Zhenhua
• Dobrynin Andrey V

Classifications

• C30B29/403

  AIII-nitrides · CPC title

• H01G4/14 Primary

  Organic dielectrics · CPC title

• C30B29/64

  Flat crystals, e.g. plates, strips or discs · CPC title

• H01G4/06

  Solid dielectrics · CPC title

• H01G4/206

  inorganic and synthetic material · CPC title