Method of refining of scandium oxide from concentrates using solvent extraction

Patent metadata

Field	Value
Publication number	US-10047414-B2
Application number	US-201615041332-A
Country	US
Kind code	B2
Filing date	Feb 11, 2016
Priority date	Feb 11, 2016
Publication date	Aug 14, 2018
Grant date	Aug 14, 2018

Abstract

A method of selectively removing impurities from a scandium-containing feed solution includes contacting an aqueous scandium-containing solution with an organic solvent stream containing an extractant, thereby forming a loaded organic solvent stream containing the impurity or impurities while leaving the scandium in the raffinate. The aqueous stream containing the scandium is washed, diluted and has inorganic salts added before being contacted with a second organic solvent stream to extract the scandium selectively, and followed by stripping the scandium from the scandium-containing loaded organic extractant stream by adding oxalic acid to the loaded organic extractant stream to form scandium oxalate.

First claim

The invention claimed is:

1. A method of selectively removing scandium from a scandium-containing feed solution, comprising:
selectively removing zirconium from the aqueous scandium-containing solution by contacting an aqueous scandium-containing solution with a first organic solvent stream comprising a first extractant;
providing MgSO 4 and adding the MgSO 4 to the aqueous scandium-containing solution after contacting the aqueous scandium-containing solution with the first organic solvent stream;
contacting the aqueous scandium-containing solution with a second organic solvent stream comprising a second extractant after adding the MgSO 4 , thereby forming a scandium-containing loaded organic solvent stream having at least a portion of the scandium from the scandium-containing solution; and
stripping the scandium from the scandium-containing loaded organic extractant stream by adding oxalic acid to the loaded organic extractant stream to form scandium oxalate and a stripped organic extractant stream.

2. The method of claim 1 , wherein the second extractant comprises an organophosphorus compound.

3. The method of claim 1 , wherein the second organic solvent stream further comprises a modifier and a diluent.

4. The method of claim 1 , further comprising calcining the scandium oxalate to form Sc 2 O 3 .

5. The method of claim 1 , further comprising scrubbing the stripped organic extractant stream after stripping the scandium to remove titanium from the stripped organic extractant stream.

6. The method of claim 1 , wherein the first extractant comprises an amine compound, and wherein the step of selectively removing zirconium occurs prior to contacting the aqueous scandium-containing solution with the second organic solvent stream.

7. The method of claim 6 , further comprising stripping the zirconium from the first organic solvent with an aqueous chloride solution.

8. The method of claim 7 , wherein the aqueous chloride solution comprises an aqueous HCl solution.

9. The method of claim 5 , wherein scrubbing the stripped organic extractant stream to remove titanium from the stripped organic extractant stream comprises using sulfuric acid and hydrogen peroxide to remove the titanium.

10. The method of claim 1 , wherein the second extractant comprises a dialkyl phosphinic acid extractant.

11. The method of claim 1 , wherein the second extractant comprises bis(2,4,4-trimethylpentyl) phosphinic acid.

Assignees

• Bloom Energy Corp

Inventors

• Liao Lunzhi
• Hartley Christopher Jeffrey
• Mcallister Justin
• Sarmiento Andrew

Classifications

• C07C51/412

  by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part · CPC title

• C07C55/07

  Salts thereof · CPC title

• C22B59/00 Primary

  Obtaining rare earth metals · CPC title

• C22B34/14

  Obtaining zirconium or hafnium {(treatment or purification of solutions by liquid-liquid extraction, by ion exchange or by adsorption C22B3/00, C01G25/003, C01G27/003)} · CPC title

• C22B3/44

  by chemical processes (treatment or purification of solutions by liquid-liquid extraction C22B3/26, by ion-exchange extraction C22B3/42) · CPC title