Partially degradable particulates as time-released tracers for acidized and fractured gas wells
US-2024209729-A1 · Jun 27, 2024 · US
US10047281B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10047281-B2 |
| Application number | US-201515555950-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 6, 2015 |
| Priority date | Apr 6, 2015 |
| Publication date | Aug 14, 2018 |
| Grant date | Aug 14, 2018 |
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Methods including pumping a fracturing fluid into a subterranean formation through an annulus between the subterranean formation and a pipe conveyance at a rate above a fracture gradient of the subterranean formation to create and/or open at least one fracture in the subterranean formation; continuously pumping a proppant-free fluid into the subterranean formation through the annulus at a first rate to extend the open fracture; continuously pumping a proppant fluid through an interior of the pipe conveyance and out the exit of the interior of the pipe conveyance at a second rate that is less than the first rate; and placing the proppant particulates into a portion of a fracture in the subterranean formation so as to form a proppant pack having proppant-free channels therein.
Opening claim text (preview).
The invention claimed is: 1. A method comprising: providing a fracturing fluid comprising a first base fluid and a first gelling agent; providing a proppant-free fluid comprising a second base fluid and a second gelling agent; providing a proppant fluid comprising a third base fluid, a third gelling agent, and proppant particulates, wherein the proppant-free fluid and the proppant fluid are substantially immiscible; pumping the fracturing fluid through an annulus formed between a subterranean formation and a pipe conveyance extending into the subterranean formation at a rate above a fracture gradient of the subterranean formation to create and/or open at least one fracture in the subterranean formation; continuously pumping the proppant-free fluid into the subterranean formation through the annulus at a first rate to extend the open fracture; continuously pumping the proppant fluid through an interior of the pipe conveyance and out an exit of the interior of the pipe conveyance at a second rate that is less than the first rate, wherein the proppant fluid and the proppant-free fluid are present simultaneously in a portion of the subterranean formation but remain substantially immiscible; and upon exiting the pipe conveyance, shearing off the proppant fluid by the proppant-free fluid thereby placing the proppant particulates into a portion of a fracture in the subterranean formation so as to form a proppant pack having proppant-free channels therein. 2. The method of claim 1 , wherein the first rate is above the fracture gradient pressure of the subterranean formation. 3. The method of claim 1 , wherein the fracturing fluid further comprises proppant particulates having a size selected from the group consisting of micro-sized, nano-sized, and any combination thereof. 4. The method of claim 1 , wherein the continuous pumping of the proppant-free fluid and the continuous pumping of the proppant fluid is ceased after the proppant pack having proppant-free channels is formed in the fracture, or if an increase in treating pressure is observed above a threshold treating pressure. 5. The method of claim 1 , wherein the proppant-free fluid is hydrophilic and the proppant fluid is hydrophobic, thereby causing the proppant-free fluid and the proppant fluid to be substantially immiscible, or wherein the proppant-free fluid is hydrophobic and the proppant fluid is hydrophilic, thereby causing the proppant-free fluid and the proppant fluid to be substantially immiscible. 6. The method of claim 1 , wherein a viscosity of the proppant-free fluid is at least about 50% greater than a viscosity of the proppant fluid, thereby causing the proppant-free fluid and the proppant fluid to be substantially immiscible. 7. The method of claim 1 , wherein the proppant-free fluid is a linear fluid and the proppant fluid is a macromolecularly structured fluid, thereby causing the proppant-free fluid and the proppant fluid to be substantially immiscible, or wherein the proppant-free fluid is a macromolecularly structured fluid and the proppant fluid is a linear fluid, thereby causing the proppant-free fluid and the proppant fluid to be substantially immiscible. 8. The method of claim 1 , wherein the proppant-free fluid is a linear fluid and the proppant fluid is a foamed fluid, thereby causing the proppant-free fluid and the proppant fluid to be substantially immiscible, or wherein the proppant-free fluid is a foamed fluid and the proppant fluid is a linear fluid, thereby causing the proppant-free fluid and the proppant fluid to be substantially immiscible. 9. The method of claim 1 , wherein the proppant particulates comprise proppant particulates with at least a portion thereof coated with a stabilization agent selected from the group consisting of a non-aqueous tackifying agent, an aqueous tackifying agent, a silyl-modified polyamide compound, a curable resin, a crosslinkable aqueous polymer composition, a polymerizable organic monomer composition, a zeta potential-modifying aggregating composition, a silicon-based resin, a binder, a stabilization agent emulsion, and any combination thereof. 10. A method comprising: providing a fracturing fluid comprising a first base fluid and a first gelling agent; providing a proppant-free fluid comprising a second base fluid, a second gelling agent, and a breaker; providing a proppant fluid comprising a third base fluid, a third gelling agent, and proppant particulates, wherein the proppant-free fluid and the proppant fluid are substantially immiscible; pumping the fracturing fluid through an annulus formed between a subterranean formation and a pipe conveyance extending into the subterranean formation at a rate above the fracture gradient to create and/or open at least one fracture in the subterranean formation; continuously pumping the proppant-free fluid into the subterranean formation through the annulus at a first rate to extend the open fracture; continuously pumping the proppant fluid through an interior of the pipe conveyance and out an exit of the interior of the pipe conveyance at a second rate that is less than the first rate, wherein the proppant fluid and the proppant-free fluid are present simultaneously in a portion of the subterranean formation but remain substantially immiscible; upon exiting the pipe conveyance, shearing off the proppant fluid by the proppant-free fluid thereby placing the proppant particulates into a portion of a fracture in the subterranean formation so as to form a proppant pack having proppant-free channels therein; activating the breaker in the proppant-free fluid; and removing at least a portion of the proppant-free fluid from the subterranean formation. 11. The method of claim 10 , wherein the first rate is above the fracture gradient pressure of the subterranean formation. 12. The method of claim 10 , wherein the fracturing fluid further comprises proppant particulates having a size selected from the group consisting of micro-sized, nano-sized, and any combination thereof. 13. The method of claim 10 , wherein the continuous pumping of the proppant-free fluid and the continuous pumping of the proppant fluid is ceased after the proppant pack having proppant-free channels is formed in the fracture, or if an increase in treating pressure is observed. 14. The method of claim 10 , wherein the proppant particulates comprise proppant particulates with at least a portion thereof coated with a stabilization agent selected from the group consisting of a non-aqueous tackifying agent, an aqueous tackifying agent, a silyl-modified polyamide compound, a curable resin, a crosslinkable aqueous polymer composition, a polymerizable organic monomer composition, a zeta potential-modifying aggregating composition, a silicon-based resin, a binder, a stabilization agent emulsion, and any combination thereof. 15. The method of claim 10 , wherein the breaker is encapsulated in an encapsulating material. 16. The method of claim 10 , wherein the proppant-free fluid is a linear fluid and the proppant fluid is a macromolecularly structured fluid, thereby causing the proppant-free fluid and the proppant fluid to be substantially immiscible, or wherein the proppant-free fluid is a macromolecularly structured fluid and the proppant fluid is a linear fluid, thereby causing the proppant-free fluid and the proppant fluid to be substantially immiscible. 17. The method of claim 10 , wherein the proppant-free fluid is a linear fluid and the proppant fluid is a foamed fluid, thereby causing the proppant-free fluid and the proppant fluid to
Compositions based on water or polar solvents (C09K8/64 takes precedence) · CPC title
Foams · CPC title
in association with fracturing processes {or crevice forming processes} · CPC title
Oil-based compositions · CPC title
Compositions for reinforcing fractures, e.g. compositions of proppants used to keep the fractures open · CPC title
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