Invertible water-in-oil latices and methods of use
US-9822297-B2 · Nov 21, 2017 · US
US10047274B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10047274-B2 |
| Application number | US-201615152852-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 12, 2016 |
| Priority date | May 13, 2015 |
| Publication date | Aug 14, 2018 |
| Grant date | Aug 14, 2018 |
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Disclosed herein are inversion systems and methods of diluting w/o lattices including about 10 wt % to 80 wt % of a water soluble polymer. Using the inversion systems and methods described herein, dilution of w/o lattices is carried out in a single step to form dilute lattices having 10,000 ppm or less polymer; the dilute lattices form polymer solutions with no further addition of mixing force or water. The solution viscosities of the polymer solutions obtained using the systems and methods of the invention are at least about 80% of solution viscosity expected in the absence of shear.
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The invention claimed is: 1. A method of inverting a water-in-oil latex, the method comprising a. providing a single inversion device comprising at least one inlet and an outlet, the device designed and adapted to provide a pressure drop of about 2 psi to 150 psi between at least an inlet and the outlet; b. applying a water-in-oil latex source to an inlet of the inversion device, the latex comprising about 10 wt % to 80 wt % of a water soluble polymer having a weight average molecular weight of about 1,000,000 to 100,000,000 g/mole; c. applying a water source to an inlet of the inversion device; d. combining the latex with the water source within the inversion device to form a dilute polymer latex comprising about 10,000 ppm or less of the water soluble polymer; and e. dispensing the dilute polymer latex from the inversion device, wherein the dispensed dilute polymer latex forms a polymer solution having a viscosity of about 80% to 100% of an expected viscosity of the polymer solution in the absence of shear. 2. The method of claim 1 wherein the inversion device is a static mixer. 3. The method of claim 1 wherein the inversion device is a mixing pump. 4. The method of claim 1 wherein the latex source and the water source are applied to different inlets. 5. The method of claim 1 wherein the inversion device is characterized by the absence of mixing elements. 6. The method of claim 5 wherein the inversion device comprises a first conduit having one or more inlets and outlets; a second conduit having one or more inlets and outlets, wherein said first conduit secures to said second conduit and traverses said second conduit; a chamber that has one or more inlets and outlets, wherein said second conduit secures to said chamber and wherein said first conduit outlets and said second conduit outlets are in fluid communication with said chamber inlets, wherein the device is adapted to provide a pressure drop of about 2 psi to 150 psi between the second conduit inlets and the chamber outlets of the device. 7. The method of claim 6 wherein the latex and water are combined in the chamber of the inversion device. 8. The method of claim 1 wherein the latex comprises about 2 wt % to 5 wt % of a surfactant having an HLB of about 14 or greater. 9. The method of claim 1 wherein about 0.1 second to 180 minutes after the combining, the polymer solution has a Filter Ratio of about 1.5 or less. 10. The method of claim 1 wherein the water source is a high temperature water source, a high total dissolved solids water source, or a high temperature/high total dissolved solids water source. 11. An inversion system comprising: a. a single inversion device, the inversion device comprising at least one inlet and an outlet, the device designed and adapted to provide a pressure drop of about 2 psi to 150 psi between at least one inlet and the outlet; b. a water-in-oil latex source fluidly connected to an inlet, the latex comprising about 10 wt % to 80 wt % of a water soluble polymer having a weight average molecular weight of about 1,000,000 to 100,000,000 g/mole; c. a water source fluidly connected to an inlet, the water source being a high temperature water source, a high total dissolved solids water source, or a high temperature/high total dissolved solids water source; and d. a polymer solution in fluid communication with the outlet, the polymer solution comprising about 10,000 ppm or less of the polymer and having a viscosity about 80% to 100% of an expected viscosity of the polymer solution in the absence of shear and characterized by a filter ratio of about 1.5 or less. 12. The inversion system of claim 11 , wherein the inversion device is a static mixer. 13. The inversion system of claim 11 , wherein the inversion device is a mixing pump. 14. The inversion system of claim 11 , wherein the inversion device is characterized by the absence of mixing elements. 15. The inversion system of claim 14 wherein the inversion device comprises a first conduit having one or more inlets and outlets; a second conduit having one or more inlets and outlets, wherein said first conduit secures to said second conduit and traverses said second conduit; a chamber that has one or more inlets and outlets, wherein said second conduit secures to said chamber and wherein said first conduit outlets and said second conduit outlets are in fluid communication with said chamber inlets, wherein the device is adapted to provide a pressure drop of about 2 psi to 150 psi between the second conduit inlets and the chamber outlets of the device. 16. The inversion system of claim 14 further comprising one or more static mixers, one or more pumps, or both disposed in fluid communication with and downstream from the inversion device. 17. The inversion system of claim 11 wherein the inversion device is arranged in-line with or on a bypass of a flow of the water source toward a subterranean reservoir.
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