Cross-linkable materials based on organyl-oxysilane-terminated polymers

Patent metadata

Field	Value
Publication number	US-10047260-B2
Application number	US-201515304335-A
Country	US
Kind code	B2
Filing date	Apr 10, 2015
Priority date	Apr 17, 2014
Publication date	Aug 14, 2018
Grant date	Aug 14, 2018

Abstract

A composition containing an alkoxysilyl-functional polymer, a phenylsilicone resin, and a non-reactive plasticizer, when cured, exhibits very high elongation without loss of tensile strength. The compositions are particularly well suited for flexible adhesives.

First claim

The invention claimed is:

1. A crosslinkable composition, comprising:
(A) 100 parts by weight of one or more compounds of the formula
Y—[(CR 1 2 ) b —SiR a (OR 2 ) 3-a ] x   (I),

where
Y is an x-valent polymer radical bonded via nitrogen, oxygen, sulfur or carbon,
R are identical or different monovalent, optionally substituted hydrocarbon radicals,
R 1 are identical or different, and are hydrogen or monovalent, optionally substituted hydrocarbon radicals which are optionally attached to the carbon atom via nitrogen, phosphorus, oxygen, sulfur or carbonyl group,
R 2 are identical or different and are hydrogen or monovalent, optionally substituted hydrocarbon radicals,
x is an integer from 1 to 10,
a is 0, 1 or 2, and
b is an integer from 1 to 10,
(B) from 5 to 50 parts by weight of at least one silicone resin comprising units of the formula
R 3 c (R 4 O) d R 5 e SiO (4-c-d-e)/2   (II),

where
R 3 are identical or different and are hydrogen, monovalent, SiC-bonded, optionally substituted aliphatic hydrocarbon radicals, or divalent, optionally substituted, aliphatic hydrocarbon radicals which bridge two units of the formula (II),
R 4 are identical or different and are hydrogen or monovalent, optionally substituted hydrocarbon radicals,
R 5 are identical or different and are monovalent, SiC-bonded, optionally substituted aromatic hydrocarbon radicals,
c is 0, 1, 2 or 3,
d is 0, 1, 2 or 3, and
e is 0, 1 or 2,
with the proviso that the sum of c+d+e is less than or equal to 3 and in at least 40% of the units of formula (II) the sum c+e is equal to 0 or 1,
where component (B) comprises a component (B1) which contains less than 0.1 wt % of aromatic solvents (BL), and
(C) at least 26 parts by weight of one or more nonreactive plasticizers, the nonreactive plasticizers (C) being organic compounds which, at temperatures <80° C., react neither with water nor with components (A) and (B), which are liquid at 20° C. and 1013 hPa, which have a boiling point >250° C. at 1013 hPa, and are fully esterified aromatic or aliphatic carboxylic acids, fully esterified derivatives of phosphoric acid, fully esterified derivatives of sulfonic acids, branched or unbranched saturated hydrocarbons, polystyrenes, polybutadienes, polyisobutylenes, polyesters, and polyethers.

2. The crosslinkable composition of claim 1 , wherein radical Y comprises a polyurethane radical or polyoxyalkylene radical.

3. The crosslinkable composition of claim 1 , wherein component (B) comprises silicone resins (B1) which have, based in each case on the total number of units of the formula (II), at least 20% of units of the formula (II) in which the value of e is 1.

4. The crosslinkable composition of claim 1 , wherein component (C) comprises plasticizers which are free of phthalic esters.

5. The crosslinkable composition of claim 1 , wherein plasticizer (C) comprises at least one polyether.

6. The crosslinkable composition of claim 1 , wherein component (C) is present in amounts of 30 to 300 parts by weight, based on 100 parts by weight of component (A).

7. The crosslinkable composition of claim 1 , wherein the composition comprises:
(A) 100 parts by weight of one or more compounds of the formula (I),
(B) 10-50 parts by weight of at least one silicone resin comprising units of the formula (II),
(C) 30-150 parts by weight of non-reactive plasticizers,
(D) 0.1-25 parts by weight of organosilicon compounds comprising units of the formula
D h Si(OR 7 ) g R 6 f O (4-f-g-h)/2   (III),

in which
R 6 are identical or different and are a monovalent, optionally substituted, SiC-bonded, nitrogen-free organic radicals,
R 7 are identical or different and are hydrogen atom or optionally substituted hydrocarbon radicals,
D are identical or different and are a monovalent, SiC-bonded radicals having at least one nitrogen atom not bonded to a carbonyl group (C═O),
f is 0, 1, 2 or 3,
g is 0, 1, 2 or 3, and
h is 0, 1, 2, 3 or 4,
with the proviso that the sum of f+g+h is less than or equal to 4 and there is at least one radical D per molecule,
(E) 40 to 1000 parts by weight of fillers,

optionally
(F) catalysts,

optionally
(G) adhesion promoters,

optionally
(H) water scavengers,

optionally
(I) additives, and

optionally
(J) adjuvants.

8. A process for preparing the composition of claim 1 , comprising mixing the individual components in any order.

9. A shaped article produced by crosslinking a composition of claim 1 .

10. A method for producing a composite material, comprising applying a composition of claim 1 to at least one substrate and subsequently crosslinking the composition.

Assignees

• Wacker Chemie Ag

Inventors

• Stanjek Volker
• Zander Lars

Classifications

• B29C65/48

  using adhesives {, i.e. using supplementary joining material; solvent bonding} · CPC title

• C08K3/26

  Carbonates; Bicarbonates · CPC title

• C08K2003/265

  Calcium, strontium or barium carbonate · CPC title

• C08K9/04

  Ingredients treated with organic substances {(treated with macromolecular compounds C08K9/08)} · CPC title

• C09J183/14 Primary

  in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms (C09J183/10 takes precedence) · CPC title