Ethylene-vinyl alcohol copolymer-containing resin composition, film, laminate, packaging material, vacuum thermal insulator, film production method, and laminate production method

Patent metadata

Field	Value
Publication number	US-10047204-B2
Application number	US-201414894459-A
Country	US
Kind code	B2
Filing date	May 28, 2014
Priority date	May 29, 2013
Publication date	Aug 14, 2018
Grant date	Aug 14, 2018

Abstract

Provided is a resin composition that achieves superior appearance characteristics such as a color of a film end (or a roll end) after melt molding, film-breaking resistance, blocking resistance, vapor deposition defects-inhibiting properties, and adhesive strength of a vapor deposition layer. The resin composition contains: an ethylene-vinyl alcohol copolymer; inorganic particles; and an aliphatic carbonyl compound having 3 to 8 carbon atoms, in which the content of the inorganic particles is 50 ppm or greater and 5,000 ppm or less, the aliphatic carbonyl compound is at least one selected from the group consisting of a saturated aldehyde, an unsaturated aldehyde and a saturated ketone, and the content of the aliphatic carbonyl compound is 0.01 ppm or greater and 100 ppm or less. The inorganic particles preferably contain a metal element which is at least one selected from the group consisting of silicon, aluminum, magnesium, zirconium, cerium, tungsten and molybdenum.

First claim

The invention claimed is:

1. A resin composition, comprising:
an ethylene-vinyl alcohol copolymer (A);
inorganic particles (B); and
an aliphatic carbonyl compound (C) having 3 to 8 carbon atoms,
wherein
a content of the inorganic particles (B) is 50 ppm or greater and 5,000 ppm or less,
the aliphatic carbonyl compound (C) is a saturated ketone,
the saturated ketone is at least one selected from the group consisting of acetone, methyl ethyl ketone and 2-hexanone, and
a content of the aliphatic carbonyl compound (C) is 0.01 ppm or greater and 100 ppm or less.

2. The resin composition according to claim 1 , wherein the inorganic particles (B) comprise a metal element which is at least one selected from the group consisting of silicon, aluminum, magnesium, zirconium cerium, tungsten and molybdenum.

3. The resin composition according to claim 1 , wherein the aliphatic carbonyl compound (C) is at least one selected from the group consisting of acetone and methyl ethyl ketone.

4. A film formed from the resin composition according to claim 1 .

5. A laminate, comprising:
a layer comprising the film according to claim 4 ; and
at least one other layer comprising other component.

6. The laminate according to claim 5 , wherein the other layer is a metal vapor deposition layer.

7. The laminate according to claim 6 , wherein the laminate comprises two or more metal vapor deposition layers as the other layer on one side or both sides of the film.

8. The laminate according to claim 6 , wherein a sum of the average thickness of the metal vapor deposition layer(s) on one side of the film is 15 nm or greater and 150 nm or less.

9. A packaging material, comprising the film according to claim 4 .

10. A packaging material, comprising the laminate according to claim 5 .

11. A vacuum thermal insulator, comprising the laminate according to claim 6 .

12. A method for producing the film according to claim 4 , the method comprising:
cast-molding the resin composition.

13. A method for producing the film according to claim 4 , the method comprising:
stretching the film formed from the resin composition.

14. A method for producing the laminate according to claim 6 , the method comprising:
forming the metal vapor deposition layer on the film,
wherein a surface temperature of the film in forming the metal vapor deposition layer is 60° C. or less.

Assignees

• Kuraray Co

Inventors

• Kawai Hiroshi
• Nonaka Yasuhiro

Classifications

• C08J5/18 Primary

  Manufacture of films or sheets · CPC title

• C08K3/01

  characterized by their specific function · CPC title

• C08K3/36

  Silica · CPC title

• C08K5/07

  Aldehydes; Ketones · CPC title

• C08J7/06

  with compositions not containing macromolecular substances · CPC title