Aqueous dispersion of low molecular weight polytetrafluoroethylene, low molecular weight polytetrafluoroethylene powder, and method for producing low molecular weight polytetrafluoroethylene

Patent metadata

Field	Value
Publication number	US-10047175-B2
Application number	US-201514645775-A
Country	US
Kind code	B2
Filing date	Mar 12, 2015
Priority date	Aug 7, 2007
Publication date	Aug 14, 2018
Grant date	Aug 14, 2018

Abstract

The present invention provides an aqueous dispersion of a low-molecular-weight polytetrafluoroethylene (PTFE), which contains an easily removable surfactant, and has a good dispersion stability. Specifically, the present invention provides an aqueous dispersion of a low-molecular-weight PTFE comprising tetrafluoroethylene (TFE) units, or TFE units and modifying monomer units which are copolymerizable with the TFE units, wherein the aqueous dispersion contains from 70 to 9,000 ppm, based on the aqueous dispersion, of a fluorine-containing compound of the formula (1) below:

X—(CF 2 ) m —Y  (1)

where X is H or F; m is an integer from 3 to 5; and Y is —SO 3 M, —SO 4 M, —SO 3 R, —SO 4 R, —COOM, —PO 3 M 2 or —PO 4 M 2 , M being H, NH 4 or an alkali metal, and R being an alkyl group having 1 to 12 carbons, and the low-molecular-weight PTFE has an average primary particle size of from 100 to 350 nm.

First claim

The invention claimed is:

1. A method of producing a low-molecular-weight polytetrafluoroethylene, comprising: emulsion-polymerizing, in an aqueous medium, tetrafluoroethylene, or tetrafluoroethylene and a modifying monomer copolymerizable with the tetrafluoroethylene in the presence of a chain transfer agent,
wherein the emulsion polymerization is carried out in the presence of a fluorine-containing compound of the formula (1) below:
X—(CF 2 ) m —Y  (1)

where X is H or F; m is an integer from 3 to 5; and Y is —SO 3 M, —SO 4 M, —SO 3 R, —SO 4 R, —COOM, —PO 3 M 2 or —PO 4 M 2 , M being H, NH 4 or an alkali metal, and R being an alkyl group having 1 to 12 carbons,
wherein the emulsion polymerization is further carried out in the presence of a reactive compound which has a functional group capable of reacting in radical polymerization and a hydrophilic group, and
wherein the reactive compound is used in an amount which corresponds to from 100 ppb to 20 ppm of the aqueous medium.

2. The method of producing a low-molecular-weight polytetrafluoroethylene according to claim 1 , wherein the reactive compound has an unsaturated bond.

3. The method of producing a low-molecular-weight polytetrafluoroethylene according to claim 1 ,
wherein the reactive compound is a perfluorovinylalkyl compound of the formula (1a) below:
CF 2 ═CF—(CF 2 ) n1 —Y 1   (1a)

where n 1 is an integer from 1 to 10; and Y 1 is —SO 3 M 1 or —COOM 1 , M 1 being H, NH 4 or an alkali metal),
a perfluorovinylalkyl compound of the formula (1b) below:
CF 2 ═CF—(CF 2 C(CF 3 )F) n2 —Y 1   (1b)

where n 2 is an integer from 1 to 5; and Y 1 is as defined above,
a perfluorovinyl ether compound of the formula (1c) below:
CF 2 ═CF—O—(CFX 1 ) n3 —Y 1   (1c)

where X 1 is F or CF 3 ; n 3 is an integer from 1 to 10; and Y 1 is as defined above,
a perfluorovinyl ether compound of the formula (1d) below:
CF 2 ═CF—O—(CF 2 CFX 1 O) n4 —CF 2 CF 2 —Y 1   (1d)

where n 4 is an integer from 1 to 10; and Y 1 and X 1 are as defined above,
or a fluoroalkyl ether compound of the formula (1e) below:
CX 2 2 ═CFCF 2 —O—(CF(CF 3 )CF 2 O) n5 —CF(CF 3 )—Y 1   (1e)

where each X 2 is the same and represents F or H; n 5 is 0 or an integer from 1 to 10; and Y 1 is as defined above.

4. The method of producing a low-molecular-weight polytetrafluoroethylene according to claim 1 ,
wherein the reactive compound is used in an amount which corresponds to from 100 ppb to 10 ppm of the aqueous medium.

5. The method of producing a low-molecular-weight polytetrafluoroethylene according to claim 1 ,
wherein the fluorine-containing compound is used in an amount which corresponds to from 100 to 10,000 ppm of the aqueous medium.

6. The method of producing a low-molecular-weight polytetrafluoroethylene according to claim 1 ,
wherein the modifying monomer which is copolymerizable with tetrafluoroethylene is hexafluoropropylene, perfluoropropyl vinyl ether or vinylidene fluoride.

Assignees

• Daikin Ind Ltd

Inventors

• Yamanaka Taku
• Tsuda Nobuhiko
• Tsuji Masayuki
• Sawada Yasuhiko

Classifications

• C08F214/26

  Tetrafluoroethene · CPC title

• C08F6/16

  Purification · CPC title

• C08F14/26 Primary

  Tetrafluoroethene · CPC title

• G03G9/09766

  comprising fluorine · CPC title

• C08F6/20

  Concentration · CPC title