Process for producing alkylene oxide adduct and alkylene oxide adduct

Patent metadata

Field	Value
Publication number	US-10047029-B2
Application number	US-201415117683-A
Country	US
Kind code	B2
Filing date	Mar 10, 2014
Priority date	Mar 10, 2014
Publication date	Aug 14, 2018
Grant date	Aug 14, 2018

Abstract

A process for producing an alkylene oxide adduct can continuously produce the alkylene oxide adduct by using a microflow reactor having a tubular flow passage and a micromixer connected to a supply port of the microflow reactor. Liquid state alkylene oxide, alkylene catalyst and an organic compound having an active hydrogen atom(s) are reacted while passing therethrough under the conditions of a temperature of the flow passage of 70 to 200° C. and a pressure of the supply port of the flow passage of 1 to 10 MPa.

First claim

The invention claimed is:

1. A process for producing an alkylene oxide adduct, comprising:
using a microflow reactor having a tubular flow passage and a micromixer connected to a supply port of the microflow reactor, wherein an apparatus having a flow passage with an inner diameter of 0.15 to 2.5 mm and a length of at least 10 m is used as the microflow reactor, and an apparatus having two or more independent supply routes and a discharge route connected to a confluence part of the supply routes and having inner diameters of the supply routes and the discharge route of 0.07 to 0.2 mm is used as the micromixer,
supplying a liquid alkylene oxide reactant to a first supply route of the micromixer,
supplying an organic compound reactant having an active hydrogen atom(s) and an alkaline catalyst reactant in a liquid state to a second supply route into the micromixer, and
discharging a mixed material mixed in the micromixer from the discharge route of the micromixer into the flow passage of the microflow reactor via the supply port of the microflow reactor,
wherein the reactants are reacted while passing through the microflow reactor under conditions of a temperature of the flow passage of the microflow reactor of 70 to 200° C., a pressure at a supply port of the flow passage of 1 to 10 MPa, and with a retention time in the flow passage of at least 20 minutes, to produce an alkylene oxide adduct having a platinum-cobalt scale number of between 0 and 20 and a Mw/Mn ratio of no more than 1.1.

2. The production process of the alkylene oxide adduct according to claim 1 , wherein the alkylene oxide is ethylene oxide and/or propylene oxide.

3. The production process of the alkylene oxide adduct according to claim 2 , wherein the organic compound having an active hydrogen atom(s) is one or two or more selected from a monovalent aliphatic alcohol having 1 to 6 carbon atoms and a monoalkylamine having 1 to 6 carbon atoms.

4. The production process of the alkylene oxide adduct according to claim 1 , wherein the alkylene oxide reactant is ethylene oxide, the organic compound having an active hydrogen atom(s) reactant is methyl alcohol, and the alkaline catalyst reactant is sodium methoxide.

5. The production process of the alkylene oxide adduct according to claim 1 , wherein the conditions of the tubular flow passage of the microflow reactor are a temperature of 90 to 160° C. and a pressure at the supply port of 2 to 5 MPa, while passing through the flow passage for 20 to 60 minutes to obtain an alkylene oxide adduct.

Assignees

• Takemoto Oil & Fat Co Ltd

Inventors

• Furuta Akihiro
• Okada Kazuhisa

Classifications

• C08G65/2696

  characterised by the process or apparatus used · CPC title

• C08G65/2609

  containing aliphatic hydroxyl groups · CPC title

• C07C41/03 Primary

  by reaction of oxirane rings with hydroxy groups · CPC title

• C07C43/13

  containing hydroxy or O-metal groups (C07C43/11 takes precedence) · CPC title

• C07C213/04

  by reaction of ammonia or amines with olefin oxides or halohydrins · CPC title