Organic polymer thin membrane, and method for producing same

Patent metadata

Field	Value
Publication number	US-10046283-B2
Application number	US-201715599841-A
Country	US
Kind code	B2
Filing date	May 19, 2017
Priority date	Sep 7, 2012
Publication date	Aug 14, 2018
Grant date	Aug 14, 2018

Abstract

Provided is a technique for fabricating a novel thin membrane with a starting material such as a biocompatible compound that is not easily processible into a membrane, particularly a technique for fabricating a novel thin membrane of a composition that is gradually polymerized from a membrane surface into the membrane in the cross sectional direction of the membrane, and having, for example, different structures on the front and back of the membrane. The technique includes the steps of preparing a solution of a starting material compound; forming a thin membrane of the solution on a base material surface; and forming the organic polymer thin membrane through a polymerization reaction caused by irradiating the exposed surface of the thin membrane with a plasma or an electron beam.

First claim

The invention claimed is:

1. An organic polymer thin membrane consisting of an organic polymer soluble in water, ethanol, or a mixture of water and ethanol, of at least one compound selected from the group consisting of a compound having a hydrophilic functional group, a compound having a polyalkylene glycol chain, and a compound having a functional group selected from the group consisting of a hydroxyl group and a carboxyl group, and having a composition that is gradually polymerized from a thin membrane surface into the membrane in a cross sectional direction of the membrane.

2. The organic polymer thin membrane according to claim 1 , wherein the gradually polymerized composition reflects a polymerization reaction profile that occurs in a direction from an irradiated surface to a non-irradiated surface during formation of the organic polymer thin membrane in a polymerization reaction caused by irradiating a surface of a solution in which the organic polymer is dissolved with a plasma or an electron beam, and wherein the solution is coated on a base material surface.

3. The organic polymer thin membrane according to claim 2 , wherein the organic polymer thin membrane is a self-supporting membrane detached from the base material surface.

4. The organic polymer thin membrane according to claim 3 , wherein the self-supporting membrane has different structures on a front and a back of the self-supporting membrane, and is similar in structure to a cuticle of a living organism.

5. The organic polymer thin membrane according to claim 4 , wherein the self-supporting membrane has a surface having large numbers of polar groups and being easily wettable with water, and a surface having small numbers of polar groups and being less wettable with water.

6. The organic polymer thin membrane according to claim 1 , wherein the organic polymer thin membrane has different structures on a front and a back of the membrane.

Assignees

• Japan Science & Tech Agency

Inventors

• Hariyama Takahiko
• TAKAKU Yasuharu
• Suzuki Hiroshi
• Shimomura Masatsugu
• Ishii Daisuke
• Ohta Isao
• Muranaka Yoshinori

Classifications

• C09D4/00 Primary

  Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond {; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16} · CPC title

• B01D67/009

  with wave-energy, particle-radiation or plasma · CPC title

• C09D4/06

  {Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond} in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00 · CPC title

• B01D2325/36

  Hydrophilic membranes · CPC title

• B01D69/02

  characterised by their properties · CPC title