Negative electrode active material for lithium ion secondary battery, method for producing the same, negative electrode, and battery
US-2015325853-A1 · Nov 12, 2015 · US
US10044033B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10044033-B2 |
| Application number | US-201715459088-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 15, 2017 |
| Priority date | Mar 30, 2013 |
| Publication date | Aug 7, 2018 |
| Grant date | Aug 7, 2018 |
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A negative electrode active material for a lithium ion secondary battery, comprising silicon, copper and oxygen as major constitutional elements, the negative electrode active material for a lithium ion secondary battery, containing fine particles of silicon having an average crystallite diameter (Dx) measured by an X-ray diffractometry of 50 nm or less, and having elemental ratios, expressed by molar ratios, Cu/(Si+Cu+O) and O/(Si+Cu+O) of from 0.02 to 0.30, wherein the negative electrode active material contains an intermetallic compound of silicon and copper.
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The invention claimed is: 1. A negative electrode active material for a lithium ion secondary battery, comprising silicon, copper and oxygen as major constitutional elements, the negative electrode active material for the lithium ion secondary battery, containing fine particles of silicon having an average crystallite diameter (D x ) measured by an X-ray diffractometry using a half value width of the (111) plane of the silicon phase of 50 nm or less, and having average elemental ratios measured by an energy dispersive X-ray analysis in a measurement field of 200 μm×200 μm, expressed by molar ratios, Cu/(Si+Cu+O) of from 0.02 to 0.30 and O/(Si+Cu+O) of from 0.02 to 0.30, wherein the negative electrode active material contains an intermetallic compound of silicon and copper. 2. The negative electrode active material for a lithium ion secondary battery according to claim 1 , wherein the negative electrode active material contains an amorphous silicon oxide. 3. The negative electrode active material for a lithium ion secondary battery according to claim 1 , wherein the intermetallic compound of silicon and copper is Cu 3 Si. 4. The negative electrode active material for a lithium ion secondary battery according to claim 3 , wherein a peak intensity ratio of the negative electrode active material (Cu 3 Si/Si) calculated from a result of an X-ray diffractometry measurement is from 0.05 to 1.5.
Silicon · CPC title
Copper · CPC title
Alkali metal silicates ({C01B33/24} , C01B33/26 take precedence) · CPC title
of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title
Electric properties · CPC title
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