Fischer-Tropsch derived fuel compositions

Patent metadata

Field	Value
Publication number	US-10041013-B2
Application number	US-201314653389-A
Country	US
Kind code	B2
Filing date	Dec 19, 2013
Priority date	Dec 20, 2012
Publication date	Aug 7, 2018
Grant date	Aug 7, 2018

Abstract

A fuel composition comprising a Fischer-Tropsch derived middle distillate fuel and a middle distillate flow improver, the remainder being another fuel component or mixture of fuel components. The other fuel component is selected from petroleum derived middle distillate fuel, hydrogenated vegetable oil, fatty acid methyl esters, and other Fischer Tropsch products. The Fischer-Tropsch derived middle distillate fuel is more than 80% v/v of the total composition; the maximum weight content in the carbon number distribution of the n-paraffins in the Fischer-Tropsch derived middle distillate fuel is below C16 and the weight ratio of iso to normal paraffins in the Fischer-Tropsch derived middle distillate fuel is 3.5:1 or higher. The middle distillate flow improver is a substituted ethylene polymer.

First claim

That which is claimed is:

1. A fuel composition comprising a Fischer-Tropsch derived middle distillate fuel and a middle distillate flow improver, the remainder of the composition being another fuel component or mixture of fuel components, the other fuel component being selected from a petroleum derived middle distillate fuel, hydrogenated vegetable oil, fatty acid methyl esters, and other Fischer Tropsch products such as light F-T base oil;
wherein
the amount of the Fischer-Tropsch derived middle distillate fuel is at least 90% v/v of the total composition;
the maximum weight content in the carbon number distribution of the n-paraffins in the Fischer-Tropsch derived middle distillate fuel is below C16 and the weight ratio of iso to normal paraffins in the Fischer-Tropsch derived middle distillate fuel is 3.5:1 or higher; and wherein the middle distillate flow improver is a substituted ethylene polymer, being a single long alkyl chain substituted with acetate ester groups and 2-ethylhexanoate ester groups and further carrying some methyl branches, wherein the average ratio of acetate to 2-ethylhexanoate is 1:8, the mole percentage of acetate is 2% and 2-ethylhexanoate 16%, and the average number of methyl branches per 100 methylene groups is 4.9, and wherein the middle distillate flow improver is present in the composition at a treat rate of 500-4000 mg/kg, and wherein the CFPP of the fuel composition is below −25° C.

2. The fuel composition of any claim 1 , wherein the Fischer-Tropsch derived middle distillate fuel consists of at least 95% w/w of paraffinic components.

3. The fuel composition of claim 1 wherein the weight ratio of iso to normal paraffins in the Fischer-Tropsch derived middle distillate fuel is at least 4.0.

4. The fuel composition of claim 1 , wherein the middle distillate flow improver is present in the composition at a treat rate of 500-3000 mg/kg.

5. The fuel composition of claim 1 , wherein the middle distillate flow improver is present in the composition at a treat rate of 750-2000 mg/kg.

6. The fuel composition of claim 1 , wherein the amount of the Fischer-Tropsch derived middle distillate fuel is at least 95% v/v of the total composition.

7. The fuel composition of claim 1 , wherein the amount of the Fischer-Tropsch derived middle distillate fuel is at least 98% v/v of the total composition.

8. The fuel composition of claim 1 , wherein the amount of the Fischer-Tropsch derived middle distillate fuel is at least 99% v/v of the total composition.

9. The fuel composition of claim 1 , wherein the Fischer-Tropsch derived middle distillate fuel is the only fuel component in the fuel composition.

Assignees

• Shell Oil Co

Inventors

• Camero Mylin
• Dahlstrom Mary Ann
• Stevenson Paul Anthony

Classifications

• C10L1/1641 Primary

  from compounds containing aliphatic monomers · CPC title

• C10L10/14

  for improving low temperature properties · CPC title

• C10L2250/04

  Additive or component is a polymer · CPC title

• C10L2200/0492

  Fischer-Tropsch products · CPC title

• C10L1/1973

  mono-carboxylic · CPC title