Hydrogenated branched conjugated diene copolymer, rubber composition and pneumatic tire

Patent metadata

Field	Value
Publication number	US-10040877-B2
Application number	US-201314378193-A
Country	US
Kind code	B2
Filing date	Jan 22, 2013
Priority date	Mar 6, 2012
Publication date	Aug 7, 2018
Grant date	Aug 7, 2018

Abstract

A pneumatic tire produced by processing a rubber composition including a hydrogenated branched conjugated diene copolymer produced by copolymerizing a branched conjugated diene compound and a vinyl compound to form a branched conjugated diene copolymer and hydrogenating the branched conjugated diene copolymer. The branched conjugated diene compound is represented by formula (1),

where R 1 is an aliphatic hydrocarbon having 6 to 11 carbon atoms, the vinyl compound is represented by formula (3),

where R 4 is a hydrogen atom, an aliphatic hydrocarbon group having 1 to 3 carbon atoms, an alicyclic hydrocarbon group having 3 to 8 carbon atoms, or an aromatic hydrocarbon group having 6 to 10 carbon atoms, copolymerization ratio of the branched conjugated diene compound is 1 to 99% by weight, copolymerization ratio of the vinyl compound is 99 to 1% by weight, the branched conjugated diene compound is myrcene and/or farnesene, and the vinyl compound is styrene.

First claim

The invention claimed is:

1. A pneumatic tire produced by processing a rubber composition comprising a hydrogenated branched conjugated diene copolymer and a rubber component consisting of a styrene-butadiene rubber,
wherein the hydrogenated branched conjugated diene copolymer is produced by copolymerizing a branched conjugated diene compound and a vinyl compound to form a branched conjugated diene copolymer and hydrogenating the branched conjugated diene copolymer, a copolymerization ratio of the branched conjugated diene compound is 1 to 99% by weight, a copolymerization ratio of the vinyl compound is 99 to 1% by weight, the branched conjugated diene compound is at least one compound of formula (1),

where R 1 is an aliphatic hydrocarbon having 6 to 11 carbon atoms such that the branched conjugated diene compound includes farnesene, the vinyl compound is styrene, and the rubber composition includes 20 to 100 parts by weight of the hydrogenated branched conjugated diene copolymer based on 100 parts by weight of the rubber component consisting of the styrene-butadiene rubber.

2. The pneumatic tire of claim 1 , wherein a Mooney viscosity ML 1+4 (130° C.) of the rubber composition to which the hydrogenated branched conjugated diene copolymer is blended is lower compared with a Mooney viscosity ML 1+4 (130° C.) of a rubber composition comprising a polymer having the same weight-average molecular weight as the branched conjugated diene copolymer and prepared by replacing the branched conjugated diene compound by at least one of 1,3-butadiene and isoprene.

3. The pneumatic tire of claim 1 , wherein the hydrogenated branched conjugated diene copolymer has a weight-average molecular weight of 2,000 to 200,000.

4. The pneumatic tire of claim 1 , wherein the hydrogenated branched conjugated diene copolymer has a hydrogenation ratio of 10 to 90%.

5. The pneumatic tire of claim 1 , wherein the copolymerization ratio of the vinyl compound is 40% by weight or more.

6. The pneumatic tire of claim 2 , wherein the branched conjugated diene compound is farnesene.

7. The pneumatic tire of claim 4 , wherein the copolymerization ratio of the vinyl compound is 40% by weight or more.

8. The pneumatic tire of claim 3 , wherein the hydrogenated branched conjugated diene copolymer has a hydrogenation ratio of 10 to 90%.

9. The pneumatic tire of claim 1 , wherein the processing comprises forming a tread comprising the rubber composition and vulcanizing an unvulcanized tire comprising the tread.

10. The pneumatic tire of claim 3 , wherein the copolymerization ratio of the vinyl compound is 40% by weight or more.

11. The pneumatic tire of claim 2 , wherein the branched conjugated diene compound is myrcene and farnesene.

12. The pneumatic tire of claim 1 , wherein the branched conjugated diene compound is farnesene.

13. The pneumatic tire of claim 1 , wherein the branched conjugated diene compound is myrcene and farnesene.

14. The pneumatic tire of claim 1 , wherein the rubber composition includes 30 to 70 parts by weight of the hydrogenated branched conjugated diene copolymer based on 100 parts by weight of the rubber component consisting of the styrene-butadiene rubber.

15. The pneumatic tire of claim 1 , wherein the hydrogenated branched conjugated diene copolymer has a weight-average molecular weight of 3,000 to 100,000.

16. The pneumatic tire of claim 1 , wherein the hydrogenated branched conjugated diene copolymer has a hydrogenation ratio of 30 to 70%.

17. The pneumatic tire of claim 3 , wherein the processing comprises forming a tread comprising the rubber composition and vulcanizing an unvulcanized tire comprising the tread.

18. The pneumatic tire of claim 1 , wherein the hydrogenated branched conjugated diene copolymer has a glass transition temperature of −80° C. to 110° C.

19. The pneumatic tire of claim 1 , wherein the hydrogenated branched conjugated diene copolymer is produced by copolymerizing a conjugated diene compound, the branched conjugated diene compound and the vinyl compound to form the branched conjugated diene copolymer and hydrogenating the branched conjugated diene copolymer, the conjugated diene compound is at least one of 1,3-butadiene and isoprene, a copolymerization ratio of the conjugated diene compound is greater than 0% by weight and less than 99% by weight, and the copolymerization ratio of the vinyl compound is less than 99% by weight.

20. The pneumatic tire of claim 1 , wherein the hydrogenated branched conjugated diene copolymer is produced by copolymerizing a conjugated diene compound, the branched conjugated diene compound and the vinyl compound to form the branched conjugated diene copolymer and hydrogenating the branched conjugated diene copolymer, the conjugated diene compound is at least one of 1,3-butadiene, isoprene, and 2,3-dimethyl-1,3-butadiene, a copolymerization ratio of the conjugated diene compound is greater than 0% by weight and less than 99% by weight, and the copolymerization ratio of the vinyl compound is less than 99% by weight.

Assignees

• Sumitomo Rubber Ind

Inventors

• Washizu Kensuke

Classifications

• C08F236/10

  with vinyl-aromatic monomers · CPC title

• C08F36/06

  Butadiene · CPC title

• C08F236/22

  the radical having three or more carbon-to-carbon double bonds · CPC title

• C08F36/08

  Isoprene · CPC title

• C08F36/22 Primary

  the radical having three or more carbon-to-carbon double bonds · CPC title