Production of higher alcohols with minimum methanol content from the gasification of carbonaceous materials

Patent metadata

Field	Value
Publication number	US-10040736-B2
Application number	US-201514836495-A
Country	US
Kind code	B2
Filing date	Aug 26, 2015
Priority date	May 17, 2012
Publication date	Aug 7, 2018
Grant date	Aug 7, 2018

Abstract

Systems and methods for generating higher alcohols from synthesis gas produced from carbonaceous materials are described, which can include a reactor configured to produce an alcohol stream and CO 2 from a syngas feed. The alcohol stream can be separated in one or more downstream separators to produce a net reactor product and a methanol stream that can recycled into the reactor. The net reactor product preferably comprises higher-order alcohols such as ethanol, propanol, and butanol.

First claim

What is claimed is:

1. A plant configured to produce higher alcohols from synthesis gas produced from carbonaceous materials, comprising:
a gasification system configured to receive a carbonaceous feedstock and produce a syngas feed primarily composed of CO, H 2 , CH 4 , and CO 2 ;
a reactor configured to receive the syngas feed and produce an alcohol stream and CO 2 ;
a first heat exchanger configured to cool the alcohol stream and CO 2 using refrigeration content of the synthesis gas;
a separator configured to receive at least a portion of the alcohol stream and CO 2 and produce a methanol stream and a product stream;
a second heat exchanger configured to heat the alcohol stream and CO 2 before reaching the separator using heat content of the product stream; and
wherein the product stream from the separator is substantially depleted of methanol.

2. The plant of claim 1 , wherein the net reactor product primarily comprises ethanol, propanol, and butanol.

3. The plant of claim 1 , further comprising a slurry preparation unit upstream of the gasification system; wherein the slurry preparation unit is configured to mix water with the carbonaceous materials to form a slurry; wherein the gasification system is configured to receive the slurry, grey water, recycled condensate, and air to produce a scrubbed syngas stream that can be fed into a hydrolysis unit; wherein the gasification system is further configured to receive carbonaceous feedstock that comprises biomass.

4. The plant of claim 1 , further comprising a hydrolysis unit configured to produce steam; wherein the gasification system is configured to receive condensate from the hydrolysis unit; wherein the gasification system is further configured to receive carbonaceous feedstock that comprises at least one of petroleum coke and coal.

5. The plant of claim 1 , further comprising an acid gas removal unit configured to remove H 2 S; wherein the separator is further configured to produce the methanol stream that also comprises ethanol.

6. The plant of claim 1 , further comprising a CO 2 removal unit fluidly coupled to, and disposed upstream of, the reactor, and wherein the CO 2 removal unit is configured to selectively remove CO 2 from at least a portion of the syngas feed.

7. The plant of claim 1 , further comprising:
a second separator disposed downstream of the reactor and configured to receive at least a portion of the alcohol stream and produce a syngas stream and the alcohol stream; and
wherein the reactor is further configured to receive at least a portion of the syngas stream.

8. The plant of claim 7 , further comprising a CO 2 removal unit fluidly coupled to, and disposed upstream of, the reactor, and wherein the CO 2 removal unit is configured to receive at least some of the syngas stream.

9. The plant of claim 7 , further comprising a methanol wash unit fluidly coupled to, and disposed downstream of, the second separator, and wherein the methanol wash unit is configured to receive at least some of the syngas stream to produce a cleaned syngas stream and a methanol/H 2 O stream.

10. The plant of claim 9 , further comprising a methanol/H 2 O separation unit fluidly coupled to, and disposed downstream of, the methanol wash unit, and wherein the methanol/H 2 O separation unit is configured to receive the methanol/H 2 O stream and produce a condensate stream and a second methanol stream.

11. The plant of claim 10 , wherein the reactor is further configured to receive at least a portion of the methanol stream and the second methanol stream.

12. The plant of claim 1 , wherein the reactor is further configured to receive at least a portion of the methanol stream.

Assignees

• Fluor Tech Corp

Inventors

• Ravikumar Ravi
• Li Denny

Classifications

• C10J2300/0943

  Coke · CPC title

• C10K1/004

  Sulfur containing contaminants, e.g. hydrogen sulfide · CPC title

• C10J2300/093

  Coal · CPC title

• C10J2300/1665

  to alcohols, e.g. methanol or ethanol · CPC title

• C07C29/32

  increasing the number of carbon atoms by reactions without formation of -OH groups · CPC title