Process for providing a defined surface topography to at least a portion of a ceramic body

Patent metadata

Field	Value
Publication number	US-10040727-B2
Application number	US-201415106863-A
Country	US
Kind code	B2
Filing date	Dec 22, 2014
Priority date	Dec 23, 2013
Publication date	Aug 7, 2018
Grant date	Aug 7, 2018

Abstract

A Process for providing a defined surface topography to at least a portion of a ceramic body, the process comprising the subsequent steps of
a) applying a layer of a calcium containing substance comprising at least one calcium compound onto the surface of at least a portion of the ceramic basic body; b) thermally treating the ceramic basic body with the layer applied thereon at an elevated temperature, whereby a calcium compound or a calcium component based on the calcium compound diffuses into the basic body to form an intermediate body, said intermediate body comprising in its outermost surface region a calcium containing crystalline phase; and c) chemically treating the outermost surface region of the intermediate body with an inorganic acid or base to partially remove the calcium containing crystalline phase, thereby obtaining the surface topography.

First claim

The invention claimed is:

1. Process for providing a defined surface topography to at least a portion of a ceramic body, the process comprising the subsequent steps of
a) applying a layer of a calcium containing substance comprising at least one calcium compound onto the surface of at least a portion of the ceramic basic body;
b) thermally treating the ceramic basic body with the layer applied thereon at an elevated temperature, whereby a calcium compound or a calcium component based on the calcium compound diffuses into the basic body to form an intermediate body, said intermediate body comprising in its outermost surface region a calcium containing crystalline phase; and
c) chemically treating the outermost surface region of the intermediate body with hydrofluoric acid, an inorganic acid other than hydrofluoric acid, or an inorganic base to partially remove the calcium containing crystalline phase, thereby obtaining the surface topography,
wherein when the hydrofluoric acid is used, it is diluted in water in a volume ratio of water to hydrofluoric acid of at least 4:1.

2. Process according to claim 1 , wherein the ceramic basic body is made of a ceramic material comprising alumina and/or zirconia.

3. Process according to claim 1 , wherein the calcium containing crystalline phase is a Ca—Zr—O phase.

4. Process according to claim 3 , wherein the calcium containing crystalline phase is a CaO—ZrO 2 phase.

5. Process according to claim 1 , wherein the calcium compound contained in the calcium containing substance is selected from the group consisting of a calcium salt, calcium oxide, calcium hydroxide, metallic calcium, and mixtures thereof.

6. Process according to claim 1 , wherein the thermal treatment of step b) is carried out at a temperature of at least 500° C.

7. Process according to claim 1 , wherein an inorganic acid selected from the group consisting of HNO 3 , HCl, HF diluted in water in a volume ratio of water to hydrofluoric acid of at least 4:1, H 3 PO 4 and H 2 SO 4 and mixtures thereof, is used for the chemical treatment of step c).

8. Process according to claim 1 , further comprising a step of roughening at least a part of the surface of the basic body by a subtractive mechanical treatment.

9. Process according to claim 1 , wherein the surface topography is defined by the arithmetic mean height Sa being in a range from 0.1 μm and 1.7 μm.

10. Process according to claim 1 , wherein the surface topography is further defined by a developed surface area Sdr being in a range from 5% to 40%.

11. Process according to claim 1 , wherein step c) is carried out with an inorganic acid other than hydrofluoric acid.

12. Process according to claim 1 , wherein step c) is carried out with hydrofluoric acid diluted in water in a volume ratio of water to hydrofluoric acid of at least 80:1.

Assignees

• Straumann Holding Ag

Inventors

• Berner Simon

Classifications

• C04B41/5042

  Zirconium oxides or zirconates; Hafnium oxides or hafnates · CPC title

• C04B41/87 Primary

  Ceramics · CPC title

• C04B41/009

  characterised by the material treated · CPC title

• A61C2008/0046

  Textured surface, e.g. roughness, microstructure (A61C8/0013 takes precedence) · CPC title

• A61C8/0013

  with a surface layer, coating · CPC title