Hydrogen sulfide production process and related reactor vessels

Patent metadata

Field	Value
Publication number	US-10040684-B2
Application number	US-201615244024-A
Country	US
Kind code	B2
Filing date	Aug 23, 2016
Priority date	Dec 10, 2015
Publication date	Aug 7, 2018
Grant date	Aug 7, 2018

Abstract

The present invention discloses a hydrogen sulfide reactor vessel with an external heating system that is conductively and removably attached to an exterior portion of the reactor vessel. Also disclosed are processes for producing hydrogen sulfide utilizing the reactor vessel.

First claim

We claim:

1. A H 2 S reactor vessel comprising:
(a) a reaction chamber comprising a reactor wall, the reaction chamber configured to contain liquid sulfur;
(b) a reactor inlet for liquid sulfur, the reactor inlet positioned at an upper portion of the reactor vessel;
(c) a reactor outlet for liquid sulfur, the reactor outlet positioned at a lower portion of the reactor vessel;
(d) a gas inlet for a hydrogen-containing gas, the gas inlet connected to a gas distributor, the gas distributor positioned above the reactor outlet for liquid sulfur and configured to inject the hydrogen-containing gas into the liquid sulfur in the reaction chamber;
(e) a gas outlet for a H 2 S-rich gas stream, the gas outlet positioned above the reactor inlet;
(f) an internal heating system, the internal heating system positioned in the liquid sulfur in the reaction chamber during continuous operation of the reactor vessel and configured to maintain an operating temperature above the melting point of sulfur;
(g) an external heating system comprising a heated reactor conduit conductively and removably attached to a portion of an exterior surface of the reactor wall, wherein at least a portion of the heated reactor conduit is positioned in close proximity to the internal heating system and is configured to maintain a start-up temperature of the liquid sulfur above the melting point of sulfur at least until a level of the liquid sulfur in the reaction chamber is above the internal heating system; and
(h) a quench column positioned above the internal heating system and below the reactor inlet; wherein:
the external heating system further comprises a heated column conduit conductively and removably attached to at least a portion of an exterior surface of the quench column, wherein the heated column conduit is configured to maintain a quench column operating temperature of the liquid sulfur in the quench column above the melting point of sulfur; and
the quench column operating temperature is at least about 120° C.

2. The vessel of claim 1 , wherein the reactor vessel is configured for an operating temperature of at least about 300° C.

3. The vessel of claim 1 , wherein the hydrogen-containing gas comprises H 2 .

4. The vessel of claim 1 , wherein the reactor vessel is configured to produce a H 2 S-rich gas stream comprising at least about 95 wt. % H 2 S.

5. The vessel of claim 1 , wherein the internal heating system is an electric heating system configured to maintain an operating temperature of at least about 400° C.

6. The vessel of claim 1 , wherein the external heating system is configured to maintain a start-up temperature of at least about 120° C.

7. The vessel of claim 1 , wherein the heated reactor conduit comprises steam circulating through a pipe constructed of a conductive metal material.

8. The vessel of claim 1 , wherein the external heating system comprises from 1 to 4 heated reactor conduits.

9. The vessel of claim 1 , wherein a heat transfer material is present between the heated reactor conduit and the exterior surface of the reactor wall.

10. The vessel of claim 1 , wherein the reactor vessel comprises stainless steel, and the external heating system is capable of withstanding the thermal expansion and contraction of stainless steel over a temperature range of at least about 350° C.

11. The vessel of claim 1 , wherein the heated reactor conduit is present on less than about 10% of the surface area of the exterior surface of the reactor wall.

12. The vessel of claim 1 , wherein the external heating system comprises a cover over the heated reactor conduit, the cover configured to be removably attached to the exterior surface of the reactor wall.

13. The vessel of claim 12 , wherein the exterior surface of the reactor wall further comprises an attachment point configured for the removable attachment of the cover.

14. The vessel of claim 12 , wherein the heated reactor conduit and the cover are removably supported about the exterior surface of the reactor wall with a fastener.

15. The vessel of claim 1 , wherein the heated column conduit is present on less than about 20% of the surface area of the exterior surface of the quench column.

16. The vessel of claim 1 , wherein the external heating system comprises from 1 to 4 heated column conduits.

17. The vessel of claim 1 , wherein the quench column operating temperature is in a range from about 125° C. to about 450° C.

18. The vessel of claim 1 , wherein the heated column conduit comprises steam circulating through a pipe constructed of a conductive metal material.

19. The vessel of claim 1 , wherein a heat transfer material is present between the heated column conduit and the exterior surface of the quench column.

20. The vessel of claim 1 , wherein the external heating system comprises a cover over the heated column conduit, the cover configured to be removably attached to the exterior surface of the quench column.

21. The vessel of claim 20 , wherein the exterior surface of the quench column further comprises an attachment point configured for the removable attachment of the cover.

22. The vessel of claim 20 , wherein the heated column conduit and the cover are removably supported about the exterior surface of the quench column with a fastener.

Assignees

• Chevron Phillips Chemical Co Lp

Inventors

• Hasenberg Daniel M
• Pauwels Alex
• Mertens Ives

Classifications

• B01J19/2465

  externally, i.e. the mixture leaving the vessel and subsequently re-entering it · CPC title

• B01J2219/00083

  Coils · CPC title

• B01J19/24

  Stationary reactors without moving elements inside (B01J19/08, B01J19/26 take precedence; with stationary particles B01J8/02) · CPC title

• B01J2219/182

  horizontal · CPC title

• B01J2219/0009

  Coils · CPC title