Methods for fiber reinforced additive manufacturing

Patent metadata

Field	Value
Publication number	US-10040252-B2
Application number	US-201615186651-A
Country	US
Kind code	B2
Filing date	Jun 20, 2016
Priority date	Mar 22, 2013
Publication date	Aug 7, 2018
Grant date	Aug 7, 2018

Abstract

Various embodiments related to three dimensional printers, and reinforced filaments, and their methods of use are described. In one embodiment, a void free reinforced filament is fed into an extrusion nozzle. The reinforced filament includes a core, which may be continuous or semi-continuous, and a matrix material surrounding the core. The reinforced filament is heated to a temperature greater than a melting temperature of the matrix material and less than a melting temperature of the core prior to extruding the filament from the extrusion nozzle.

First claim

What is claimed is:

1. A method for additive manufacturing of a part, the method comprising:
feeding an unmelted fiber reinforced composite filament including multiple strands extending within a matrix material;
heating the fiber reinforced composite filament in a transverse pressure zone to a temperature greater than a melting temperature of the matrix material to melt the matrix material interstitially within the fiber reinforced composite filament;
applying a flattening force to the fiber reinforced composite filament as the fiber reinforced composite filament is deposited in bonded ranks to the part; and
maintaining a neutral to positive tension in the fiber reinforced composite filament between the flattening force and the part, the neutral to positive tension being a tension less than that necessary to separate a bonded rank from the part.

2. The method of claim 1 , wherein the feeding the unmelted fiber reinforced composite filament includes feeding the unmelted fiber reinforced composite along a clearance fit zone that prevents buckling of the fiber reinforced composite filament.

3. The method of claim 1 , wherein the matrix material comprises a thermoplastic resin having an unmelted ultimate tensile strength of approximately 10 through 100 MPa and a melted ultimate tensile strength of less than 10 MPa, and at least one of the multiple strands includes a stranded material having an ultimate tensile strength of approximately 200-100000 MPa.

4. The method of claim 3 , further comprising heating the fiber reinforced composite filament in a non-contact zone, and maintaining the neutral to positive tension primarily via tensile force within the multiple strands.

5. The method of claim 1 , further comprising maintaining a substantially constant cross sectional area of the fiber reinforced composite filament in the transverse pressure zone as a bonded rank is attached to the part.

6. The method of claim 5 , wherein the fiber reinforced composite filament has a cross sectional area greater than 1×10E-5 square inches and less than 2×10E-3 square inches.

7. The method of claim 5 , wherein at least one of the multiple strands includes, in any cross-section area, between 100 and 6000 parallel continuous axial strands.

8. The method of claim 1 , further comprising cutting the fiber reinforced composite filament at or adjacent the flattening force.

9. The method of claim 1 , further comprising:
drawing the fiber reinforced composite filament in the transverse pressure zone from a connection to a first portion of the part;
translating the transverse pressure zone through free space; and
flattening to reconnect the fiber reinforced composite filament to a second portion of the part.

10. A method for additive manufacturing of a part, the method comprising:
supplying an unmelted fiber reinforced composite filament including multiple strands extending within a matrix material of the fiber reinforced composite filament;
threading forward the fiber reinforced composite filament to contact the part in a transverse pressure zone;
translating the transverse pressure zone relative to and adjacent to the part-to bring an end of the fiber reinforced composite filament to a melting position; and
melting the matrix material interstitially within the fiber reinforced composite filament at the melting position.

11. The method of claim 10 , further comprising:
flattening, with a flattening force, the fiber reinforced composite filament as it is pressed in bonded ranks to the part; and
maintaining a neutral to positive tension in the fiber reinforced composite filament between the flattening force and the bonded ranks, the neutral to positive tension being a tension less than that necessary to separate a bonded rank from the part.

12. The method of claim 11 , further comprising controlling a height of the flattening force from a top of the part during the flattening to be less than a diameter of the fiber reinforced composite filament.

13. The method of claim 10 , wherein the matrix material comprises a thermoplastic resin having an unmelted elastic modulus of approximately 0.1 through 5 GPa and a melted elastic modulus of less than 0.1 GPa, and at least one of the multiple strands includes a stranded material having an elastic modulus of approximately 5-1000 GPa.

14. The method of claim 10 , further comprising;
heating the fiber reinforced composite filament immediately upstream of the flattening; and
compressing along the fiber reinforced composite filament via an axial compressive force within the multiple strands extending along the fiber reinforced composite filament.

15. The method of claim 14 , further comprising translating an end of the fiber reinforced composite filament abutting the part laterally underneath the transverse pressure zone to be flattened by application of heat and pressure.

16. The method of claim 15 , further comprising maintaining the fiber reinforced composite filament at a temperature below a glass transition temperature of the matrix material throughout at least one channel.

17. The method of claim 10 , further comprising cutting the fiber reinforced composite filament in an unmelted state.

18. The method of claim 10 , further comprising preventing the fiber reinforced composite filament from touching at least one heated wall of a cavity adjacent the transverse pressure zone.

19. The method of claim 10 , further comprising touching the fiber reinforced composite filament to a heated member in the transverse pressure zone to melt the matrix material of the fiber reinforced composite filament.

20. The method of claim 10 , further comprising:
forming ranks formed from flattened fiber reinforced composite filament bonded to the part, and
reshaping the ranks laterally and vertically with the flattening force combined with a reaction force from previously formed ranks.

21. The method according to claim 1 , wherein heating the fiber reinforced composite filament in the transverse pressure zone to the temperature greater than the melting temperature of the matrix material to melt the matrix material interstitially within the fiber reinforced composite filament includes heating the fiber reinforced composite filament in the transverse pressure zone to a temperature greater than a glass transition temperature of the matrix material to flow the matrix material interstitially within the fiber reinforced composite filament.

22. The method according to claim 1 , wherein heating the fiber reinforced composite filament in the transverse pressure zone to the temperature greater than the melting temperature of the matrix material to melt the matrix material interstitially within the fiber reinforced composite filament includes heating the fiber reinforced composite filament in the transverse pressure zone to a temperature greater than a melting point temperature of the matrix material to flow the matrix material interstitially within the fiber reinforced composite filament.

23. The method according to claim 10 , wherein translating the transverse pressure zone relative to and adjacent to the part to bring the end of the fiber reinforced composite filament to the melting position comprises translating the transverse pressure zone relative to and adjacent to the part to bring the end of the fiber reinforced composite filament to a glass transition position, and
wherein melting the matrix material interstitially within the fiber reinforced composite filamen

Assignees

• Markforged Inc

Inventors

• Mark Gregory Thomas

Classifications

• B29K2025/08

  Copolymers of styrene, e.g. AS or SAN, i.e. acrylonitrile styrene (B29K2055/02 takes precedence) · CPC title

• B29C64/209

  Heads; Nozzles · CPC title

• B33Y10/00

  Processes of additive manufacturing · CPC title

• B29K2071/00

  Use of polyethers {, e.g. PEEK, i.e. polyether-etherketone or PEK, i.e. polyetherketone or derivatives thereof}, as moulding material · CPC title

• B29C64/118

  using filamentary material being melted, e.g. fused deposition modelling [FDM] · CPC title