Slurry hydroconversion using enhanced slurry catalysts

Patent metadata

Field	Value
Publication number	US-10035959-B2
Application number	US-201414308905-A
Country	US
Kind code	B2
Filing date	Jun 19, 2014
Priority date	Jun 20, 2013
Publication date	Jul 31, 2018
Grant date	Jul 31, 2018

Abstract

Systems and methods are provided for slurry hydroconversion of a heavy oil feed, such as an atmospheric or vacuum resid. The systems and methods allow for slurry hydroconversion using catalysts with enhanced activity and/or catalysts that can be recycled as a side product from a complementary refinery process.

First claim

What is claimed is:

1. A method for processing a heavy oil feedstock, comprising:
providing a heavy oil feedstock having a 10% distillation point of at least about 650° F. (343° C.); and
exposing the heavy oil feedstock to a plurality of slurry hydroconversion catalysts under effective slurry hydroconversion conditions to form at least a plurality of liquid products, the effective slurry hydroconversion conditions being effective for conversion of at least about 80 wt % of the heavy oil feedstock relative to a conversion temperature,
wherein the plurality of slurry hydroconversion catalysts consist of a first Mo-based catalyst and a second Fe-based catalyst, a ratio of Fe to Mo being about 8:1 to about 25:1.

2. The method of claim 1 , further comprising separating the plurality of liquid products using one or more separators, wherein a first separator of the one or more separators separates a slurry hydroconversion effluent to form a second plurality of liquid products and a product comprising a slurry hydroconversion pitch, wherein at least a portion of the product comprising the slurry hydroconversion pitch is recycled for exposure to the plurality of slurry hydroconversion catalysts under the effective slurry hydroconversion conditions.

3. The method of claim 1 , wherein the conversion temperature is at least about 975° F. (524° C.).

4. The method of claim 1 , wherein the heavy oil feedstock comprises a catalytic slurry oil.

5. The method of claim 1 , wherein the first Mo-based catalyst is formed from a first catalyst precursor comprising phosphomolybdic acid.

6. The method of claim 1 , wherein the first Mo-based catalyst is formed from a first catalyst precursor while forming the second Fe-based catalyst from a second catalyst precursor.

7. The method of claim 6 , wherein the first catalyst is formed from the first catalyst precursor in situ by reaction and/or decomposition of the first catalyst precursor in at least one of a hydroprocessing reaction zone environment and a pretreatment step, the first catalyst comprising catalytically active solid particulates.

8. The method of claim 1 , wherein a concentration of the Mo of the first catalyst in the heavy oil feedstock is at least about 50 wppm.

Assignees

• Sundararaman Ramanathan
• Degnan Jr Thomas Francis
• Billimoria Rustom Merwan
• Fassbender Natalie Ann
• Francisco Manuel A
• Kovvali Anjaneya Sarma
• Smiley Randolph J
• Greeley John Peter
• Lewis William Ernest
• Bearden Jr Roby
• Exxonmobil Res & Eng Co

Inventors

• Sundararaman Ramanathan
• Degnan Jr Thomas Francis
• Billimoria Rustom Merwan
• Fassbender Natalie Ann
• Francisco Manuel A
• Kovvali Anjaneya Sarma
• Smiley Randolph J
• Greeley John Peter
• Lewis William Ernest
• Bearden Jr Roby

Classifications

• C10G69/14

  plural parallel stages only · CPC title

• C10G49/12 Primary

  suspended in the oil, e.g. slurries · CPC title

• C10G69/06

  including at least one step of thermal cracking in the absence of hydrogen · CPC title

• C10G9/005

  Coking (in order to produce liquid products mainly) · CPC title

• C10G49/04

  containing nickel, cobalt, chromium, molybdenum, or tungsten metals, or compounds thereof · CPC title