Inorganic blue pigments from cobalt doped magnesium having transition element oxides and a process for the preparing the same

Patent metadata

Field	Value
Publication number	US-10035914-B2
Application number	US-201515311423-A
Country	US
Kind code	B2
Filing date	Sep 22, 2015
Priority date	Sep 22, 2014
Publication date	Jul 31, 2018
Grant date	Jul 31, 2018

Abstract

The present invention relates to a new Inorganic Blue pigments from Cobalt doped Magnesium having Transition Element Oxides and a process for the preparing the same. The present invention more particularly relates to the development of blue pigments, comprising oxides of alkaline earth, and transition metals of the general formula Mg 1-x Co x WO 4 (x=0.1 to 0.5), Mg 1-x Co x N-bO 6 (x=0.1 to 0.5), and Mg 1-x Co x TiO 3 (x=0.1 to 0.5) and well suited for coloring applications of a wide variety of substrates for example paints, varnishes, plastics, ceramics etc. Raw materials such as MgO, CoO and one of WO 3 , TiO 2 , Nb 2 O 5 and are weighted in the stoichiometric ratio and calcined in the range 1100-1300° C. for 6-12 hrs duration in air atmosphere. The well ground calcined powders were used for characterization of the pigments. The phase purity and optical properties of the prepared pigments were investigated.

First claim

We claim:

1. A Blue pigment having the general formula Mg 1-x Co x WO 4 (x=0.1 to 0.5).

2. The Blue pigment according to claim 1 of the formula, Mg 1-x Co x WO 4 (x=0.1 to 0.5) having chromaticity coordinates, determined as per the CIE 1976 colour scales are L*=39.01 to 46.28, a*=−0.10 to 6.33, b*=−32.88 to −46.97.

3. The Blue pigment according to claim 1 of the formula, Mg 1-x Co x WO 4 (x=0.1 to 0.5) having NIR reflectance of 42 to 56% and NIR solar reflectance of 21 to 28.6%.

4. A Blue pigment having the general formula Mg 1-z Co x Nb 2 O 6 (x=0.1 to 0.5).

5. The Blue pigment according to claim 4 of the formula, Mg 1-x Co x Nb 2 O 6 (x=0.1 to 0.5) having chromaticity coordinates, determined as per the CIE 1976 colour scales are L*=52.78 to 68.05, a*=−0.97 to −2.55, b*=−27.64 to −36.16.

6. The Blue pigment according to claim 4 of the formula, Mg 1-x Co x Nb 2 O 6 (x=0.1 to 0.5) having NIR reflectance of 86 to 74% and NIR solar reflectance of 38 to 43%.

7. A Blue pigment having the general formula Mg 1-x Co x TiO 3 (x=0.2, 0.3, or 0.4.

8. The Blue pigment according to claim 7 of the formula, Mg 1-x Co x TiO 3 (x=0.2, 0.3, or 0.4) having chromaticity coordinates, determined as per the CIE 1976 colour scales are L*=36.62 to 54.13, a*=−11.04 to −15.73, b*=−11.66 to −25.61.

9. The Blue pigment according to claim 7 of the formula, Mg 1-x Co x TiO 3 (x=0.2, 0.3, or 0.4) having NIR reflectance of 46 to 73% and NIR solar reflectance of 23 to 37%.

10. A process for the preparation of a blue pigment comprising Cobalt doped Magnesium and one Transition Element Oxide selected from Tungsten, Niobium and Titanium, comprising the steps of:
mixing thoroughly MgO (purity 99%), CoO (99.99%) with one of the Transition Element Oxides (purity 99.995%) in a stochiometric ratio in agate mortar with a pestle;
ii) calcining the mixture at 1100-1300° C. in air atmosphere for 6-12 hrs duration; and
iii) getting blue pigment in the form of powder having particle size 1-5 μm.

Assignees

• Council Scient Ind Res

Inventors

• Rao Padala Prabhakar
• Divya Saraswathy

Classifications

• C09C1/36

  Compounds of titanium {(C09C1/0009, C09C1/0015, C09C1/0078 take precedence)} · CPC title

• C09C1/02 Primary

  Compounds of alkaline earth metals or magnesium {(C09C1/0003, C09C1/0009, C09C1/0015, C09C1/0078 take precedence; dolomitic solids C09C1/009)} · CPC title

• C01P2006/64

  b* (yellow-blue axis) · CPC title

• C01P2006/63

  a* (red-green axis) · CPC title

• C01P2006/62

  L* (lightness axis) · CPC title