Resin blend

Patent metadata

Field	Value
Publication number	US-10035902-B2
Application number	US-201514755702-A
Country	US
Kind code	B2
Filing date	Jun 30, 2015
Priority date	May 28, 2010
Publication date	Jul 31, 2018
Grant date	Jul 31, 2018

Abstract

Provided are a resin blend for melt processing, a pellet and a method of preparing a resin article using the same. The resin blend may include a first resin, and a second resin having a difference in melt viscosity from the first resin of 0.1 to 3000 pa*s at a shear rate of 100 to 1000 s −1 and a processing temperature of the resin blend. The resin blend can improve mechanical and surface characteristics of a resin article. Further, since coating or plating is not required for manufacturing a resin article, a manufacturing time and/or cost can be reduced, and productivity can be increased.

First claim

What is claimed is:

1. A melt-processed resin blend, comprising: a blend of two resins having a melt viscosity difference between the first and second resins is 0.1 to 3000 pa*s at a shear rate of 100 to 1000 s −1 and a processing temperature of the resin blend, wherein the resin blend is separated into a layer-separated structure comprising: a first resin layer; and a second resin layer having a lower melt viscosity than the first resin layer, wherein the second resin layer is disposed between the first resin layer and an ambient air in response to a melting process, wherein the second resin layer has a molecular weight distribution of 1.9 to 2.1, wherein the second resin has a weight average molecular weight of 30,000 to 200,000, wherein the first resin includes at least one selected from the group consisting of a styrene-based resin, a polyolefin-based resin, a thermoplastic elastomer, a polyoxyalkylene-based resin, a polyester-based resin, a polyvinyl chloride-based resin, a polycarbonate-based resin, a polyphenylene sulfide-based resin, a vinyl alcohol-based resin, an acrylate-based resin, engineering plastics and a copolymer thereof, and wherein a content of the second resin is 0.1 to 50 parts by weight based on 100 parts by weight of the first resin.

2. The melt-processed resin blend according to claim 1 , wherein the second resin includes at least one selected from the group consisting of a (meth)acrylate-based resin, an epoxy-based resin, an oxetane-based resin, an isocyanate-based resin, a silicon-based resin, a fluorine-based resin and a copolymer thereof.

3. A method of preparing the melt-processed resin blend of claim 1 , comprising:
(a) blending a first resin and a second resin having to form a melt blend, wherein a melt viscosity difference between the first resin and the second resin is 0.1 to 3000 pa*s at a shear rate of 100 to 1000 s −1 and a processing temperature of the blend, wherein the second resin layer has a molecular weight distribution of 1.9 to 2.1, wherein the second resin has a weight average molecular weight of 30,000 to 200,000, wherein the first resin includes at least one selected from the group consisting of a styrene-based resin, a polyolefin-based resin, a thermoplastic elastomer, a polyoxyalkylene-based resin, a polyester-based resin, a polyvinyl chloride-based resin, a polycarbonate-based resin, a polyphenylene sulfide-based resin, a vinyl alcohol-based resin, an acrylate-based resin, engineering plastics and a copolymer thereof, and wherein a content of the second resin is 0.1 to 50 parts by weight based on 100 parts by weight of the first resin; and (b) melt-processing the melt blend to form the melt-processed resin blend of claim 1 comprising the second resin layer disposed between the first resin layer and ambient air in response to the melting processing.

4. The method according to claim 3 , further comprising selecting the second resin such that a value of a melt viscosity of the second resin is less than that of the first resin, prior to the melting of the blend of the first and second resins.

5. The method according to claim 3 , wherein the melting and processing are performed under a shear stress.

6. The method according to claim 3 , further comprising:
curing the resulting product of step (b).

7. The method according to claim 6 , wherein the curing is a thermal curing or radiation curing.

8. A resin article prepared according to claim 3 , wherein the resin article has a layer-separated structure.

Assignees

• Lg Chemical Ltd

Inventors

• Ryu Jin Young
• Yoo Houng Sik
• Kim Hak Shin
• Hong Young Jun
• Shin Chong Kyu
• Choi Eun Joo

Classifications

• C08L33/04

  Homopolymers or copolymers of esters {(C08L43/04 takes precedence)} · CPC title

• C08L29/04

  Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids · CPC title

• C08L37/00

  Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a heterocyclic ring containing oxygen (of cyclic esters of polyfunctional acids C08L31/00; of cyclic anhydrides of unsaturated acids C08L35/00); Compositions of derivatives of such polymers · CPC title

• C08J2400/22

  Thermoplastic resins · CPC title

• Y10T428/239

  Complete cover or casing · CPC title