Rubber composition for treads and pneumatic tire

Patent metadata

Field	Value
Publication number	US-10035900-B2
Application number	US-201515503967-A
Country	US
Kind code	B2
Filing date	Jul 29, 2015
Priority date	Aug 28, 2014
Publication date	Jul 31, 2018
Grant date	Jul 31, 2018

Abstract

Provided are: a rubber composition for treads which contains a diene rubber in the rubber component and can simultaneously achieve blowing resistance during dry running, wet grip performance and abrasion resistance; and a pneumatic tire including a tread formed from the rubber composition for treads. The rubber composition contains: a diene rubber including styrene-butadiene rubber; zinc dithiophosphate; an inorganic filler including at least one selected from the group consisting of: a compound of the formula: mM.xSiO y .zH 2 O wherein M represents at least one metal selected from the group consisting of Al, Mg, Ti, Ca, and Zr, or an oxide or hydroxide of the metal, m represents an integer of 1-5, x represents an integer of 0-10, y represents an integer of 2-5, and z represents an integer of 0-10; magnesium sulfate; and silicon carbide, and having a BET value of 5-120 m 2 /g and a linseed oil absorption of 30-80 mL/100 g; and sulfur, wherein, per 100 parts by mass of the diene rubber, there are 0.2-15 parts by mass of the zinc dithiophosphate, 1-70 parts by mass of the inorganic filler, and less than 2.5 parts by mass of zinc oxide.

First claim

The invention claimed is:

1. A rubber composition for treads, comprising:
a diene rubber including styrene-butadiene rubber;
zinc dithiophosphate;
an inorganic filler which comprises at least one selected from the group consisting of a compound represented by the formula below, magnesium sulfate, and silicon carbide, and has a BET value of 5 to 120 m 2 /g and a linseed oil absorption of 30 to 80 mL/100 g; and
sulfur,
wherein, per 100 parts by mass of the diene rubber, there are 0.2 to 15 parts by mass of the zinc dithiophosphate, 1 to 70 parts by mass of the inorganic filler, and less than 2.5 parts by mass of zinc oxide,
the formula being
m M. x SiO y .z H 2 O

wherein M represents at least one metal selected from the group consisting of Al, Mg, Ti, Ca, and Zr, or an oxide or hydroxide of the metal; m represents an integer of 1 to 5; x represents an integer of 0 to 10; y represents an integer of 2 to 5; and z represents an integer of 0 to 10.

2. The rubber composition for treads according to claim 1 ,
wherein the inorganic filler has a BET value of 10 to 120 m 2 /g and a linseed oil absorption of 30 to 80 mL/100 g.

3. The rubber composition for treads according to claim 1 ,
wherein the inorganic filler is aluminum hydroxide.

4. The rubber composition for treads according to claim 1 ,
wherein the diene rubber includes 60% by mass or more of a styrene-butadiene rubber having a styrene content of 19% to 60%.

5. The rubber composition for treads according to claim 1 ,
wherein the rubber composition comprises a carbon black having a BET value of 151 m 2 /g or more in an amount of 5 to 130 parts by mass per 100 parts by mass of the diene rubber.

6. The rubber composition for treads according to claim 1 ,
wherein the rubber composition is free of zinc oxide.

7. A pneumatic tire, comprising a tread formed from the rubber composition for treads according to claim 1 .

Assignees

• Sumitomo Rubber Ind

Inventors

• Miyazaki Tatsuya

Classifications

• C08C19/22

  Incorporating nitrogen atoms into the molecule · CPC title

• C08F236/10

  with vinyl-aromatic monomers · CPC title

• C08C19/44

  of polymers containing metal atoms exclusively at one or both ends of the skeleton · CPC title

• C08C19/25

  Incorporating silicon atoms into the molecule · CPC title

• C08K2003/3063

  Magnesium sulfate · CPC title