Control methods and systems for polymer product purge

Patent metadata

Field	Value
Publication number	US-10035864-B2
Application number	US-201615258226-A
Country	US
Kind code	B2
Filing date	Sep 7, 2016
Priority date	Nov 5, 2015
Publication date	Jul 31, 2018
Grant date	Jul 31, 2018

Abstract

Disclosed herein are methods and systems for purging a polymer product of volatiles. The methods and systems are particularly useful in the purging of a polyethylene polymer product produced in a fluidized bed reactor.

First claim

What is claimed is:

1. A method for purging a polymer product of volatiles, the method comprising:
producing a polymer product comprising volatile species in a reactor;
transferring the polymer product from the reactor to at least one purge bin;
injecting a purge gas into the at least one purge bin to create a purged polymer product and a used purge gas;
discharging the purged polymer product from the at least one purge bin to produce a discharged purged polymer product; and
determining a relationship between purge efficiency, X o /X i , and (S*P)/G for one or more species of the volatile species purged from the polymer product, wherein:
X o is the concentration in ppmw of the volatile species in the discharged purged polymer product;
X i is the concentration in mol % of the volatile species in a gas phase of the reactor upstream of the at least one purge bin;
S is a production rate in Klb polymer per hour of the reactor;
P is an absolute pressure in psia within the at least one purge bin; and
G is a mass flow rate in lb purge gas per hour in the at least one purge bin.

2. The method of claim 1 , wherein the reactor comprises a fluidized bed reactor with a cycle gas loop, and X i is the concentration in mol % of the volatile species in the cycle gas.

3. The method of claim 1 , wherein the reactor comprises a fluidized bed reactor, and X i is the concentration in mol % of the volatile species in a gas phase at a point within the fluidized bed reactor.

4. The method of claim 1 , wherein the at least one purge bin comprises a top section and a bottom section.

5. The method of claim 1 , further comprising recovering at least a portion of the used purge gas and recycling it to the at least one purge bin.

6. The method of claim 5 , further comprising removing at least a portion of the volatile species comprising four or more carbon atoms from the used purge gas prior to recycling it to the at least one purge bin.

7. The method of claim 5 , further comprising removing at least a portion of the volatile species comprising three or less carbon atoms from the used purge gas, wherein the removing occurs in a bottom section of the at least one purge bin.

8. The method of claim 1 , further comprising determining a minimum fluidization velocity for the at least one purge bin, and maintaining a purge gas velocity within the at least one purge bin below the minimum fluidization velocity.

9. The method of claim 1 , further comprising determining a relationship between purge efficiency, X o /X i , and (S*P*M)/G for one or more species of the volatile species purged from the polymer product and M is a molecular weight of the purge gas in lb/lb-mol.

10. The method of claim 9 , further comprising adjusting at least one of the parameters S, P, M, or G to improve purge efficiency.

11. The method of claim 9 , further comprising maintaining the value of (S*P)/G or (S*P*M)/G at or below a target value.

12. The method of claim 1 , wherein the one or more volatile species is selected from the group consisting of 1-hexene, 3-methyl-2-pentene, cis- and trans-2-hexene, cis- and trans-3-hexene, 4-methyl-2-pentene, and 2-ethyl-1-butene.

13. The method of claim 1 , further comprising injecting steam into the at least one purge bin.

14. The method of claim 1 , wherein the purge gas is nitrogen.

15. The method of claim 1 , further comprising heating the polymer product after it is discharged from the reactor and before it is transferred to the at least one purge bin.

16. The method of claim 1 , wherein the polymer product comprises polyethylene.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Sandell David J

Classifications

• B01J2208/00973

  Products · CPC title

• C08F6/28 Primary

  Purification · CPC title

• B01J8/24

  according to "fluidised-bed" technique (B01J8/20 takes precedence) · CPC title

• B01J2208/00663

  Concentration · CPC title

• B01J8/0015 Primary

  Feeding of the particles in the reactor; Evacuation of the particles out of the reactor · CPC title