Process for the production of 1,4-butanediol and tetrahydrofuran from furan

Patent metadata

Field	Value
Publication number	US-10035783-B2
Application number	US-201615564494-A
Country	US
Kind code	B2
Filing date	Apr 7, 2016
Priority date	Apr 9, 2015
Publication date	Jul 31, 2018
Grant date	Jul 31, 2018

Abstract

The present invention provides a process for the production of THF and 1,4-BDO from furan in the presence of a catalytic composition, wherein the catalytic composition contains at least one metal selected from the group consisting of Fe, Ru, Os, Co, Rh, Jr, Ni, Pd, Pt and, optionally, contains one or more additional metal on a solid support, and wherein said process comprises the steps of: i) contacting furan with hydrogen and water in a reactor in the presence of said catalytic composition for a time; ii) stopping the flow of furan and the flow of water to the reactor and removing furan and water from the reactor; iii) subjecting the catalytic composition to a gas stream comprising hydrogen at a temperature of from 200 to 600° C. in the absence of the furan and water; iv) re-starting the flow of furan and the flow of water to the reactor.

First claim

That which is claimed is:

1. A process for the production of tetrahydrofuran and 1,4-butanediol from furan in the presence of a catalytic composition, wherein the catalytic composition contains at least one metal selected from the group consisting of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt and, optionally, contains one or more additional metal on a solid support, and wherein said process comprises the steps of:
i) contacting furan with hydrogen and water in a reactor in the presence of said catalytic composition for a time;
ii) stopping the flow of furan and the flow of water to the reactor and removing furan and water from the reactor;
iii) regenerating the catalytic composition by subjecting the catalytic composition to a gas stream comprising hydrogen at a temperature of from 200 to 600° C. in the absence of the furan and water;
iv) re-starting the flow of furan and the flow of water to the reactor.

2. The process according to claim 1 , wherein the catalyst contains one or more additional metals, comprising rhenium.

3. The process according to claim 1 , wherein in step i) the furan is contacted with hydrogen and water in a reactor in the presence of said catalytic composition for the time it takes for the activity of the catalytic composition to be reduced by at least 5% and at most 90%, as compared to the original activity of said catalytic composition under the same conditions.

4. The process according to claim 1 , wherein the temperature at which the catalytic composition is subjected to a gas stream comprising hydrogen in step iii) is at least 25° C. higher than the temperature at which furan is contacted with hydrogen and water in a reactor in the presence of said catalytic composition for a time.

5. The process according to claim 1 , wherein the temperature at which furan is contacted with hydrogen and water in a reactor in the presence of said catalytic composition for a time is in the range of from 100 to 350° C.

6. The process according to claim 5 , wherein the temperature at which the catalytic composition is subjected to a gas stream comprising hydrogen in step iii) is in the range of from 250 to 450° C.

7. The process according to claim 1 , wherein the solid support is selected from the group consisting of titanium oxides, zirconium oxides and active carbon.

8. The process according to claim 1 , wherein the reactor is cooled prior to re-starting the flow of furan and the flow of water to the reactor.

9. The process according to claim 1 , wherein the process of steps i) to iv) are repeated more than once with the same catalytic composition.

Assignees

• Shell Oil Co

Inventors

• Lange Jean Paul Andre Marie Joseph Ghislain
• Haan Rene Johan

Classifications

• C07D307/08 Primary

  Preparation of tetrahydrofuran · CPC title

• C07C31/207

  1,4-Butanediol; 1,3-Butanediol; 1,2-Butanediol; 2,3-Butanediol · CPC title

• C07C29/172

  with the obtention of a fully saturated alcohol · CPC title

• B01J38/10

  using elemental hydrogen · CPC title

• B01J23/96

  of catalysts comprising metals, oxides or hydroxides of the noble metals · CPC title