Process for continuously recovering (meth)acrylic acid and apparatus for the process

Patent metadata

Field	Value
Publication number	US-10035751-B2
Application number	US-201414914233-A
Country	US
Kind code	B2
Filing date	Aug 26, 2014
Priority date	Aug 30, 2013
Publication date	Jul 31, 2018
Grant date	Jul 31, 2018

Abstract

This disclosure relates to a method for continuous recovery of (meth)acrylic acid and an apparatus used for the recovery method. The method of continuous recovery of (meth)acrylic acid according to the present invention may minimize loss of (meth)acrylic acid particularly in the distillation process, and yet enables stable operation of the distillation process and energy reduction.

First claim

The invention claimed is:

1. A method for continuous recovery of (meth)acrylic acid, comprising:
an absorption process wherein a mixed gas comprising (meth)acrylic acid, organic by-products, and vapor, which is produced by a synthesis reaction of (meth)acrylic acid, is contacted with an absorption solvent including water to obtain a (meth)acrylic acid aqueous solution;
an extraction process wherein a part of the (meth)acrylic acid aqueous solution obtained through the absorption process is contacted with an extraction solvent in an extraction column to obtain a (meth)acrylic acid extract solution through the upper outlet of the extraction column and obtain a raffinate solution passing through the lower stationary section of the extraction column through the lower outlet; and
a distillation process wherein a feed containing the remainder of the (meth)acrylic acid aqueous solution obtained through the absorption process and the (meth)acrylic acid extract obtained through the extraction process is distilled to obtain (meth)acrylic acid,
wherein the distillation process is conducted in a distillation column having a plurality of stages partitioned by perforated trays, and wherein, based on a feed point to which the feed is supplied, the distillation column comprises a rectifying section at an area above the feed point and a stripping section at an area below the feed point, wherein the tray open area of the perforated trays located at the rectifying section is lower than the tray open area of the perforated trays located at the stripping section.

2. The method according to claim 1 , the ratio of the tray open area of the perforated trays located at the stripping section to the tray open area of the perforated trays located at the rectifying section is from 1:0.6 to 1:0.9.

3. The method according to claim 1 , wherein the perforated trays are dual-flow-type countercurrent trays.

4. The method according to claim 1 , wherein the feed point is any one point corresponding to 40 to 60% of total stages from the uppermost stage of the distillation column.

Assignees

• Lg Chemical Ltd

Inventors

• Song Jong Hun
• Baek Se Won
• Yoo Sul Hee
• Min Yoon Jae

Classifications

• C07C51/44 Primary

  by distillation · CPC title

• C07C51/43

  by change of the physical state, e.g. crystallisation · CPC title

• B01D3/143

  by two or more of a fractionation, separation or rectification step · CPC title

• C07C57/04

  Acrylic acid; Methacrylic acid · CPC title

• C07C51/47

  by solid-liquid treatment; by chemisorption · CPC title