Inorganic binder composition comprising a copolymer

Patent metadata

Field	Value
Publication number	US-10035729-B2
Application number	US-201515318033-A
Country	US
Kind code	B2
Filing date	Jun 12, 2015
Priority date	Jun 12, 2014
Publication date	Jul 31, 2018
Grant date	Jul 31, 2018

Abstract

The present invention relates to a composition comprising (α) at least one inorganic binder and (β) at least one water-soluble copolymer based on (a) 0.1 to 20 wt % of at least one monomer of the formula (I) and (b) 25 to 99.9 wt % of at least one hydrophilic monomer (b) which is different from monomer (a), where the at least one copolymer has a molar mass average M of 1 500 000 to 30 000 000 g/mol. Furthermore, a process for producing this composition is disclosed. A further aspect of the present invention is the use of the copolymer of component (β) as rheological additive in a composition of the invention.

First claim

The invention claimed is:

1. A composition comprising
(α) at least one inorganic binder
(β) at least one water-soluble copolymer based on
(a) 0.1 to 20 wt % of at least one monomer of the formula (I),
H 2 C═C(R 1 )—R 2 —O—(—CH 2 —CH 2 —O—) k —(—CH 2 —CH(R 3 )—O—) l —(—CH 2 —CH 2 —O—) m —R 4    (I)

where the units —(—CH 2 —CH 2 —O—) k , —(—CH 2 —CH(R 3 )—O—) l and —(—CH 2 —CH 2 —O—) m are arranged in a block structure in the order shown in formula (I)
and the radicals have the following meanings:
k: is from 10 to 150;
l : is from 5 to 25;
m: is from 1 to 15;
R 1 : is H or methyl;
the radicals R 2 : are each, independently of one another, a single bond or a divalent, linking group selected from the group consisting of —(C n H 2n )— and —O—(C n′ H 2n′ )— and —C(O)—O—(C n″ H 2n″ )—, where n, n′ and n″ are each a natural number from 1 to 6;
R 3 : is a hydrocarbon radical having at least 2 carbon atoms or an ether group of the general formula —CH 2 —O—R 3′ , where R 3′ is a hydrocarbon radical having at least 2 carbon atoms and the radicals R 3 can be identical or different within the group —(—CH 2 —CH(R 3 )—O—) l ;

the radicals R 4 : are each, independently of one another, H or a hydrocarbon radical having 1 to 4 carbon atoms, and
(b) 25 to 99.9 wt % by weight of at least one monoethylenically unsaturated, hydrophilic monomer (b) different from monomer (a),
where the wt % figures are in each case based on the total amount of all monomers in the copolymer and the at least one copolymer has a molar mass average M of 1 500 000 to 30 000 000 g/mol which is determined by the Mark-Houwink relationship (1)
M =([η]/ K ) 1/α   (1),

where K=0.0049, α=0.8 and [η] is the intrinsic viscosity.

2. The composition according to claim 1 , wherein the inorganic binder is at least one from the series calcium sulfate n-hydrate, Portland cement, white cement, calcium aluminum cement, calcium sulfoaluminum cement, geopolymer, and latent hydraulic and/or pozzolanic binder.

3. The composition according to claim 1 , wherein the index k is from 23 to 26.

4. The composition according to claim 1 , wherein the index l is from 8.5 to 17.25.

5. The composition according to claim 1 , wherein the radicals have the following meanings:
k: is from 23 to 26;
l: is from 12.75 to 17.25;
m: is from 2 to 5;
R 1 : is H;
R 2 : is a divalent, linking group —O—(C n′ H 2n′ )—, where n′ is 4;
R 3 : is a hydrocarbon radical having 2 carbon atoms;
R 4 : is H.

6. The composition according to claim 1 , wherein at least one of the monomers (b) is a monomer comprising acidic groups, the acidic groups comprising at least one group selected from the group of —COOH, —SO 3 H and —PO 3 H 2 and salts thereof.

7. The composition according to claim 1 , which comprises at least two different monoethylenically unsaturated, hydrophilic monomers (b), namely
at least one neutral hydrophilic monomer (b1), and
at least one hydrophilic anionic monomer (b2) which comprises at least one acidic group selected from the group of —COOH, —SO 3 H and —PO 3 H 2 and salts thereof.

8. The composition according to claim 1 , wherein the at least one copolymer is a copolymer based on
at least one monomer (a) of the formula (I), and also
acrylamide as neutral hydrophilic monomer (b1) and
acrylamido-2-methylpropanesulfonic acid (AMPS) as anionic hydrophilic monomer (b2).

9. The composition according to claim 1 , wherein the component (β) further comprises (c) at least one nonionic, nonpolymerizable, surface-active component.

10. The composition according to claim 1 , which comprises, based on its dry mass, at least 20 wt % of the at least one inorganic binder and 0.0005 to 5 wt % of the at least one copolymer.

11. A process for producing a composition according to claim 1 , wherein the monomer (a) of the general formula (I) is prepared by a process comprising the following steps:
a) reaction of a monoethylenically unsaturated alcohol A1 of the general formula (II)
H 2 C═C(R 1 )—R 2 —OH  (II),

with ethylene oxide,
where the radicals R 1 and R 2 are as defined;
with addition of an alkaline catalyst K1 comprising KOMe and/or NaOMe; giving an alkoxylated alcohol A2;
b) reaction of the alkoxylated alcohol A2 with at least one alkylene oxide Z of the formula (Z)

where R 3 is as defined;
with addition of an alkaline catalyst K2;
where the concentration of potassium ions in the reaction in step b) is less than or equal to 0.9 mol %, based on the alcohol A2 used;
and the reaction in step b) is carried out at a temperature of less than or equal to 135° C., giving an alkoxylated alcohol A3 of the formula (III),
H 2 C═C(R 1 )—R 2 —O—(—CH 2 —CH 2 —O—) k —(—CH 2 —CH(R 3 )—O—) l —H  (III)

where the radicals R 1 , R 2 , R 3 , k and l are as defined;
c) reaction of the alcohol A3 with ethylene oxide; giving an alkoxylated alcohol A4 which corresponds to the monomer (a) of the formula (I) where R 4 ═H and m=1 to 15;
d) optionally etherification of the alkoxylated alcohol A4 with a compound
R 4 —X

where R 4 is a hydrocarbon radical having 1 to 4 carbon atoms and X is a leaving group, optionally selected from the group consisting of Cl, Br, I, —O—SO 2 —CH 3 (mesylate), —O—SO 2 —CF 3 (triflate) and —O—SO 2 —OR 4 ;
giving a monomer (a) of the formula (I) where R 4 =hydrocarbon radical having 1 to 4 carbon atoms.

12. A process for producing a composition as claimed in claim 1 , wherein the copolymer is prepared by subjecting at least one monomer (a) and at least one hydrophilic monomer (b) to an aqueous solution polymerization.

13. The process according to claim 12 , wherein the solution polymerization is carried out at a pH in the range from 5.0 to 9.

14. The process according to claim 12 , wherein the solution polymerization is carried out in the presence of at least one surface-active component (c).

15. A process comprising utilizing the copolymer of component (β) as rheological additive in a composition according to claim 1 .

Assignees

• Basf Se

Inventors

• Langlotz Björn
• Gastner Thomas
• Gädt Torben
• Mazanec Oliver
• Schinabeck Michael
• Eissmann Diana
• Friedrich Stefan

Classifications

• C04B28/14

  containing calcium sulfate cements {(gypsum-paper plates E04C)} · CPC title

• C04B24/26

  obtained by reactions only involving carbon-to-carbon unsaturated bonds {(C04B24/243 takes precedence)} · CPC title

• C04B28/04

  Portland cements · CPC title

• C04B28/06

  Aluminous cements (monolithic refractories or refractory mortars C04B35/66) · CPC title

• C04B24/16

  Sulfur-containing compounds · CPC title