Method and apparatus for removal of oil from utility gas stream

Patent metadata

Field	Value
Publication number	US-10035096-B2
Application number	US-201514807742-A
Country	US
Kind code	B2
Filing date	Jul 23, 2015
Priority date	Apr 30, 2008
Publication date	Jul 31, 2018
Grant date	Jul 31, 2018

Abstract

The present application is directed to a method and system for preparing gaseous utility streams from gaseous process streams, particularly, removing oil contamination from such streams prior to use in a dry gas seal. The methods and systems may include at least one kinetic swing adsorption process including pressure swing adsorption, temperature swing adsorption, calcination, and inert purge processes to treat gaseous streams for use in dry gas seals of rotating equipment such as compressors, turbines and pumps and other utilities. The adsorbent materials used include a high surface area solid structured microporous and mesoporous materials.

First claim

What is claimed is:

1. A system for treating a gaseous feed stream, comprising:
a selective component removal system, comprising:
a gaseous feed stream inlet configured to pass a gaseous feed stream into a swing adsorption unit having at least one structured adsorbent bed comprising a high surface area solid, wherein:
the gaseous feed stream includes a volume of oil droplets and a volume of oil vapor and has a pressure from at least about 100 bar to at least about 500 bar;
the at least one structured adsorbent bed is configured to remove at least a portion of the volume of oil droplets and a portion of the volume of oil vapor to provide a substantially oil-free gaseous outlet stream; and
the at least one structured adsorbent bed is regenerated in a kinetic swing adsorption process; and

one or more compressors configured to receive a sour gas process stream, to receive a portion of the substantially oil-free gaseous outlet stream, to compress the sour gas process stream and to utilize the portion of the substantially oil-free gaseous outlet stream as a dry seal gas.

2. The system of claim 1 , wherein the kinetic swing adsorption process is selected from the group consisting of a calcination process, a temperature swing process, a pressure swing process, an inert purge process, and any combination thereof.

3. The system of claim 2 , wherein the system is configured to remove the volume of oil droplets and vapor in a sharp adsorption front as modeled by a Langmuir isotherm.

4. The system of claim 3 , wherein the at least one structured adsorbent bed is regenerated by raising the temperature of the structured adsorbent bed to at least about 250° C.

5. The system of claim 2 , wherein the structured adsorbent bed is regenerated by a thermal wave process.

6. The system of claim 2 , wherein the structured adsorbent bed is regenerated by a gas or fluid flowed co-currently, counter-currently, or orthogonally (e.g. crossflow) to a flow direction of the gaseous feed stream.

7. The system of claim 1 , further comprising a fluid impermeable housing substantially surrounding the swing adsorption unit.

8. The system of claim 7 , wherein the fluid impermeable housing is operable at up to about 10,000 pounds per square inch.

9. The system of claim 2 , wherein the structured adsorbent bed is selected from the group consisting of a parallel channel contactor, a structured flow through adsorbent contactor, a flow through adsorbent, and any combination thereof.

10. The system of claim 9 , further comprising a segmented contactor configured to house at least two structured adsorbent beds, wherein each pair of structured adsorbent beds is separated by a seal.

11. The system of claim 1 , wherein the oil is a substantially ash-free oil.

12. The system of claim 1 , wherein the oil is a synthetic composed of a random copolymer of ethylene oxide and propylene oxide.

13. The system of claim 12 , wherein the random copolymer of ethylene oxide and propylene oxide has an average molecular weight greater than about 1,200 gram/mole and less than or equal to about 2,500 gram/mole.

14. The system of claim 1 , further comprising a cooling jacket operatively engaging the at least one structured adsorbent bed.

15. The system of claim 2 , further comprising a heater selected from the group consisting of an indirect electric adsorbent bed heater, a direct electric adsorbent bed heater, a direct gas heating fluid, and any combination thereof.

16. The system of claim 1 , further comprising a heat exchanger configured to utilize cooling fluid to cool the substantially oil-free gaseous outlet stream.

17. The system of claim 1 , further comprising an accumulator configured to hold the substantially oil-free gaseous outlet stream.

18. The system of claim 1 , wherein the high surface area solid is selected from the group consisting of: alumina, mesoporous solids, and microporous solids.

19. The system of claim 18 , wherein the high surface area solid is selected from the group consisting of: aluminas, carbons, activated carbon, charcoal, cationic zeolites, high silica zeolites, highly siliceous ordered mesoporous materials, sol gel materials, ALPO materials (microporous and mesoporous materials containing predominantly aluminum phosphorous and oxygen), SAPO materials (microporous and mesoporous materials containing predominantly silicon aluminum phosphorous and oxygen), MOF materials (microporous and mesoporous materials comprised of a metal organic framework) and ZIF materials (microporous and mesoporous materials comprised of zeolitic imidazolate frameworks).

20. The system of claim 18 , wherein the high surface area solid has a surface area greater than about 10 square meters per gram (m 2 /gm).

21. The system of claim 3 , wherein greater than 99.99999 percent of the oil is removed from the gaseous feed stream.

22. The system of claim 18 , wherein the high surface area solid is a 12-14 ring zeolite with a Si to Al ratio of more than about 50:1.

23. The system of claim 18 , wherein the high surface area solid is an ordered mesoporous material of the M41S family.

24. The system of claim 1 , further comprising a conditioning unit.

Assignees

• Deckman Harry W
• Kamakoti Preeti
• Ravikovitch Peter I
• Kelley Bruce T
• Northrop P Scott
• Rasmussen Peter C
• Tanaka Paul L
• Webster Martin N
• Roth Wieslaw J
• Corcoran Jr Edward W
• Exxonmobil Upstream Res Co

Inventors

• Deckman Harry W
• Kamakoti Preeti
• Ravikovitch Peter I
• Kelley Bruce T
• Northrop P Scott
• Rasmussen Peter C
• Tanaka Paul L
• Webster Martin N
• Roth Wieslaw J
• Corcoran Jr Edward W

Classifications

• Y02C20/40

  of CO2 · CPC title

• B01D2257/70

  Organic compounds not provided for in groups B01D2257/00 - B01D2257/602 · CPC title

• B01D2253/204

  Metal organic frameworks (MOF's) · CPC title

• B01D2253/20

  Organic adsorbents · CPC title

• B01D2253/1124

  Metal oxides · CPC title