Transition metal containing nitrogen-doped carbon support structure for sulfur active material as a cathode for a lithium-sulfur battery

Patent metadata

Field	Value
Publication number	US-10033046-B2
Application number	US-201615339495-A
Country	US
Kind code	B2
Filing date	Oct 31, 2016
Priority date	Oct 31, 2016
Publication date	Jul 24, 2018
Grant date	Jul 24, 2018

Abstract

Cathodes for lithium-sulfur batteries inhibit the parasitic polysulfide shuttle effect. The cathodes contain an active material support having a transition metal-containing nitrogen doped carbon developed to host the sulfur and suppress the diffusion of polysulfides into the electrolyte by retaining them in the high surface area nanostructured pores of the carbon while the transition metals serve as anchors for the soluble species due to the transition metals' affinity for sulfur. The cathodes 12 are gram scalable and have high surface area and high conductivity. The cathode active material support includes a nitrogen-containing polymer structure doped with a sulfide precursor of one or more transition metals selected from the group containing Fe, V, Mo, W, Co, Ni, Cu and Zn.

First claim

What is claimed is:

1. A cathode for a lithium-sulfur battery comprising:
an active material support comprising a nitrogen-containing polymer structure doped with a sulfide precursor of one or more transition metals selected from the group containing Fe, V, Mo, W, Co, Ni, Cu and Zn; and
an active material comprising sulfur supported on the active material support.

2. The cathode of claim 1 , wherein the nitrogen-containing polymer is one or more of melamine, polymeric melamine, polyaniline, bipyridine, 5-aminotetrazole, polyethyleneimine, poly(melamine formaldehyde) and ammonium carbamate.

3. The cathode of claim 2 , wherein the nitrogen-containing polymer is a combination of two or more of polymeric melamine, melamine and polyaniline.

4. The cathode of claim 2 , wherein the nitrogen-containing polymer is a combination of polyaniline and ammonium carbamate.

5. The cathode of claim 1 , wherein the nitrogen-containing polymer is polymeric melamine and the active material support further includes additional sulfur that is covalently bonded to the transition metal, the additional sulfur derived from the solvent used during polymerization of the melamine to produce the polymeric melamine.

6. The cathode of claim 1 , wherein the cathode has a nitrogen content of greater than or equal to 5 wt. % and less than or equal to 20 wt. %.

7. The cathode of claim 1 , wherein the sulfur in the active material support is greater than or equal to 0.5 wt. % and less than or equal to 10 wt. % and the sulfur in the cathode is greater than or equal to 0.5 wt. % and less than or equal to 60 wt. %.

8. The cathode of claim 1 , wherein the active material support further comprises carbon.

9. The cathode of claim 8 , wherein the active material support has a surface area greater than or equal to 100 m 2 /g and less than or equal to 1400 m 2 /g.

10. The cathode of claim 8 , wherein the active material support has a pore volume greater than or equal to 20 mL/g and less than or equal to 500 mL/g.

11. The cathode of claim 1 , wherein the sulfur in the active material is uniformly distributed on the active material support.

12. The cathode of claim 11 , wherein the sulfur in the active material forms a coating on the active material support.

13. A cathode active material support for a lithium-sulfur battery comprising:
one or more nitrogen-containing polymer selected from melamine, polymeric melamine and polyaniline, doped with one or more transition metal sulfide precursor, the transition metal selected from the group containing Fe, V, Mo, W, Co, Ni, Cu and Zn; and
carbon.

14. A method of preparing a cathode for a lithium-sulfur battery, the method comprising:
preparing an active material support comprising:
pyrolyzing, at a temperature greater than or equal to 800° C. and less than or equal to 1200° C., a nitrogen-containing polymer, carbon, and a sulfide precursor of one or more transition metal selected from the group containing Fe, V, Mo, W, Co, Ni, Cu and Zn; and

mixing the active material support with an active material containing sulfur.

15. The method of claim 14 , wherein the nitrogen-containing polymer is melamine, the method further comprising:
prior to pyrolyzing, polymerizing the melamine using dimethyl sulfoxide as a solvent, wherein sulfur from the dimethyl sulfoxide covalently bonds to the transition metal during pyrolyzing.

16. The method of claim 14 , wherein the cathode has a nitrogen content of greater than or equal to 5 wt. % and less than or equal to 20 wt. %.

17. The method of claim 14 , wherein the sulfur in the active material support is greater than or equal to 0.5 wt. % and less than or equal to 10 wt. % and the sulfur in the cathode is greater than or equal to 0.5 wt. % and less than or equal to 60 wt. %.

18. The method of claim 14 , wherein the active material support has a surface area greater than or equal to 100 m 2 /g and less than or equal to 1400 m 2 /g.

19. The method of claim 14 , wherein the active material support has a pore volume greater than or equal to 20 mL/g and less than or equal to 500 mL/g.

20. The method of claim 14 , wherein the nitrogen-containing polymer is one or more of melamine, polyaniline, bipyridine, 5-aminotetrazole, polyethyleneimine, poly(melamine formaldehyde) and ammonium carbamate.

Assignees

• Nissan North America Inc

Inventors

• Gumeci Cenk
• Atienza Dianne

Classifications

• H01M4/13

  Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title

• H01M4/139 Primary

  Processes of manufacture · CPC title

• H01M4/366

  as layered products · CPC title

• H01M4/38

  of elements or alloys · CPC title

• H01M4/382

  Lithium (H01M4/405 takes precedence) · CPC title