Polymer composition and a power cable comprising the polymer composition

Patent metadata

Field	Value
Publication number	US-10032543-B2
Application number	US-201715456329-A
Country	US
Kind code	B2
Filing date	Mar 10, 2017
Priority date	Nov 3, 2010
Publication date	Jul 24, 2018
Grant date	Jul 24, 2018

Abstract

An alternating current (AC) power cable includes a conductor surrounded by at least an inner semiconductive layer including a first semiconductive composition, an insulation layer including a polymer composition, an outer semiconductive layer including a second semiconductive composition, and optionally a jacketing layer including a jacketing composition, in that order. The polymer composition of the insulation layer includes an unsaturated low density polyethylene (LDPE) copolymer of ethylene with one or more polyunsaturated comonomers and a crosslinking agent. The polymer composition of the insulation layer has a dielectric loss expressed as tan δ (50 Hz) of 12.0×10 −4 or less, when measured at 25 kV/mm and 130° C. according to “Test for Tan δ measurements on 10 kV cables”.

First claim

What is claimed is:

1. An alternating current (AC) power cable, comprising a conductor surrounded by at least an inner semiconductive layer comprising a first semiconductive composition, an insulation layer comprising a polymer composition, an outer semiconductive layer comprising a second semiconductive composition and optionally a jacketing layer comprising a jacketing composition, in that order, wherein
the polymer composition of the insulation layer comprises a polyolefin and a crosslinking agent, wherein the polyolefin is an unsaturated low density polyethylene (LDPE) copolymer of ethylene with one or more polyunsaturated comonomers, and
wherein the polymer composition of the insulation layer has a dielectric loss expressed as tan δ (50 Hz) of 12.0×10 −4 or less, when measured at 25 kV/mm and 130° C. according to “Test for Tan δ measurements on 10 kV cables” as described in the description part under “Determination methods”; and
wherein the polyolefin is obtainable by a high pressure process comprising:
(a) compressing one or more monomer(s) under pressure in a compressor, using a compressor lubricant comprising a mineral oil for lubrication,
(b) polymerizing a monomer optionally together with one or more comonomer(s) in a polymerization zone, and
(c) separating the obtained polyolefin from the unreacted products and recovering the separated polyolefin in a recovery zone.

2. The cable according to claim 1 , wherein the polymer composition of the insulation layer has a dielectric loss expressed as tan δ (50 Hz) of 11.0×10 −4 or less, when measured at 25 kV/mm and 130° C. according to “Test for Tan δ measurements on 10 kV cables” as described in the description part under “Determination methods”.

3. The cable according to claim 1 , wherein the polymer composition of the insulation layer has a dielectric loss expressed as tan δ (50 Hz) of 0.01×10 −4 -10.0×10 −4 , when measured at 25 kV/mm and 130° C. according to “Test for Tan δ measurements on 10 kV cables” as described in the description part under “Determination methods”.

4. The cable according to claim 1 , wherein the compressor lubricant comprises a white oil as the mineral oil and is suitable for production of polymers for food or medical industry.

5. The cable according to claim 1 , wherein the mineral oil is a white mineral oil which meets requirements given for white mineral oil in European Directive 2002/72/EC of 6 Aug. 2002, Annex V, for plastics used in food contact.

6. The cable according to claim 1 , wherein the crosslinking agent is peroxide.

7. The cable according to claim 1 , wherein each of the inner and outer semiconductive composition comprises independently a conductive filler.

8. The cable according to claim 1 , wherein the cable comprises a jacketing layer comprising a jacketing composition.

9. The cable according to claim 1 , wherein at least the polymer composition of the insulation layer is crosslinked in the presence of said crosslinking agent.

10. The cable according to claim 1 , wherein at least the first semiconductive composition of the inner semiconductive layer and the polymer composition of the insulation layer are crosslinked.

11. The cable according to claim 1 , which is a medium voltage (MV) cable, a high voltage (HV) cable, or an extra high voltage (EHV) cable.

12. The cable according to claim 1 , wherein the unsaturated LDPE copolymer of ethylene with one or more polyunsaturated comonomers comprises one or more other comonomer(s).

13. The cable according to claim 1 , wherein the polyunsaturated comonomer consists of a straight carbon chain with at least 8 carbon atoms and at least 4 carbons between non-conjugated double bonds, of which at least one is terminal.

14. The cable according to claim 13 , wherein said polyunsaturated comonomer is a diene which comprises at least eight carbon atoms, the first carbon-carbon double bond being terminal and the second carbon-carbon double bond being non-conjugated to the first carbon-carbon double bond.

15. The cable according to claim 14 , wherein said diene is selected from C8- to C14-non-conjugated diene or mixtures thereof.

16. The cable according to claim 15 , wherein said diene is selected from the group consisting of 1,7-octadiene, 1,9-decadiene, 1,11-dodecadiene, 1,13-tetradecadiene, 7-methyl-1,6-octadiene, 9-methyl-1,8-decadiene, and mixtures thereof.

17. An alternating current (AC) power cable, comprising a conductor surrounded by at least an optionally crosslinked inner semiconductive layer comprising an optionally crosslinked first semiconductive composition, a crosslinked insulation layer comprising a crosslinked polymer composition, an optionally crosslinked outer semiconductive layer comprising an optionally crosslinked second semiconductive composition and optionally a jacketing layer comprising a jacketing composition, in that order, wherein
the crosslinked polymer composition of the insulation layer comprises a crosslinked polyolefin wherein the polyolefin is an unsaturated low density polyethylene (LDPE) copolymer of ethylene with one or more polyunsaturated comonomers, and
wherein the crosslinked polymer composition of the insulation layer has a dielectric loss expressed as tan δ (50 Hz) of 12.0×10 −4 or less, when measured at 25 kV/mm and 130° C. according to “Test for Tan δ measurements on 10 kV cables” as described in the description part under “Determination methods”; and

wherein the polyolefin is obtainable by a high pressure process comprising:
(a) compressing one or more monomer(s) under pressure in a compressor, using a compressor lubricant comprising a mineral oil for lubrication,
(b) polymerizing a monomer optionally together with one or more comonomer(s) in a polymerization zone, and
(c) separating the obtained polyolefin from the unreacted products and recovering the separated polyolefin in a recovery zone.

18. A process for producing an alternating current (AC) power cable wherein the process comprises:
applying on a conductor an inner semiconductive layer comprising a first semiconductive composition, an insulation layer comprising a polymer composition, an outer semiconductive layer comprising a second semiconductive composition, and optionally a jacketing layer comprising a jacketing composition; wherein the polymer composition of the insulation layer comprises a polyolefin and a crosslinking agent, wherein the polyolefin is an unsaturated low density polyethylene (LDPE) copolymer of ethylene with one or more polyunsaturated comonomers, and
wherein the polyolefin is obtainable by a high pressure process comprising:
(a) compressing one or more monomer(s) under pressure in a compressor, using a compressor lubricant comprising a mineral oil for lubrication,
(b) polymerizing a monomer optionally together with one or more comonomer(s) in a polymerization zone, and
(c) separating the obtained polyolefin from the unreacted products and recovering the separated polyolefin in a recovery zone;
crosslinking at least said insulation layer so as to form a crosslinked polymer composition of the insulation layer which has a dielectric loss expressed as tan δ (50 Hz) of 12.0×10 −4 or less, when measured at 25 kV/mm and 130° C. according to “Test for Tan δ measurements on 10 kV cables” as described in the description part under “Determination methods”.

Assignees

• Borealis Ag

Inventors

• Nilsson Ulf
• Smedberg Annika
• Campus Alfred

Classifications

• C08K5/14

  Peroxides · CPC title

• H01B7/17

  Protection against damage caused by external factors, e.g. sheaths or armouring · CPC title

• C08J3/24

  Crosslinking, e.g. vulcanising, of macromolecules (mechanical aspects B29C35/00; crosslinking agents C08K) · CPC title

• C08J2323/08

  Copolymers of ethene (C08J2323/16 takes precedence) · CPC title

• H01B3/441

  from alkenes · CPC title