Systems and methods of calibrating integrated computational elements

Patent metadata

Field	Value
Publication number	US-10031074-B2
Application number	US-201314362551-A
Country	US
Kind code	B2
Filing date	Sep 25, 2013
Priority date	Sep 25, 2013
Publication date	Jul 24, 2018
Grant date	Jul 24, 2018

Abstract

Disclosed are systems and methods for calibrating integrated computational elements. One method includes measuring with a spectrometer sample interacted light comprising spectral data derived from one or more calibration fluids at one or more calibration conditions, the one or more calibration fluids circulating in a measurement system, programming a virtual light source based on the spectral data, simulating the spectral data with the virtual light source and thereby generating simulated fluid spectra corresponding to the spectral data, conveying the simulated fluid spectra to the one or more ICE and thereby generating corresponding beams of optically interacted light, and calibrating the one or more ICE based on the corresponding beams of optically interacted light.

First claim

What is claimed is:

1. A method of calibrating an output signal from an integrated computational element (ICE), comprising:
configuring a virtual light source to emit a radiation that replicates an absorbance feature or a transmittance feature of a calibration fluid at multiple calibration conditions that comprise one of a plurality of temperatures, a plurality of pressures, or a plurality of fluid compositions;
conveying the radiation to the ICE and generating an optically interacted light;
receiving the optically interacted light with a detector that generates a response signal corresponding to the optically interacted light;
receiving the response signal with a data acquisition system to generate the output signal;
determining a gain and an offset to be applied to an output signal from the optically interacted light by comparing the output signal with archived regression vectors of known reference fluids; and
storing the gain and the offset in a non-transitory, computer readable medium.

2. The method of claim 1 , wherein configuring the virtual light source to emit a radiation that replicates an absorbance feature of a calibration fluid comprises conveying spectral signals generated in a spectrometer to the virtual light source, the spectral signals corresponding to collected spectra derived from the calibration fluid circulating in a measurement system at the calibration conditions.

3. The method of claim 1 , further comprising rotating the ICE on a filter wheel, the ICE being arranged radially about a periphery of the filter wheel.

4. The method of claim 1 , wherein the calibration fluid comprises at least a first calibration fluid, and wherein to derive the absorbance feature or the transmittance feature from the calibration fluid comprises:
circulating the first calibration fluid through an optic cell;
altering at least one of a temperature, a pressure, and a gas-oil-ratio of the first calibration fluid to obtain a first calibration condition of the calibration conditions;
equilibrating a measurement system to the first calibration condition;
optically interacting electromagnetic radiation with the first calibration fluid as it flows through the optic cell and thereby generating a first sample interacted light of a sample interacted light; and
conveying the first sample interacted light to a spectrometer, the first sample interacted light comprising spectral data derived from the first calibration fluid at the first calibration condition.

5. The method of claim 1 , further comprising:
replacing the ICE with an additional ICE;
conveying the radiation to the additional ICE and thereby generating corresponding additional beam of optically interacted light; and
calibrating the additional ICE based on the corresponding additional beam of optically interacted light.

6. The method of claim 5 , further comprising circulating the first calibration fluid through at least one of a liquid charging system, a gas charging system, a temperature control system, and a pressure control system in order to achieve the first calibration condition, the optic cell being fluidly coupled to the at least one of the liquid charging system, the gas charging system, the temperature control system, and the pressure control system.

7. The method of claim 5 , further comprising:
altering at least one of the temperature, the pressure, and the gas-oil-ratio of the first calibration fluid to obtain a second calibration condition of the calibration conditions;
equilibrating the measurement system to the second calibration condition;
optically interacting electromagnetic radiation with the first calibration fluid as it flows through the optic cell and thereby generating a second sample interacted light of the sample interacted light; and
conveying the second sample interacted light to the spectrometer, the second sample interacted light comprising spectral data derived from the first calibration fluid at the second calibration condition.

8. The method of claim 7 , wherein the calibration fluid further comprises a second calibration fluid, the method further comprising:
circulating the second calibration fluid through the optic cell;
altering at least one of a temperature, a pressure, and a gas-oil-ratio of the second calibration fluid to obtain a third calibration condition of the calibration conditions;
equilibrating the measurement system to the third calibration condition;
optically interacting electromagnetic radiation with the second calibration fluid as it flows through the optic cell and thereby generating a third sample interacted light of the sample interacted light; and
conveying the third sample interacted light to the spectrometer, the third sample interacted light comprising spectral data derived from the second calibration fluid at the third calibration condition.

9. The method of claim 8 , further comprising:
altering at least one of the temperature, the pressure, and the gas-oil-ratio of the second calibration fluid to obtain a fourth calibration condition of the calibration conditions;
equilibrating the measurement system to the fourth calibration condition;
optically interacting electromagnetic radiation with the second calibration fluid as it flows through the optic cell and thereby generating a fourth sample interacted light of the sample interacted light; and
conveying the fourth sample interacted light to the spectrometer, the fourth sample interacted light comprising spectral data derived from the second calibration fluid at the fourth calibration condition.

10. A system, comprising:
a virtual light source configured to emit a radiation that replicates an absorbance feature or a transmittance feature of a calibration fluid circulating in a measurement system at one or more calibration conditions, wherein the one or more calibration conditions comprises one of a plurality of temperatures, a plurality of pressures, or a plurality of fluid compositions;
an integrated computational element (ICE) arranged to receive the radiation from the virtual light source, the ICE being configured to generate an optically interacted light;
a detector arranged to receive the optically interacted light and generate a response signal corresponding to the optically interacted light;
a data acquisition system arranged to receive the response signal and generate an output signal corresponding to the ICE; and
a data analysis system arranged to receive the output signal and configured to determine a corresponding gain and offset to be applied to the output signal corresponding to the ICE by comparing the output signal with archived regression vectors of the calibration fluid.

11. The system of claim 10 , wherein the absorbance feature derived from a light interacted with the calibration fluid is collected with a Fourier transform infrared spectrometer.

12. The system of claim 10 , wherein the virtual light source is a programmable agile light source.

13. The system of claim 10 , wherein the ICE is arranged radially about a periphery of a filter wheel, the filter wheel comprising a second ICE.

14. The system of claim 10 , wherein the virtual light source is installed within a downhole tool and conveyed downhole such that the corresponding gain and offset are applied to the output signal corresponding to the ICE when the ICE is downhole.

15. The system of claim 10 , wherein the one or more calibration conditions comprise a pressure condition of the calibration fluid, a volume condition of the calibration fluid, and a temperature condition of the calibration fluid.

16. The system of claim 10

Assignees

• Halliburton Energy Services Inc

Inventors

• Gao Li
• Perkins David L
• Pelletier Michael T
• Chen Dingding

Classifications

• G01N21/314

  with comparison of measurements at specific and non-specific wavelengths (dual wavelength spectrometry G01J3/427) · CPC title

• G01N2021/3174

  Filter wheel · CPC title

• G01N21/274 Primary

  Calibration, base line adjustment, drift correction · CPC title

• G01N33/2841

  Gas in oils, e.g. hydrogen in insulating oils · CPC title