Films of nitrides of group 13 elements and layered body including the same
US-9041004-B2 · May 26, 2015 · US
US10030318B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10030318-B2 |
| Application number | US-201514969809-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 15, 2015 |
| Priority date | Jul 22, 2013 |
| Publication date | Jul 24, 2018 |
| Grant date | Jul 24, 2018 |
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A composite substrate includes a polycrystalline ceramic substrate, a silicon substrate directly bonded to the polycrystalline ceramic substrate, a seed crystal film formed on the silicon substrate by vapor phase process and made of a nitride of a group 13 element, and a gallium nitride crystal layer grown on the seed crystal film by flux method.
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The invention claimed is: 1. A method of manufacturing a functional element, said method comprising the steps of: thinning a silicon body of a composite body to provide a silicon film having a thickness of greater than 0.2 μm but not more than 8.0 μm, said composite body comprising a polycrystalline ceramic substrate and said silicon substrate directly bonded with each other; chamfering an outer peripheral surface of said composite body by a beveling process, a surface of said silicon film being positioned inside of said outer peripheral surface of said polycrystalline ceramic body after said beveling process; depositing a seed crystal film comprising a nitride of a group 13 element on said silicon film by a gas-phase method to cover said silicon film by said seed crystal film; growing a gallium nitride crystal layer on said seed crystal film by a flux method in a in a melt in a crucible, said melt comprising a gallium raw material and at least one element selected from the group consisting of an alkali metal and an alkaline earth metal, while said seed crystal film preventing contact of said silicon film and said melt and thereby preventing dissolution of silicon from a side surface of said silicon film into said melt; removing said composite substrate from said crucible, said composite substrate comprising said polycrystalline ceramic substrate, said silicon film, said seed crystal substrate, and said gallium nitride crystal layer; and forming a functional layer comprising a nitride of a group 13 element on said gallium nitride crystal layer by a gas-phase method to provide said functional element comprising said polycrystalline ceramic substrate, said silicon film, said seed crystal substrate, said gallium nitride crystal layer and said functional layer. 2. The method of claim 1 , wherein said functional layer has a function of emitting light. 3. The method of claim 1 , wherein said nitride of said group 13 element comprises gallium nitride. 4. The method of claim 1 , wherein said polycrystalline ceramic substrate comprises alumina or aluminum nitride. 5. The method of claim 1 , wherein said silicon film has a thickness of 0.5 μm or larger but not more than 8.0 μm.
of semiconductor materials · CPC title
Nitrides · CPC title
Crystal orientation · CPC title
consisting of two layers · CPC title
Nitrides · CPC title
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