Lubricant for powder metallurgy and metal powder compositions containing said lubricant

Patent metadata

Field	Value
Publication number	US-10030209-B2
Application number	US-201414484833-A
Country	US
Kind code	B2
Filing date	Sep 12, 2014
Priority date	Sep 12, 2013
Publication date	Jul 24, 2018
Grant date	Jul 24, 2018

Abstract

A particulate composite lubricant for powder metallurgy comprises: first discrete particles comprising at least about 90 wt % of a fatty primary monoamide wax, being substantially free of fatty bisamide wax, and being at least partially coated with metal oxide nanoparticles and second metal-stearate free discrete particles comprising a fatty bisamide wax. A particulate composite lubricant for powder metallurgy can comprise: a Montan acid ester wax and at least one fatty amide wax comprising at least one of a fatty monoamide wax and a fatty bisamide wax.

First claim

The invention claimed is:

1. A particulate composite lubricant for powder metallurgy comprising: first discrete particles comprising at least about 90 wt % of a fatty primary monoamide wax, being substantially free of fatty bisamide wax, and being at least partially coated with metal oxide nanoparticles and second metal-stearate free discrete particles comprising a fatty bisamide wax.

2. The particulate composite lubricant as claimed in claim 1 , wherein the particulate composite lubricant comprises between about 10 wt % and about 60 wt % of the first discrete particles and between about 40 wt % and about 90 wt % of the second discrete particles.

3. The particulate composite lubricant as claimed in claim 1 , wherein the first discrete particles consist essentially of the fatty primary monoamide wax at least partially coated with the metal oxide nanoparticles.

4. The particulate composite lubricant as claimed in claim 1 , wherein the second discrete particles further comprise at least about 50 wt % of the fatty bisamide wax and less than about 10 wt % of a fatty primary monoamide wax.

5. The particulate composite lubricant as claimed in claim 1 , wherein the second discrete particles further comprise at least about 90 wt % of the fatty bisamide wax.

6. The particulate composite lubricant as claimed in claim 1 , wherein the metal oxide nanoparticles comprise at least one of iron oxides, fumed silica, TiO 2 , Al 2 O 3 , SnO 2 , SiO 2 , CeO 2 , and indium titanium oxide nanoparticles, and combinations thereof.

7. The particulate composite lubricant as claimed in claim 1 , wherein the first discrete particles comprises less than about 5 wt % of metal oxide nanoparticles.

8. The particulate composite lubricant as claimed in claim 1 , wherein the first discrete particles are smaller than about 250 μm and the second discrete particles have an average particle size smaller than about 50 μm.

9. The particulate composite lubricant as claimed in claim 1 , wherein the at least partially coated first discrete particles have an average particle size between about 15 μm and about 100 μm.

10. The particulate composite lubricant as claimed in claim 1 , wherein the second discrete particles are substantially metal free.

11. A metallurgical powder composition, comprising a metal-based powder admixed with the particulate composite lubricant as claimed in claim 1 in a concentration ranging between about 0.1 wt % and about 5 wt %.

12. A process for producing a powder composition for powder metallurgy, comprising:
adding the particulate composite lubricant as claimed in claim 1 in a concentration ranging between about 0.1 wt % and about 5 wt %, based on a total weight of the powder composition, to a metal-based powder.

13. A particulate composite lubricant for powder metallurgy comprising: first discrete particles comprising a fatty primary monoamide wax, being substantially free of fatty bisamide wax, and being at least partially coated with metal oxide nanoparticles, the at least partially coated first discrete particles having average particle size between about 15 μm and about 100 μm, and second metal-stearate free discrete particles comprising a fatty bisamide wax and having average particle size smaller than about 50 μm.

14. The particulate composite lubricant as claimed in claim 13 , wherein the particulate composite lubricant comprises between about 10 wt % and about 60 wt % of the first discrete particles and the first discrete particles comprise at least about 90 wt % of the fatty primary monoamide wax.

15. The particulate composite lubricant as claimed in claim 13 , wherein the particulate composite lubricant comprises between about 40 wt % and about 90 wt % of the second discrete particles.

16. The particulate composite lubricant as claimed in claim 13 , wherein the first discrete particles consist essentially of the fatty primary monoamide wax at least partially coated with the metal oxide nanoparticles.

17. The particulate composite lubricant as claimed in claim 13 , wherein the second discrete particles further comprise at least about 50 wt % of the fatty bisamide wax and less than about 10 wt % of a fatty primary monoamide wax.

18. The particulate composite lubricant as claimed in claim 13 , wherein the second discrete particles further comprise at least about 90 wt % of the fatty bisamide wax.

19. The particulate composite lubricant as claimed in claim 13 , wherein the second discrete particles are substantially metal free.

20. A metallurgical powder composition, comprising a metal-based powder admixed with the particulate composite lubricant as claimed in claim 13 in a concentration ranging between about 0.1 wt % and about 5 wt %.

Assignees

• Nat Res Council Canada

Inventors

• Thomas Yannig
• Paris Vincent
• St-Laurent Sylvain

Classifications

• C10N2050/14

  Composite materials or sliding materials in which lubricants are integrally molded · CPC title

• C10N2020/06

  Particles of special shape or size · CPC title

• C10N2040/20

  Metal working · CPC title

• B22F1/10

  Metallic powder containing lubricating or binding agents; Metallic powder containing organic material · CPC title

• B22F1/103

  containing an organic binding agent comprising a mixture of, or obtained by reaction of, two or more components other than a solvent or a lubricating agent · CPC title