Polystyrene and polylactic acid blends

Patent metadata

Field	Value
Publication number	US-10030130-B2
Application number	US-201414894746-A
Country	US
Kind code	B2
Filing date	May 16, 2014
Priority date	Jun 6, 2013
Publication date	Jul 24, 2018
Grant date	Jul 24, 2018

Abstract

Polymeric blends of polystyrene (PS) and polylactic acid (PLA) are described, in the preparation of which a compatibilizing agent was added, preferably a PS-PLA block copolymer. Such compatibilizing agents act controlling phase separation of the blending compounds, and preventing excessive growth of polystyrene domains scattered in the PLA matrix; and this results in blends with good mechanical and thermal resistance.

First claim

The invention claimed is:

1. A polystyrene and polylactic acid blend, characterized by having:
a) a mixture of polystyrene (PS)/polylactic acid (PLA), wherein the polystyrene is a high impact polystyrene (HIPS), having as its base a matrix of styrene-based polymer and, dispersed in this matrix, a rubber phase made of discrete particles of rubber based on butadiene and/or styrene-butadiene, and where the polystyrene has a concentration from 70% m/m to 30% m/m, and the PLA has a concentration from 30% m/m to 70% m/m; and
b) PS-PLA block copolymer in concentrations of 0.1% to 15% in relation to the mixture of polystyrene/PLA.

2. The polystyrene and polylactic acid blend according to claim 1 , wherein the polystyrene is in concentrations from 60% m/m to 40% m/m in the mixture of polystyrene/polylactic acid.

3. The polystyrene and polylactic acid blend according to claim 1 , wherein the polylactic acid concentrations are in the range from 40% m/m to 60% m/m in the mixture of polystyrene/poly-lactic acid.

4. The polystyrene and polylactic acid blend according to claim 1 , wherein the PS-PLA copolymer is in concentrations from 3% m/m to 12% m/m in relation to the mixture of polystyrene/polylactic acid.

5. The polystyrene and polylactic acid blend according to claim 1 , wherein the PS-PLA copolymer concentrations are from 5% m/m to 10% m/m in relation to the mixture of polystyrene/polylactic acid.

6. The polystyrene and polylactic acid blend according to claim 1 , wherein the concentration by mass of the rubber phase in the polymeric matrix varies between 3% and 15%, in relation to the total mass of the polystyrene.

7. The polystyrene and polylactic acid blend according to claim 1 , wherein the rubber phase is constituted by rubber particles representing a morphology of the types “core shell” or “salami”, or even a mixture of those in different proportions.

8. The polystyrene and polylactic acid blend according to claim 7 , wherein the average diameter of the rubber particles range is from 0.1 microns to 8 microns over a distribution curve of particle sizes.

9. The polystyrene and polylactic acid blend according to claim 1 , wherein the styrene-based polymeric matrix comprising styrene presents average weighted molar mass (Mw) between 120,000 g/mol and 300,000 g/mol.

10. The polystyrene and polylactic acid blend according to claim 1 , wherein the appropriate PLA for this blend is obtained through lactic ring opening polymerization.

11. The polystyrene and polylactic acid blend according to claim 1 , wherein the PLA present different D or L isomers, that is, it can generate PLLA, PDLA or even a mixture of isomers, generating PDLLA is present as PLLA, PDLA, and/or PDLLA.

12. The polystyrene and polylactic acid blend according to claim 1 , wherein the average PLA number molar mass (Mn) is from 30,000 g/mol to 200,000 g/mol.

13. The polystyrene and polylactic acid blend according to claim 1 , wherein the average PLA number molar mass (Mn) is from 50,000 g/mol to 160,000 g/mol.

14. The polystyrene and polylactic acid blend according to claim 1 , wherein the PS-PLA block copolymer is obtained in two steps, the first step the PS block with OH thermal functionality (hydroxyl group) is synthesized via atom transfer radical polymerization (ATRP), and using tribromoethanol as the trigger; and in the second step the PS-OH block is used to initiate the polymerization via opening of the lactic ring, forming the PS-PLA block copolymer.

15. The polystyrene and polylactic acid blend according to claim 14 , wherein the average number molar mass (Mn) of the PS block is from 2,000 g/mol to 20,000 g/mol, and the average number molar mass (Mn) of the PLA block is from 2,000 g/mol to 20,000 g/mol.

16. The polystyrene and polylactic acid blend according to claim 14 , wherein the average number molar mass (Mn) of the PLA block is from 5,000 g/mol to 15,000 g/mol.

17. The polystyrene and polylactic acid blend according to claim 14 , wherein the average number molar mass (Mn) of HIPS is from 5,000 g/mol to 15,000 g/mol.

18. A pelleted composition prepared by extruding the blend according to claim 1 , in a single or double-screw extruder, at temperatures between 160° C. and 230° C., followed by cooling and then pelletizing.

19. The pelleted composition according to claim 18 , wherein the temperature of the blend in the extruder is between 165° C. and 210° C.

20. The pelleted composition according to claim 18 , wherein the temperature of the blend in the extruder is between 170° C. and 190° C.

21. The pelleted composition according to claim 18 , wherein the polylactic acid in the polystyrene/polylactic acid mixture is PLLA.

Assignees

• Petroleo Brasileiro S A —Petrobras
• Univ Federal Do Rio Grande Do Sul—Ufrgs
• Galhard Grassi Vinicius
• De Carvalho Peres Augusto Cesar
• Dal Pizzol Marcus Fernando
• Da Costa Joao Manoel
• Ossig Andreia
• Liberato Petzhold Cesar

Inventors

• Galhard Grassi Vinicius
• De Carvalho Peres Augusto Cesar
• Dal Pizzol Marcus Fernando
• Da Costa Joao Manoel
• Ossig Andreia
• Liberato Petzhold Cesar

Classifications

• C08L67/04 Primary

  Polyesters derived from hydroxycarboxylic acids, e.g. lactones (C08L67/06 takes precedence) · CPC title

• B29B9/12

  characterised by structure or composition · CPC title

• C08L25/06 Primary

  Polystyrene · CPC title

• C08L51/04

  grafted on to rubbers · CPC title

• B29K2025/06

  PS, i.e. polystyrene · CPC title