Polyacetal resin molded article

Patent metadata

Field	Value
Publication number	US-10030118-B2
Application number	US-201415512683-A
Country	US
Kind code	B2
Filing date	Oct 16, 2014
Priority date	Oct 16, 2014
Publication date	Jul 24, 2018
Grant date	Jul 24, 2018

Abstract

The resin molded article of the present invention comprises (B) 0.1 to 5 parts by mass of a sliding agent having a weight average molecular weight of 10,000 or less, and (C) 0.01 to 3 parts by mass of a coloring agent, based on (A) 100 parts by mass of a polyacetal resin, wherein a relative element concentration ratio between carbon and oxygen on a surface thereof [C/O] (atomic %) is 1.01 to 2.50.

First claim

The invention claimed is:

1. A resin molded article comprising (B) 0.1 to 5 parts by mass of a sliding agent having a weight average molecular weight of 10,000 or less and a melting point of 40° C. to 150° C. and (C) 0.01 to 3 parts by mass of a coloring agent, based on (A) 100 parts by mass of a polyacetal resin, wherein a relative element concentration ratio between carbon and oxygen [C/O] (atomic %) on a surface of the resin molded article is 1.01 to 2.50, wherein a peak intensity ratio (C—O/C═O) between a C—O stretching vibration peak and a C═O stretching vibration peak on the surface thereof, which is obtained by infrared spectroscopy, is 10 to 200.

2. The resin molded article according to claim 1 , wherein (A) the polyacetal resin comprises a block copolymer.

3. The resin molded article according to claim 2 , wherein the block copolymer is an ABA-based block copolymer, in which a polyacetal segment A and a hydrogenated polybutadiene segment B, both termini of which are hydroxyalkylated, are configured in the order of A-B-A.

4. The resin molded article according to claim 1 , wherein (B) the sliding agent having the weight average molecular weight of 10,000 or less is at least one compound selected from the group consisting of alcohol, amine, carboxylic acid, an ester, an amide compound consisting of monovalent or divalent amine and carboxylic acid, and wax.

5. The resin molded article according to claim 1 , wherein (C) the coloring agent comprises at least one metal oxide selected from the group consisting of iron, zinc, and titanium.

6. The resin molded article according to claim 1 , further comprising (D) 0.01 to 5 parts by mass of a polyolefin resin based on (A) 100 parts by mass of the polyacetal resin.

7. The resin molded article according to claim 6 , wherein (D) the polyolefin resin is at least one selected from the group consisting of (i) polyethylene, (ii) polypropylene, (iii) an ethylene-α-olefin copolymer, (iv) an ethylene-acrylic acid ester copolymer in which the content of the acrylic acid ester unit is 5% to 30% by mass, (v) a block polymer having a structure in which a block of polyolefin (d1) and a block of a hydrophilic polymer (d2) are repeatedly and alternatively bound to one another via at least one bond selected from the group consisting of an ester bond, an amide bond, an ether bond, a urethane bond, and an imide bond, and (vi) a modified product thereof.

8. The resin molded article according to claim 1 , wherein
(A) the polyacetal resin comprises a block copolymer,
(B) the sliding agent having the weight average molecular weight of 10,000 or less is at least one compound selected from the group consisting of alcohol, amine, carboxylic acid, an ester, an amide compound consisting of monovalent or divalent amine and carboxylic acid, and wax, and
(C) the coloring agent comprises at least one metal oxide selected form the group consisting of iron, zinc, and titanium.

Assignees

• Asahi Chemical Ind

Inventors

• Tsuzuki Junichi
• Miyoshi Takaaki

Classifications

• C08K2003/2296

  of zinc · CPC title

• C08K2003/2265

  of iron · CPC title

• C08K3/08

  Metals · CPC title

• C08L2666/72

  Fillers; Inorganic pigments; Reinforcing additives · CPC title

• C08K3/22

  of metals · CPC title