Polypropylene composite

Patent metadata

Field	Value
Publication number	US-10030109-B2
Application number	US-201515115929-A
Country	US
Kind code	B2
Filing date	Feb 6, 2015
Priority date	Feb 14, 2014
Publication date	Jul 24, 2018
Grant date	Jul 24, 2018

Abstract

Fiber reinforced composition comprising (a) a polypropylene random copolymer comprising ethylene and/or C4 to C8 a-olefin (PP-RACO), (b) glass fibers (GF), and (c) a polar modified polypropylene as adhesion promoter (AP), wherein (i) the polypropylene random copolymer comprising ethylene and/or C4 to C8 a-olefin (PP-RACO) heaving a melt flow rate MFR2 (230° C.) measured according to ISO 1133 of at least 2.5 g/10 min, (ii) the glass fibers (GF) are cut glass fibers and (iii) the polymer contained in the reinforced composition forms a continuous phase being the matrix of the fiber reinforced composition.

First claim

The invention claimed is:

1. A fiber reinforced composition comprising
(a) 50.0 to 84.5 wt. % of a metallocene catalyzed polypropylene random copolymer comprising ethylene and/or C 4 to C 8 α-olefin (PP-RACO),
(b) 15.0 to 45.0 wt. % glass fibers (GF) and
(c) 0.5 to 5.0 wt. % a modified polypropylene as adhesion promoter (AP), based on the total weight of the fiber reinforced composition,

wherein
(i) the polypropylene random copolymer comprising 1.0 to 10.0 wt. % of ethylene and/or C 4 to C 8 α-olefin (PP-RACO) having a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 of at least 2.5 g/10 min up to 15.0 g/10 min, having a xylene cold soluble content (XCS) measured according ISO 16152 (25° C.) in the range of 10 to 25 wt. %, and having a polydispersity (Mw/Mn) as determined by size exclusion chromatography in the range of 1.5 to 6.5,
(ii) the glass fibers (GF) are cut glass fibers and
(iii) the complete polymer contained in the reinforced composition forms a monophasic continuous phase being the matrix of the fiber reinforced composition.

2. The fiber reinforced composition according to claim 1 , wherein the adhesion promoter (AP) is a polypropylene homo- or copolymer with grafted polar groups.

3. The fiber reinforced composition according to claim 1 , wherein the overall tensile modulus measured at 23° C. according to ISO 527-2, measured at a cross head speed of 1 mm/min, is at least 2,500 MPa.

4. The fiber reinforced composition according to claim 1 , wherein the tensile strain at break measured at 23° C. according to ISO 527-2, measured at a cross head speed of 50 mm/min, is at least 4.0%.

5. The fiber reinforced composition according to claim 1 , wherein the amount of volatile organic compounds (VOC) measured according to VDA 278:2002 is equal to or below 50 ppm.

6. The fiber reinforced composition according to claim 1 , wherein the amount of fogging compounds (FOG) measured according to VDA 278:2002 is equal to or below 130 ppm.

7. The fiber reinforced composition according to claim 1 , wherein the polypropylene random copolymer (PP-RACO) is prepared by polymerizing propylene and ethylene and/or C 4-8 α-olefin in the presence of a catalyst, the catalyst comprising an asymmetrical complex of formula (I)

wherein
M is zirconium or hafnium;
each X is a sigma ligand;
L is a divalent bridge selected from —R′ 2 C—, —R′ 2 C—CR′ 2 —, —R′ 2 Si—, —R′ 2 Si—SiR′ 2 —, and —R′ 2 Ge—, wherein each R′ is independently a hydrogen atom, C 1-20 -hydrocarbyl, tri(C 1-20 -alkyl)silyl, C 6-20 -aryl, C 7-20 -arylalkyl or C 7-20 -alkylaryl;
R 2 and R 2′ are each independently a C 1-20 hydrocarbyl radical optionally containing one or more heteroatoms from groups 14-16;
R 5′ is a C 1-20 hydrocarbyl group optionally containing one or more heteroatoms from groups 14-16 and optionally substituted by one or more halo atoms;
R 6 and R 6′ are each independently hydrogen or a C 1-20 hydrocarbyl group optionally containing one or more heteroatoms from groups 14-16;
R 7 and R 7′ are each independently hydrogen or C 1-20 hydrocarbyl group optionally containing one or more heteroatoms from groups 14-16;
Ar is an aryl or heteroaryl group having up to 20 carbon atoms optionally substituted by one or more groups R 1 ;
Ar′ is an aryl or heteroaryl group having up to 20 carbon atoms optionally substituted by one or more groups R 1 ;
each R 1 is a C 1-20 hydrocarbyl group or two R 1 groups on adjacent carbon atoms taken together can form a fused 5 or 6 membered non aromatic ring with the Ar group, said ring being itself optionally substituted with one or more groups R 4 ; and
each R 4 is a C 1-20 hydrocarbyl group.

8. The fiber reinforced composition according to claim 7 , wherein the polypropylene random copolymer (PP-RACO) is prepared by polymerizing propylene and ethylene and/or C 4-8 α-olefin in the presence of a catalyst, the catalyst comprising an asymmetrical complex of formula (V) or (V′)

wherein each X is a sigma ligand;
R′ is independently a C 1-6 alkyl or C 3-10 cycloalkyl;
R 1 is C 3-8 alkyl;
R 6 is hydrogen or a C 3-8 alkyl group;
R 6′ is a C 3-8 alkyl group or C 6-10 aryl group;
R 3′ is a C 1-6 alkyl group, or C 6-10 aryl group optionally substituted by one or more halo groups; and
n is 0, 1 or 2.

9. A process for preparing the fiber reinforced composition according to claim 1 comprising the steps of adding
(a) polypropylene random copolymer (PP-RACO),
(b) the glass fibers (GF), and
(c) the polar modified polypropylene as adhesion promoter (AP) to an extruder and extruding the same obtaining the fiber reinforced composition.

10. An automotive article comprising the fiber reinforced composition according to claim 1 .

11. A foamed article comprising the fiber reinforced composition according to claim 1 .

Assignees

• Borealis Ag

Inventors

• Boragno Luca
• Tranninger Cornelia
• Gahleitner Markus

Classifications

• C08L23/0846

  with unsaturated hydrocarbons containing atoms other than carbon or hydrogen · CPC title

• C08K5/09

  Carboxylic acids; Metal salts thereof; Anhydrides thereof · CPC title

• C08J3/203

  Solid polymers with solid and/or liquid additives · CPC title

• C08F4/65925

  two cyclopentadienyl rings being mutually non-bridged · CPC title

• C08L23/14 Primary

  Copolymers of propene (C08L23/16 takes precedence) · CPC title