Catalyst components for the polymerization of olefins

Patent metadata

Field	Value
Publication number	US-10030082-B2
Application number	US-201615557014-A
Country	US
Kind code	B2
Filing date	Mar 7, 2016
Priority date	Mar 10, 2015
Publication date	Jul 24, 2018
Grant date	Jul 24, 2018

Abstract

A solid catalyst component for the polymerization of olefins made from or containing Mg, Ti, halogen and an electron donor of formula (I) or (II):

When activated with an aluminum alkyl and optionally an external electron donor, the solid catalyst component can give high activity and stereospecificity in the polymerization of olefins.

First claim

What is claimed is:

1. A solid catalyst component for the polymerization of olefins comprising:
(i) Mg,
(ii) Ti,
(iii) halogen,
(iv) and an electron donor of formula (I) or (II)

where:
R 1 and R 3 are selected from C 1 -C 15 hydrocarbon groups, optionally containing a heteroatom selected from the group consisting of halogens, P, S, N and O;
R 5 -R 7 groups are independently hydrogen or a C 1 -C 20 hydrocarbon radicals, optionally substituted with heteroatoms selected from the group consisting of halogens, P, S, N, O and Si, which are optionally fused together to form one or more cycles;
R 8 to R 11 , independently, are selected from the group consisting of hydrogen, halogens and C 1 -C 15 hydrocarbon groups optionally containing heteroatoms selected from the group consisting of halogens, P, S, N, O and Si;
R 12 to R 13 groups, which are the same or different from each other, are hydrogen or R 1 groups which are optionally fused together to form one or more cycles; and
n is an integer from 0 to 2.

2. The catalyst component according to claim 1 , wherein the electron donor of formula (I) has at least one of R 5 -R 7 group as a C 1 -C 20 hydrocarbon radical.

3. The catalyst component according to claim 2 , wherein at least one of R 5 -R 7 groups is a C 1 -C 10 alkyl group.

4. The catalyst component according to claim 3 , wherein both R 5 and R 7 are C 1 -C 10 alkyl groups.

5. The catalyst component according to claim 1 , wherein at least one of R 8 to R 11 groups is different from hydrogen.

6. The catalyst component according to claim 5 , wherein the aromatic ring is substituted in position 3, in position 5, or in both positions with a C 1 -C 5 alkyl group.

7. The catalyst component according to claim 6 , wherein the alkyl group in position 5 is a secondary or tertiary alkyl group.

8. The catalyst component according to claim 1 , wherein n is 1.

9. The catalyst component according to claim 8 , wherein both R 12 and R 13 are hydrogen.

10. The catalyst component according to claim 1 , wherein R 1 and R 3 groups are independently selected from the group consisting of C 1 -C 15 alkyl groups, C 6 -C 14 aryl groups, C 3 -C 15 cycloalkyl groups, and C 7 -C 15 arylalkyl or alkylaryl groups.

11. The catalyst component according to claim 10 , wherein R 1 and R 3 groups are independently selected from the group consisting of C 1 -C 5 alkyl groups.

12. The catalyst component according to claim 11 , wherein R 1 and R 3 groups are ethyl.

13. A catalyst for the polymerization of olefins comprising:
(a) a product of a reaction between:
(i) a solid catalyst component comprising:
(A) Mg,
(B) TI,
(C) halogen, and
(D) an electron donor of formula (I) or (II)

where:
R 1 and R 3 are selected from C 1 -C 15 hydrocarbon groups, optionally containing a heteroatom selected from the group consisting of halogens, P, S, N and O;
R 5 -R 7 groups are independently hydrogen or a C 1 -C 20 hydrocarbon radicals, optionally containing heteroatoms selected from the group consisting of halogens, P, S, N, O and Si, and are optionally fused together to form one or more cycles;
R 8 to R 11 , independently, are selected from the group consisting of hydrogen, halogens and C 1 -C 15 hydrocarbon groups optionally containing heteroatoms selected from the group consisting of halogens, P, S, N, O and Si;
R 12 to R 13 groups, which are the same or different from each other, are hydrogen or R 1 groups which are optionally fused together to form one or more cycles and

n is an integer from 0 to 2;
(ii) an alkylaluminum compound and optionally,
(iii) an external electron donor compound.

14. The catalyst according to claim 13 further comprising an external electron donor compound.

15. A process for the polymerization or copolymerization of an olefins comprising:
(a) polymerizing an olefin CH 2 ═CHR, wherein R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, in the presence of a catalyst system comprising:
(A) a product of a reaction between:
i. a solid catalyst component comprising:
(1) Mg,
(2) Ti,
(3) halogen, and
(4) an electron donor of formula (I) or (II)

where:
R 1 and R 3 are selected from C 1 -C 15 hydrocarbon groups, optionally containing a heteroatom selected from the group consisting of halogens, P, S, N and O;
R 5 -R 7 groups are independently hydrogen or a C 1 -C 20 hydrocarbon radicals, optionally containing heteroatoms selected from the group consisting of halogens, P, S, N, O and Si, and are optionally fused together to form one or more cycles;
R 8 to R 11 , independently, are selected from the group consisting of hydrogen, halogens and C 1 -C 15 hydrocarbon groups optionally substituted with heteroatoms selected from the group consisting of halogens, P, S, N, O and Si;

R 12 to R 13 groups, which are the same or different from each other, are hydrogen or R 1 groups which are optionally fused together to form one or more cycles and
n is an integer from 0 to 2;
ii. an alkylaluminum compound; and
iii. optionally an external donor compound.

Assignees

• Basell Poliolefine Italia Srl

Inventors

• Mignogna Alessandro
• Morini Giampiero

Classifications

• C08F4/649

  organic · CPC title

• C08F10/06

  Propene · CPC title

• C08F4/654

  with magnesium or compounds thereof · CPC title

• C08F4/6495

  containing nitrogen · CPC title

• C08F110/06 Primary

  Propene · CPC title