Light absorptive compound, polymer composition containing the compound, polymer film, and cured layer

Patent metadata

Field	Value
Publication number	US-10029982-B2
Application number	US-201615390965-A
Country	US
Kind code	B2
Filing date	Dec 27, 2016
Priority date	Dec 28, 2015
Publication date	Jul 24, 2018
Grant date	Jul 24, 2018

Abstract

The object of the present invention is to provide a light absorptive compound which is capable of selectively absorbing light around a wavelength of 400 nm, and is excellent in solubility in various solvents and/or affinity with hydrophobic substances. Also, the object of the present invention is to provide an optical film containing such a light absorptive compound, and a cured layer. A compound represented by the following formula (I):

First claim

What is claimed is:

1. A compound represented by formula (I) below:

wherein in the formula (I):
A denotes a methylene group, a secondary amino group, an oxygen atom or a sulfur atom,
R 1 denotes a hydrogen atom or an alkyl group with a carbon number of 1 to 10; and when the alkyl group has at least one methylene group, at least one of the methylene groups is optionally substituted with an oxygen atom or a sulfur atom,
R 2 and R 3 independently denote a hydrogen atom or an alkyl group with a carbon number of 1 to 12,
R 4 denotes an alkyl group with a carbon number of 3 to 50 or an alkyl group with a carbon number of 3 to 50 having at least one methylene group, wherein at least one of the methylene groups is substituted with an oxygen atom, and a substituent may be bonded to a carbon atom in the alkyl group,
X 1 denotes an electron-withdrawing group,
Y 1 denotes —CO—, —COO—, —OCO—, —O—, —S—, —NR 5 —,—NR 6 CO—or —CONR 7 —, and R 5 , R 6 and R 7 independently denote a hydrogen atom, an alkyl group with a carbon number of 1 to 6 or a phenyl group.

2. The compound according to claim 1 , wherein R 4 in the formula (I) is an alkyl group with a carbon number of 3 to 12 having a branched structure.

3. The compound according to claim 1 , wherein the compound represented by the formula (I) is represented by formula (I-I) below:

wherein in formula (I-I):
R 4-1 denotes an alkyl group with a carbon number of 1 to 6,
n denotes an integer of 1 to 10, and
A, R 1 , R 2 and R 3 are the same as in the formula (I).

4. The compound according to claim 3 , wherein the compound represented by the formula (I-I) is represented by formula (I-II) below:

wherein in formula (I-II): R 4-1 and n are the same as in the formula (I-I).

5. A polymer composition comprising the compound according to claim 1 and a polymer.

6. The polymer composition according to claim 5 , wherein the polymer is at least one kind selected from the group consisting of poly(meth)acrylate, polyurethane, polyester, polycarbonate, polycycloolefin and triacetyl cellulose.

7. The polymer composition according to claim 5 , wherein the polymer is a copolymer which has as a constitutional unit a (meth)acrylate monomer (A-1) represented by formula (A-1) below:

wherein in formula (A-1):
R p denotes a hydrogen atom or a methyl group,
R q denotes an alkyl group or an aralkyl group with a carbon number of 1 to 20, wherein a hydrogen atom constituting the alkyl group or the aralkyl group is optionally substituted with —O—(C 2 H 4 O)n—R r , n denotes an integer of 0 to 4, and R r denotes an alkyl group with a carbon number of 1 to 12 or an aryl group with a carbon number of 1 to 12and a (meth)acrylic monomer (A-2) having a hydroxyl group, and which is poly(meth)acrylate with a weight-average molecular weight of 500000 to 2000000; and
the polymer composition contains 0.01 to 5 parts by mass of a crosslinking agent and 0.01 to 10 parts by mass of the compound of formula (I) with respect to 100 parts by mass of the polymer.

8. A polymer film comprising the polymer composition according to claim 5 .

9. A pressure-sensitive adhesive comprising the polymer composition according to claim 7 .

10. A photopolymerizable composition comprising a monomer having a photopolymerizable functional group, a photopolymerization initiator, a solvent and the compound according to claim 1 .

11. A cured layer comprising a cured material of the photopolymerizable composition according to claim 10 , which satisfies formulae (1) to (3) below:
0nm≤Re<10 nm  (1)

A (420)/ A (400)≤0.4  (2)

Hz≤3  (3)

wherein:
Re in formula (1) denotes an in-plane retardation value at a wavelength of 550 nm,
A(420) in the formula (2) denotes absorbance at 420 nm and A(400) denotes absorbance at 400 nm, and
Hz in the formula (3) denotes turbidity.

12. An image display device comprising the polymer film according to claim 8 .

13. An image display device comprising the pressure-sensitive adhesive according to claim 9 .

14. An image display device comprising the cured layer according to claim 11 .

Assignees

• Sumitomo Chemical Co

Inventors

• Miyazaki Katsuaki
• Okawa Haruki
• Fujimoto Daichi
• Yoshioka Shinnosuke

Classifications

• G02B5/3033

  in the form of a thin sheet or foil, e.g. Polaroid · CPC title

• C09J175/04

  Polyurethanes · CPC title

• C08K5/005

  Stabilisers against oxidation, heat, light, ozone · CPC title

• G02B1/16

  having an anti-static effect, e.g. electrically conducting coatings · CPC title

• C09J133/066

  containing -OH groups · CPC title