System and method for ion exchange regeneration

Patent metadata

Field	Value
Publication number	US-10029249-B1
Application number	US-201514808787-A
Country	US
Kind code	B1
Filing date	Jul 24, 2015
Priority date	Jul 25, 2014
Publication date	Jul 24, 2018
Grant date	Jul 24, 2018

Abstract

Systems and methods for ion exchange regeneration for resins onsite at an industrial facility are disclosed. The resins can be boron selective resins and the systems and methods can utilize onsite regeneration, recycling of certain effluent streams, and/or treated water as a main water source for regeneration.

First claim

What is claimed is:

1. A method of regenerating a boron-selective ion exchange resin, the method comprising:
introducing an acid regeneration stream into a reactor vessel having the boron-selective ion exchange resin disposed therein and reacting the acid regeneration stream with the boron-selective ion exchange resin, wherein the acid regeneration stream comprises one or more of HCl, HNO 3 and acetic acid;
withdrawing the acid regeneration stream from the reactor vessel as an acid regeneration effluent stream, wherein the acid regeneration effluent stream comprises boron released from the ion exchange resin;
introducing an acid rinse stream into the reactor vessel and contacting the acid rinse stream with the boron-selective ion exchange resin, wherein the acid regeneration stream comprises treated water;
withdrawing the acid rinse stream from the reactor vessel as an acid rinse effluent stream;
introducing a caustic regeneration stream into the reactor vessel and reacting the caustic regeneration stream with the boron-selective ion exchange resin, wherein the caustic regeneration stream comprises one or more of NaOH and KOH;
withdrawing the caustic regeneration stream from the reactor vessel as a caustic regeneration effluent stream;
introducing a caustic rinse stream into the reactor vessel and contacting the caustic rinse stream with the boron-selective ion exchange resin, wherein the caustic regeneration stream comprises treated water;
withdrawing the caustic rinse stream from the reactor vessel as a caustic rinse effluent stream;
introducing a surfactant rinse stream into the reactor vessel and contacting the surfactant rinse stream with the boron-selective ion exchange resin, wherein treated water is added to the surfactant rinse stream prior to introducing the surfactant rinse stream into the reactor vessel at any point in the regeneration process; and
withdrawing the surfactant rinse stream from the reactor vessel as a surfactant rinse effluent stream;
wherein the treated water is obtained by subjecting one or more of oilfield produced water and flowback water to a pretreatment comprising one or more of electrocoagulation, carbon filtration and resin bed treatment before being added to the acid rinse stream, the surfactant rinse stream or the caustic rinse stream, such that after the pretreatment, the treated water has a boron content greater than 0 mg/L and less than or equal to 10 mg/L.

2. The method of claim 1 , further comprising:
prior to introducing the acid regeneration stream into the reactor vessel, introducing a backwash stream into the reactor vessel and contacting the backwash stream with the boron-selective ion exchange resin;
backwashing the boron-selective ion exchange resin; and
withdrawing the backwash stream from the reactor vessel as a backwash effluent stream.

3. The method of claim 2 , wherein treated water is utilized as the backwash stream, and wherein the treated water has a boron content greater than 0 mg/L and less than or equal to 10 mg/L.

4. The method of claim 3 , wherein the treated water has a boron content greater than 1 mg/L and less than or equal to 10 mg/L.

5. The method of claim 3 , wherein the treated water has a boron content greater than or equal to 5 mg/L and less than or equal to 10 mg/L.

6. The method of claim 1 , further comprising
adding treated water to the acid rinse effluent stream to produce an acid rinse recycle stream, wherein the treated water has a boron content greater than 0 mg/L and less than or equal to 10 mg/L; and
introducing the acid rinse recycle stream into the reactor vessel.

7. The method of claim 6 , wherein the introducing of the acid rinse recycle stream into the reactor vessel comprises introducing the acid rinse recycle stream into the acid rinse stream prior to the acid rinse stream being introduced into the reactor vessel.

8. The method of claim 6 , wherein the adding of treated water to the acid rinse effluent stream comprises mixing treated water with the acid rinse effluent stream in a mixing vessel.

9. The method of claim 6 , wherein the treated water has a boron content greater than 1 mg/L and less than or equal to 10 mg/L.

10. The method of claim 6 , wherein the treated water has a boron content greater than or equal to 5 mg/L and less than or equal to 10 mg/L.

11. The method of claim 1 , further comprising
adding the treated water to the acid regeneration stream prior to introducing the acid regeneration stream into the reactor vessel.

12. The method of claim 1 , wherein the acid regeneration stream introduced into the reactor vessel comprises an HCl solution in the range from 2-10%.

13. The method of claim 12 , wherein the acid regeneration stream introduced into the reactor vessel comprises an HCl solution of about 5%.

14. The method of claim 1 , wherein the treated water has a boron content greater than 1 mg/L and less than or equal to 10 mg/L.

15. The method of claim 1 , wherein the treated water has a boron content greater than or equal to 5 mg/L and less than or equal to 10 mg/L.

Assignees

• Baker Hughes A Ge Co Llc

Inventors

• Vittur Brandon
• Matherly Ronald
• Cao Jiasheng

Classifications

• C02F2101/108

  Boron compounds · CPC title

• B01J49/60 Primary

  Cleaning or rinsing ion-exchange beds · CPC title

• C02F1/42 Primary

  by ion-exchange (ion-exchange in general B01J) · CPC title

• C02F2303/16

  Regeneration of sorbents, filters · CPC title

• B01J49/0078 Primary

  Operations & Transport · mapped topic