Method for producing fuel cell electrode catalyst

Patent metadata

Field	Value
Publication number	US-10026968-B2
Application number	US-201214000569-A
Country	US
Kind code	B2
Filing date	Jan 4, 2012
Priority date	Feb 21, 2011
Publication date	Jul 17, 2018
Grant date	Jul 17, 2018

Abstract

A method for producing a fuel cell electrode catalyst, including a step (I) of bringing an aqueous solution of a transition metal compound (1) into contact with ammonia and/or ammonia water to generate a precipitate (A) containing an atom of the transition metal, a step (II) of mixing at least the precipitate (A), an organic compound (B), and a liquid medium (C) to obtain a catalyst precursor liquid, and a step (IV) of subjecting the solid in the catalyst precursor liquid to heat treatment at a temperature of 500 to 1200° C. to obtain an electrode catalyst; a portion or the entirety of the transition metal compound (1) being a compound containing a transition metal element of group 4 or group 5 of the periodic table; and the organic compound (B) being at least one selected from sugars and the like.

First claim

The invention claimed is:

1. A method for producing a fuel cell electrode catalyst, comprising:
a step (I) of bringing an aqueous solution of a transition metal compound (1) into contact with ammonia and/or ammonia water to generate a precipitate (A) containing an atom of the transition metal,
a step (II) of adding the precipitate (A) to an organic compound (B) and a liquid medium (C), and mixing them to obtain a catalyst precursor, and
a step (IV) of subjecting the catalyst precursor to heat treatment at a temperature of 500 to 1200° C. to obtain an electrode catalyst;
a portion or the entirety of the transition metal compound (1) being a compound containing, as a transition metal element, at least one transition metal element M1 selected from elements of group 4 and group 5 of the periodic table; and
the organic compound (B) being at least one selected from sugars, amino sugars, glycosaminoglycans, polyvinyl alcohols, polyalkylene glycols, polyesters, nitrogen-containing polymer compounds, nitrile group-containing compounds, amino acids, ascorbic acid and stearic acid.

2. The method for producing a fuel cell electrode catalyst according to claim 1 , further comprising a step (III) of removing the liquid medium (C) from the catalyst precursor before the step (IV).

3. The method for producing a fuel cell electrode catalyst according to claim 1 , wherein the transition metal element M1 is at least one selected from titanium, zirconium, niobium, and tantalum.

4. The method for producing a fuel cell electrode catalyst according to claim 1 , wherein the transition metal compound (1) is at least one selected from the group consisting of metal halides, metal sulfates, metal alkoxides, metal acetates, metal phosphates, metal nitrates, metal organic acid salts, metal acid halides, metal perhalates, metal hypohalites, and metal complexes.

5. The method for producing a fuel cell electrode catalyst according to claim 1 , further comprising mixing a compound containing, as a transition metal element, at least one transition metal element M2 selected from iron, nickel, chromium, cobalt, and manganese, in the step (II).

6. A method for producing a fuel cell electrode catalyst layer, comprising a step of producing a fuel cell electrode catalyst by the method according to claim 1 , and a step of forming a fuel cell electrode catalyst layer using a catalyst layer formation material comprising the fuel cell electrode catalyst.

7. A method for producing a fuel cell electrode comprising a fuel cell electrode catalyst layer and a porous support layer, the method comprising a step of producing a fuel cell electrode catalyst layer by the method according to claim 6 , and a step of forming the fuel cell electrode catalyst layer on a surface of the porous support layer.

8. A method for producing a membrane electrode assembly comprising a cathode, an anode, and an electrolyte membrane placed between the cathode and the anode, the method comprising a step of producing a fuel cell electrode by the method according to claim 7 , and a step of placing the cathode, the electrolyte membrane, and the anode to produce a membrane electrode assembly while using the fuel cell electrode as at least one of the cathode and the anode.

9. A method for producing a fuel cell, comprising a step of producing a membrane electrode assembly by the method according to claim 8 , and a step of producing a fuel cell using the membrane electrode assembly.

10. The method for producing a fuel cell according to claim 9 , wherein the fuel cell is a polymer electrolyte fuel cell.

Assignees

• Horikita Masaki
• Lee Kunchan
• Wakizaka Yasuaki
• Sato Takashi
• Showa Denko Kk

Inventors

• Horikita Masaki
• Lee Kunchan
• Wakizaka Yasuaki
• Sato Takashi

Classifications

• H01M4/9083

  on carbon or graphite · CPC title

• H01M4/8882 Primary

  Heat treatment, e.g. drying, baking · CPC title

• H01M4/9016

  Oxides, hydroxides or oxygenated metallic salts · CPC title

• H01M4/8825

  Methods for deposition of the catalytic active composition · CPC title

• H01M4/9008 Primary

  Organic or organo-metallic compounds · CPC title