Cathode active material coating solution for secondary battery and method of manufacturing the same

Patent metadata

Field	Value
Publication number	US-10026960-B2
Application number	US-201414419508-A
Country	US
Kind code	B2
Filing date	Sep 30, 2014
Priority date	Sep 30, 2013
Publication date	Jul 17, 2018
Grant date	Jul 17, 2018

Abstract

Provided are a method of manufacturing a cathode active material coating solution for a secondary battery including preparing a mixed solution by dispersing a metal precursor and a chelating agent in a glycol-based solvent, performing primary heating on the mixed solution, and performing secondary heating on the mixed solution, and a cathode active material coating solution for a secondary battery manufactured by the above method.

First claim

The invention claimed is:

1. A method of manufacturing a cathode active material coating solution for a secondary battery, the method consisting of:
preparing a mixed solution by dispersing a metal precursor, a chelating agent, and an additive in a glycol-based solvent,
wherein the metal precursor is selected from the group consisting of acetate, hydroxide, nitrate, nitride, sulfate, sulfide, alkoxide, and halide, which include at least one metal selected form the group consisting of magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), yttrium (Y), titanium (Ti), zirconium (Zr), vanadium (V), niobium (Nb), tantalum (Ta), chromium (Cr), molybdenum (Mo), tungsten (W), manganese (Mn), iron (Fe), cobalt (Co), iridium (Ir), nickel (Ni), zinc (Zn), aluminum (Al), gallium (Ga), indium (In), silicon (Si), germanium (Ge), tin (Sn), lanthanum (La), cerium (Ce), and a mixture of two or more thereof; and
wherein the additive is selected from the group consisting of formaldehyde, acetaldehyde and glycolic acid, and a mixture of two or more thereof;
performing a primary heating on the mixed solution to form a primary heated solution; and

performing a secondary heating on the heated solution to form a secondary heated solution to form the cathode active material coating solution,
wherein the coating solution is a metal glycolate coating solution comprising at least one metal organo-compound selected from the group consisting of compounds represented by Chemical Formulae 1 to 3 in which a metal desorbed from a metal precursor, a glycol-based solvent, and a chelating agent are combined:
M(C 2 H 5 O 2 ) n   [Chemical Formula 1]

M(C 6 H (8-n) O 7 )  [Chemical Formula 2]

M(C 6 H (8-n) O 7 )(C 2 H 5 O 2 )  [Chemical Formula 3]

wherein M, as the metal desorbed from the metal precursor, represents at least one metal selected from the group consisting of magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), yttrium (Y), titanium (Ti), zirconium (Zr), vanadium (V), niobium (Nb), tantalum (Ta), chromium (Cr), molybdenum (Mo), tungsten (W), manganese (Mn), iron (Fe), cobalt (Co), iridium (Ir), nickel (Ni), zinc (Zn), aluminum (Al), gallium (Ga), indium (In), silicon (Si), germanium (Ge), tin (Sn), lanthanum (La), and cerium (Ce), and n is an integer between 1 and 4.

2. The method of claim 1 , wherein the glycol-based solvent comprises a single material selected from the group consisting of ethylene glycol, propylene glycol, diethylene glycol, triethylene glycol, and polyethylene glycol, or a mixture of two or more thereof.

3. The method of claim 1 , wherein the metal precursor is aluminum acetate, zirconium nitride, or manganese acetate.

4. The method of claim 1 , wherein the chelating agent comprises a single material selected from the group consisting of citric acid, ethylenediaminetetraacetic acid (EDTA), oxalic acid, and gluconic acid, or a mixture of two or more thereof.

5. The method of claim 1 , wherein a content ratio (parts by weight) of the metal precursor:the glycol-based solvent:the chelating agent is in a range of 1:1:0.1 to 1:500:20.

6. The method of claim 1 , wherein the additive is included in an amount of 0.1 parts by weight to 20 parts by weight based on total 1 part by weight of the metal precursor.

7. The method of claim 1 , wherein the performing of the primary heating is performed in a temperature range of 100° C. to 300° C. for 1 hour to 48 hours.

8. The method of claim 7 , wherein the performing of the primary heating is performed in a temperature range of 110° C. to 230° C. for 5 hours to 20 hours.

9. The method of claim 1 , wherein the performing of the secondary heating is performed in a temperature range of 150° C. to 300° C. for 1 hour to 5 hours.

10. The method of claim 9 , wherein the performing of the secondary heating is performed in a temperature range of 170° C. to 250° C. for 1 hour to 5 hours.

11. The method of claim 1 , wherein the performing of the primary heating and the performing of the secondary heating are performed in an inert gas atmosphere.

12. The method of claim 1 , wherein the primary heated solution has a viscosity of about 1 cps to about 1,000 cps.

13. The method of claim 1 , wherein the secondary heated solution has a viscosity of 1 cps to 15,000 cps.

14. A method of manufacturing a cathode active material coating solution for a secondary battery, the method consisting of:
preparing a mixed solution by dispersing a metal precursor, a chelating agent, and optionally an additive in a glycol-based solvent,
wherein the metal precursor is selected from the group consisting of acetate, hydroxide, nitrate, nitride, sulfate, sulfide, alkoxide, and halide, which include at least one metal selected form the group consisting of magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), yttrium (Y), titanium (Ti), zirconium (Zr), vanadium (V), niobium (Nb), tantalum (Ta), chromium (Cr), molybdenum (Mo), tungsten (W), manganese (Mn), iron (Fe), cobalt (Co), iridium (Ir), nickel (Ni), zinc (Zn), aluminum (Al), gallium (Ga), indium (In), silicon (Si), germanium (Ge), tin (Sn), lanthanum (La), cerium (Ce), and a mixture of two or more thereof; and
wherein the additive is selected from the group consisting of formaldehyde, acetaldehyde and glycolic acid, and a mixture of two or more thereof;
performing a primary heating on the mixed solution to form a primary heated solution; and
performing a secondary heating on the heated solution to form a secondary heated solution to form the cathode active material coating solution,
wherein the coating solution is a metal glycolate coating solution comprising at least one metal organo-compound selected from the group consisting of compounds represented by Chemical Formulae 1 to 3 in which a metal desorbed from a metal precursor, a glycol-based solvent, and a chelating agent are combined:
M(C 2 H 5 O 2 ) n   [Chemical Formula 1]

M(C 6 H (8-n) O 7 )  [Chemical Formula 2]

M(C 6 H (8-n) O 7 )(C 2 H 5 O 2 )  [Chemical Formula 3]

wherein M, as the metal desorbed from the metal precursor, represents at least one metal selected from the group consisting of magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), yttrium (Y), titanium (Ti), zirconium (Zr), vanadium (V), niobium (Nb), tantalum (Ta), chromium (Cr), molybdenum (Mo), tungsten (W), manganese (Mn), iron (Fe), cobalt (Co), iridium (Ir), nickel (Ni), zinc (Zn), aluminum (Al), gallium (Ga), indium (In), silicon (Si), germanium (Ge), tin (Sn), lanthanum (La), and cerium (Ce), and n is an integer between 1 and 4.

15. The method of claim 14 , wherein the glycol-based solvent comprises a single material selected from the group consisting of ethylene glycol, propylene glycol, diethylene glycol, triethylene glycol, and polyethylene glycol, or a mixture of two or more thereof.

16. The method of claim 14 , wherein the metal precursor is aluminum acetate, zirconium nitride, or manganese acetate.

17. The method of claim 14 , wherein the chelating agent comprises a single material selected from the group consisting of citric acid, ethylenediaminetetraacetic acid (EDTA), oxalic acid, and gluconic acid, or a mixture of two or more thereof.

18. The method of claim 14 , wherein a content ratio (parts by weight) of the metal precursor:the glycol-based solvent:the chelating agent is in a range of 1:1:0.1 to 1:500:20.

Assignees

• Lg Chemical Ltd

Inventors

• Lee Dong Kwon
• Cho Seung Beom
• Nho Jun Seok
• Jang Wook

Classifications

• H01M4/62

  Selection of inactive substances as ingredients for active masses, e.g. binders, fillers · CPC title

• H01M4/525 Primary

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/366

  as layered products · CPC title

• H01M4/485

  of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title