Quantum dot electronic device and quantum dot transfer printing method

Patent metadata

Field	Value
Publication number	US-10026913-B2
Application number	US-201515519453-A
Country	US
Kind code	B2
Filing date	Jul 22, 2015
Priority date	Nov 28, 2014
Publication date	Jul 17, 2018
Grant date	Jul 17, 2018

Abstract

A quantum dot electronic device comprises a first encapsulation layer, a first electrode disposed on the first encapsulation layer, a quantum dot pattern disposed on the first electrode, a second electrode disposed on the quantum dot pattern and a second encapsulation layer disposed on the second electrode. The quantum dot pattern may be formed by an intaglio transfer printing method, where the method comprises forming a quantum dot layer on a donor substrate, picking up the quantum dot layer using a stamp, putting the quantum dot layer into contact with an intaglio substrate using the stamp and separating the stamp from the intaglio substrate. Using the quantum dot transfer printing method, a subminiature quantum dot pattern can be transferred at a high transfer rate. Accordingly, a highly integrated quantum dot electronic device exhibiting excellent performance and a high integrated quantum dot light emitting device with an ultrathin film can be realized.

First claim

The invention claimed is:

1. A quantum dot electronic device comprising:
a first encapsulation layer;
a first electrode disposed on the first encapsulation layer;
a quantum dot pattern disposed on the first electrode;
a second electrode disposed on the quantum dot pattern; and
a second encapsulation layer disposed on the second electrode,
wherein the quantum dot pattern is formed by an intaglio transfer printing method that comprises:
forming a quantum dot layer on a donor substrate;
picking up the quantum dot layer using a stamp;
putting the quantum dot layer into contact with an intaglio substrate using the stamp; and
separating the stamp from the intaglio substrate.

2. The quantum dot electronic device of claim 1 , further comprising:
a first charge transportation layer disposed between the first electrode and the quantum dot pattern; and
a second charge transportation layer disposed between the second electrode and the quantum dot pattern.

3. The quantum dot electronic device of claim 2 , wherein a sum of thickness of the first encapsulation layer, the first electrode, the first charge transportation layer, the quantum dot pattern, the second charge transportation layer, the second electrode and the second encapsulation layer is about 3 μm or less, and a sum of thickness of the first electrode, the first charge transportation layer, the quantum dot pattern, the second charge transportation layer and the second electrode is about 300 nm or less.

4. The quantum dot electronic device of claim 1 , wherein a surface energy of the intaglio substrate is greater than a surface energy of the stamp.

5. The quantum dot electronic device of claim 1 , wherein a transfer rate of the quantum dot pattern by the intaglio transfer printing method is about 99% or more in a size of about 5 μm×5 μm or more.

6. The quantum dot electronic device of claim 1 , wherein a size of the quantum dot pattern is about 20 μm×20 μm or less.

7. The quantum dot electronic device of claim 1 , wherein the quantum dot pattern comprises a red quantum dot pattern, a green quantum dot pattern and a blue quantum dot pattern, and the quantum dot electronic device is a wearable quantum dot light emitting device.

8. The quantum dot electronic device of claim 1 , wherein the quantum dot pattern is formed of a colloid nanocrystal substance comprising at least one of CdSe/ZnS quantum dot and CdSe/CdS/ZnS quantum dot.

9. The quantum dot electronic device of claim 1 , wherein the first encapsulation layer comprises a first protection layer and a first adhesion layer, the second encapsulation layer comprises a second protection layer and a second adhesion layer, the first and second protection layers are formed of poly (p-xylylene), and the first and second adhesion layers are formed of epoxy resin.

10. A quantum dot electronic device comprising:
a substrate; and
a quantum dot pattern disposed on the substrate,
wherein the quantum dot pattern is formed by an intaglio transfer printing method that comprises:
forming a quantum dot layer on a donor substrate;
picking up the quantum dot layer using a stamp;
putting the quantum dot layer into contact with an intaglio substrate using the stamp; and
separating the stamp from the intaglio substrate.

11. The quantum dot electronic device of claim 10 , wherein a surface energy of the intaglio substrate is greater than a surface energy of the stamp.

12. The quantum dot electronic device of claim 10 , wherein a transfer rate of the quantum dot pattern by the intaglio transfer printing method is about 99% or more in a size of about 5 μm×5 μm or more.

13. The quantum dot electronic device of claim 10 , wherein a size of the quantum dot pattern is about 20 μm×20 μm or less.

14. The quantum dot electronic device of claim 10 , wherein the quantum dot pattern comprises a red quantum dot pattern, a green quantum dot pattern and a blue quantum dot pattern, and the quantum dot electronic device is a quantum dot light emitting device.

15. The quantum dot electronic device of claim 10 , wherein the quantum dot pattern is formed of a colloid nanocrystal substance comprising at least one of CdSe/ZnS quantum dot and CdSe/CdS/ZnS quantum dot.

16. The quantum dot electronic device of claim 10 , wherein the substrate is a wearable substrate, a flexible substrate, a stretchable substrate or a plastic substrate.

17. The quantum dot electronic device of claim 1 , wherein the quantum dot pattern includes a plurality of patterns, each of the plurality of patterns occupying a portion of a predetermined shape, a size of the portion being equal to or greater than 99% of a size of the predetermined shape.

18. The quantum dot electronic device of claim 17 , wherein the size of the predetermined shape is in a range from 5 μm×5 μm to 230 μm×230 μm.

Assignees

• Seoul Nat Univ R&Db Foundation
• Inst Basic Science

Inventors

• Kim Daehyeong
• Hyeon Taeghwan
• Choi Moonkee
• Yang Jiwoong
• Kang Kwanghun

Classifications

• B41F9/00

  Rotary intaglio printing presses · CPC title

• Y10S977/824

  Group II-VI nonoxide compounds, e.g. CdxMnyTe · CPC title

• C09K11/883

  with zinc or cadmium · CPC title

• C09D11/037

  characterised by the pigment · CPC title

• Y10S977/95

  Electromagnetic energy · CPC title