Magnetic tape having controlled surface properties of the magnetic layer and method of manufacturing the same

Patent metadata

Field	Value
Publication number	US-10026434-B2
Application number	US-201615241297-A
Country	US
Kind code	B2
Filing date	Aug 19, 2016
Priority date	Aug 21, 2015
Publication date	Jul 17, 2018
Grant date	Jul 17, 2018

Abstract

The magnetic tape has a magnetic layer containing ferromagnetic powder and binder on a nonmagnetic support, wherein the centerline average surface roughness Ra as measured on the surface on the magnetic layer side of the magnetic tape is less than or equal to 1.8 nm, and the logarithmic decrement as determined by a pendulum viscoelasticity test on the surface on the magnetic layer side of the magnetic tape is less than or equal to 0.050.

First claim

What is claimed is:

1. A magnetic tape,
which comprises a magnetic layer comprising ferromagnetic powder and binder on a nonmagnetic support,
wherein the centerline average surface roughness Ra as measured on a surface on the magnetic layer side of the magnetic tape is less than or equal to 1.8 nm,
the logarithmic decrement as determined by a pendulum viscoelasticity test on the surface on the magnetic layer side of the magnetic tape is greater than or equal to 0.010 but less than or equal to 0.050, and
the logarithmic decrement is determined by the following method:
securing a measurement sample of the magnetic tape with the measurement surface, which is the surface on the magnetic layer side, facing upward on a substrate in a pendulum viscoelasticity tester;
disposing a columnar cylinder edge which is 4 mm in diameter and equipped with a pendulum 13 g in weight on the measurement surface of the measurement sample such that the long axis direction of the columnar cylinder edge runs parallel to the longitudinal direction of the measurement sample;
raising the surface temperature of the substrate on which the measurement sample has been positioned at a rate of less than or equal to 5° C./min up to 80° C.;
inducing initial oscillation of the pendulum;
monitoring the displacement of the pendulum while it is oscillating to obtain a displacement-time curve for a measurement interval of greater than or equal to 10 minutes; and
obtaining the logarithmic decrement Δ from the following equation:

Δ
=

ln
⁡

(

A
1

A
2

)

+

ln
⁡

(

A
2

A
3

)

+

…
⁢

⁢

ln
⁡

(

A
n

A

n
+
1

)

n

wherein the interval from one minimum displacement to the next minimum displacement is adopted as one wave period; the number of waves contained in the displacement-time curve during one measurement interval is denoted by n, the difference between the minimum displacement and the maximum displacement of the n th wave is denoted by An, and the logarithmic decrement is calculated using the difference between the next minimum displacement and maximum displacement of the n th wave (A n+1 in the above equation).

2. The magnetic tape according to claim 1 ,
wherein the centerline average surface roughness Ra is greater than or equal to 1.2 nm but less than or equal to 1.8 nm.

3. The magnetic tape according to claim 1 ,
wherein the magnetic layer comprises at least one type of nonmagnetic filler.

4. The magnetic tape according to claim 3 ,
wherein the nonmagnetic filler comprises colloidal particles.

5. The magnetic tape according to claim 1 ,
which comprises a nonmagnetic layer comprising nonmagnetic powder and binder between the nonmagnetic support and the magnetic layer.

6. A method of manufacturing a magnetic tape,
wherein the magnetic tape is a magnetic tape which comprises a magnetic layer comprising ferromagnetic powder and binder on a nonmagnetic support, wherein the centerline average surface roughness Ra as measured on a surface on the magnetic layer side of the magnetic tape is less than or equal to 1.8 nm, and the logarithmic decrement as determined by a pendulum viscoelasticity test on the surface on the magnetic layer side of the magnetic tape according to the method recited in claim 1 is greater than or equal to 0.010 but less than or equal to 0.050, and
the method of manufacturing the magnetic tape comprises forming a magnetic layer, with the forming of a magnetic layer comprising:
coating a magnetic layer-forming composition containing ferromagnetic powder, binder, a curing agent, and solvent on a nonmagnetic support, either directly or over another layer to form a coating layer;
heating and drying the coating layer by a heat treatment; and
curing the coating layer by subjecting the coating layer to a curing treatment;
with cooling the coating layer after the coating but before the heating and drying, and
burnishing the surface of the coating layer after the heating and drying but before the curing.

7. The method of manufacturing a magnetic tape according to claim 6 ,
wherein the cooling is conducted by placing the coating layer in a cooling atmosphere ranging from −10° C. to 0° C.

8. The method of manufacturing a magnetic tape according to claim 6 ,
wherein the solvent that is contained in the magnetic layer-forming composition comprises ketone solvent.

9. The method of manufacturing a magnetic tape according to claim 7 ,
wherein the solvent that is contained in the magnetic layer-forming composition comprises ketone solvent.

10. The method of manufacturing a magnetic tape according to claim 6 ,
wherein the curing agent is a thermosetting compound and the curing is conducted by a heat treatment.

11. The method of manufacturing a magnetic tape according to claim 10 ,
wherein the thermosetting compound is polyisocyanate.

12. The method of manufacturing a magnetic tape according to claim 6 ,
wherein surface-smoothing is conducted after the burnishing but before the curing.

13. The method of manufacturing a magnetic tape according to claim 6 ,
wherein the centerline average surface roughness Ra is greater than or equal to 1.2 nm but less than or equal to 1.8 nm.

14. The method of manufacturing a magnetic tape according to claim 6 ,
wherein the magnetic layer comprises at least one type of nonmagnetic filler.

15. The method of manufacturing a magnetic tape according to claim 14 ,
wherein the nonmagnetic filler comprises colloidal particles.

16. The method of manufacturing a magnetic tape according to claim 6 ,
wherein the magnetic tape comprises a nonmagnetic layer comprising nonmagnetic powder and binder between the nonmagnetic support and the magnetic layer.

Assignees

• Fujifilm Corp

Inventors

• Oyanagi Masahito
• Kasada Norihito
• Tada Toshio
• Sugiyama Takuro

Classifications

• G11B5/70

  on a base layer · CPC title

• G11B5/842

  Coating a support with a liquid magnetic dispersion · CPC title

• G11B5/7085

  non-magnetic abrasive particles · CPC title

• G11B5/78 Primary

  Tape carriers · CPC title

• G11B5/714

  characterised by the dimension of the magnetic particles · CPC title