Optical sensors for downhole tools and related systems and methods

Patent metadata

Field	Value
Publication number	US-10025000-B2
Application number	US-201615003578-A
Country	US
Kind code	B2
Filing date	Jan 21, 2016
Priority date	Jan 21, 2016
Publication date	Jul 17, 2018
Grant date	Jul 17, 2018

Abstract

A method of detecting at least one of an analyte or a condition of a fluid within a subterranean formation includes operably coupling a radiation source to at least one optical fiber coupled to a sensor having optically sensitive materials including at least one of chromophores, fluorophores, metal nanoparticles, or metal oxide nanoparticles dispersed within an optically transparent permeable matrix material. The sensor is contacted within a wellbore with a fluid and the fluid is passed through at least a portion of the sensor. Electromagnetic radiation is transmitted from the radiation source through at least one optical fiber to the sensor and at least one of an absorbance spectrum, an emission spectrum, a maximum absorption intensity, or a maximum emission intensity of electromagnetic radiation passing through the sensor after contacting at least some of the optically sensitive materials with the fluid is measured. Additional methods of determining a concentration of hydrogen sulfide in a fluid within a subterranean formation and related downhole optical sensor assemblies are disclosed.

First claim

What is claimed is:

1. A method of detecting at least one of an analyte or a condition of a downhole fluid within a subterranean formation, the method comprising:
operably coupling a radiation source to at least one optical fiber coupled to a sensor comprising optically sensitive materials including at least one of chromophores, fluorophores, metal nanoparticles, or metal oxide nanoparticles dispersed within an optically transparent matrix material permeable to a downhole fluid in a wellbore;
contacting the sensor within the wellbore with the downhole fluid and gases dissolved therein and passing both the downhole fluid and gases dissolved therein through at least a portion of the sensor comprising the optically sensitive materials;
transmitting electromagnetic radiation from the radiation source through the at least one optical fiber to the sensor; and
measuring at least one of an absorbance spectrum, an emission spectrum, a maximum absorption intensity, or a maximum emission intensity of electromagnetic radiation passing through the sensor after contacting at least some of the optically sensitive materials with the downhole fluid.

2. The method of claim 1 , wherein contacting the sensor within the wellbore with the downhole fluid and passing the downhole fluid through at least a portion of the sensor comprising the optically sensitive materials comprises one of physical absorbing an analyte within the downhole fluid to the optically sensitive materials or chemically reacting the optically sensitive materials with the analyte.

3. The method of claim 1 , wherein measuring at least one of an absorbance spectrum, an emission spectrum, a maximum absorption intensity, or a maximum emission intensity of electromagnetic radiation passing through the sensor comprises measuring a wavelength of maximum absorption intensity of the electromagnetic radiation passing through the sensor.

4. The method of claim 3 , further comprising:
selecting the optically sensitive materials to comprise chromophores; and
chemically reacting at least some of the chromophores within the sensor with an analyte within the downhole fluid.

5. The method of claim 1 , further comprising determining a concentration of hydrogen sulfide in the downhole fluid based on at least one of a measured absorbance spectrum, emission spectrum, maximum absorption intensity, or maximum emission intensity of the electromagnetic radiation passing through the sensor after contacting at least some of the optically sensitive materials with the downhole fluid.

6. The method of claim 1 , further comprising selecting the optically sensitive materials to comprise rhodamine B, copper nanoparticles, chloronitrobenzofurazan, or m-bromobiamine.

7. The method of claim 1 , further comprising selecting the optically sensitive materials to comprise nanoparticles of at least one of gold, silver, palladium, or platinum.

8. The method of claim 1 , further comprising selecting the optically sensitive materials to comprise at least one of zinc oxide, cadmium oxide, tungsten oxide, or combinations thereof.

9. The method of claim 1 , further comprising selecting the optically transparent permeable matrix material to comprise a porous glass.

10. The method of claim 1 , further comprising selecting the optically transparent permeable matrix material to comprise at least one of polyvinylidene chloride, a polyether, a polyacrylate, or a polysilicone.

11. A method of determining a concentration of hydrogen sulfide in a downhole fluid within a subterranean formation, the method comprising:
locating a sensor comprising optically sensitive materials comprising at least one of chromophores, fluorophores, and nanoparticles dispersed within a permeable matrix material permeable to a downhole fluid proximate at least one component of downhole equipment in a wellbore extending through one or more subterranean formations, the sensor operably coupled through at least one fiber optic cable to a radiation source configured to provide electromagnetic radiation to the sensor;
contacting the sensor with the downhole fluid and gases dissolved therein within at least one of the downhole equipment or the wellbore and passing both the downhole fluid and gases dissolved therein through at least a portion of the sensor comprising the optically sensitive materials;
transmitting electromagnetic radiation from the radiation source through the sensor and to a detector operably coupled to the at least one fiber optic cable; and
determining, with the detector, a change in an optical characteristic of at least one of the optically sensitive materials of the sensor responsive to contact of the sensor with hydrogen sulfide in the downhole fluid.

12. The method of claim 11 , further comprising selecting the optically sensitive materials to comprise nanoparticles of at least one of gold, silver, palladium, platinum, or copper dispersed within the permeable matrix material.

13. The method of claim 11 , further comprising selecting the optically sensitive materials to comprise metal oxide nanoparticles dispersed within the permeable matrix material.

14. The method of claim 13 , further comprising selecting the metal oxide nanoparticles to comprise at least one of zinc oxide, tungsten oxide, cadmium oxide, or iron oxides.

15. The method of claim 11 , further comprising selecting the optically sensitive materials to comprise rhodamine B, a copper (II) chromophore complex, copper nanoparticles, 2,6-dichlorophenolindophenol, chloronitrobenzofurazan, or m-bromobiamine.

16. The method of claim 11 , further comprising selecting the optically sensitive materials to comprise a material selected from the group consisting of p-azidophenylalanine, rhodamine, dansyl azide, and dicyanomethylenedihydrofuran.

17. A downhole optical sensor assembly, comprising:
a sensor operably coupled to at least one component of downhole equipment, the sensor including optically sensitive materials comprising one of chromophores, fluorophores, metal nanoparticles, or metal oxide nanoparticles disposed within an optically transparent matrix material permeable to a downhole fluid;
a radiation source coupled to the sensor through a fiber optic cable, the radiation source configured to generate electromagnetic radiation for transmission through at least one optical fiber of the fiber optic cable; and
a detector coupled to the sensor through a fiber optic cable, the detector configured to measure at least one of an absorbance spectrum, an emission spectrum, a maximum absorption intensity, or a maximum emission intensity of electromagnetic radiation passing through the sensor.

18. The downhole optical sensor of claim 17 , wherein the optically sensitive materials comprise nanoparticles of at least one of gold, silver, palladium, platinum, or copper as a result of both the downhole fluid and gases dissolved therein passing through at least a portion of the sensor comprising the optically sensitive materials.

19. The downhole optical sensor assembly of claim 17 , wherein the optically sensitive materials comprise:
at least one of rhodamine B, a copper (II) chromophore complex, copper nanoparticles, 2,6-dichlorophenolindophenol, chloronitrobenzofurazan, or m-bromobiamine; and
at least one of gold, silver, platinum, palladium, zinc oxide, cadmium oxide, or tungsten oxide.

20. The downhole optical sensor assembly of claim 17 , wherein the sensor comprises at least one chromophore, at least one fluorophore, and at least one metal nanoparticle.

Assignees

• Baker Hughes Inc

Inventors

• Monteiro Othon R
• Suresh Radhika

Classifications

• E21B49/0875

  determining specific fluid parameters · CPC title

• E21B49/08 Primary

  Obtaining fluid samples or testing fluids, in boreholes or wells · CPC title

• G01N33/24

  Earth materials (G01N33/42 takes precedence) · CPC title

• G01N2021/7786

  Fluorescence · CPC title

• G01N33/2841

  Gas in oils, e.g. hydrogen in insulating oils · CPC title