System and method for cryogenic purification of a feed stream comprising hydrogen, methane, nitrogen and argon

Patent metadata

Field	Value
Publication number	US-10024595-B2
Application number	US-201615271559-A
Country	US
Kind code	B2
Filing date	Sep 21, 2016
Priority date	Sep 21, 2016
Publication date	Jul 17, 2018
Grant date	Jul 17, 2018

Abstract

A system and method for cryogenic purification of a hydrogen, nitrogen, methane and argon containing feed stream to produce a methane free, hydrogen and nitrogen containing synthesis gas and a methane rich fuel gas, as well as to recover an argon product stream, excess hydrogen, and excess nitrogen is provided. The disclosed system and method are particularly useful as an integrated cryogenic purifier in an ammonia synthesis process in an ammonia plant. The excess nitrogen is a nitrogen stream substantially free of methane and hydrogen that can be used in other parts of the plant, recovered as a gaseous nitrogen product and/or liquefied to produce a liquid nitrogen product.

First claim

What is claimed is:

1. A method for purifying a stream comprising hydrogen, nitrogen, methane and argon to produce a hydrogen and nitrogen containing synthesis gas, a methane rich fuel gas, and at least one nitrogen product, the method comprising the steps of:
conditioning the pre-purified feed stream to a temperature near saturation at a pressure greater than about 300 psia;
directing the conditioned feed stream to a synthesis gas rectification column configured to produce an hydrogen and nitrogen enriched overhead vapor stream and a methane-rich condensed phase stream at the bottom of the synthesis gas rectification column;
vaporizing the methane-rich condensed phase stream to produce a vaporized methane-rich stream or a partially vaporized methane-rich stream;
directing the vaporized methane-rich stream or the partially vaporized methane-rich stream and a nitrogen reflux stream to a nitrogen rectification column configured to produce a nitrogen containing overhead vapor stream substantially free of methane, and a methane enriched liquid bottoms stream;
warming at least a portion of the nitrogen containing overhead vapor stream via indirect heat exchange with the feed stream to produce a warm gaseous nitrogen stream and directing the warm gaseous nitrogen stream to a nitrogen recovery system to produce the at least one nitrogen product;
warming the hydrogen and nitrogen enriched overhead vapor stream via indirect heat exchange with the feed stream to produce the hydrogen and nitrogen containing synthesis gas; and
further processing the methane enriched liquid bottoms stream to produce the methane rich fuel gas.

2. The method of claim 1 , wherein the step of conditioning further comprises one or more steps selected from the group of compression of the feed stream, turbo-expansion of the feed stream, isenthalpic expansion of the feed stream, cooling of the feed stream, and warming of the feed stream.

3. The method of claim 1 , further comprising the step of removing selected contaminants from the feed stream in an adsorption based pre-purifier.

4. The method of claim 1 , wherein the hydrogen to nitrogen ratio in the hydrogen and nitrogen containing synthesis gas stream is about 3:1.

5. The method of claim 1 , wherein the nitrogen rectification column operates at a pressure less than or equal to about 50 psia.

6. The method of claim 5 , wherein the nitrogen rectification column operates at a pressure less than or equal to about 25 psia.

7. The method of claim 5 , further comprising the step of pumping the methane rich fuel gas to re-pressurize it to a pressure greater than the pressure of the nitrogen rectification column.

8. The method of claim 5 , further comprising the step of compressing the methane rich fuel gas to re-pressurize it to a pressure greater than the pressure of the nitrogen rectification column.

9. The method of claim 1 , wherein the warm gaseous nitrogen stream contains hydrogen and the method further comprises directing a portion of the warm gaseous nitrogen stream to mix with into the hydrogen and nitrogen containing synthesis gas.

10. The method of claim 1 , wherein the step of further processing the methane enriched liquid bottoms stream further comprises the steps of:
cooling the methane enriched liquid bottoms stream;
expanding the cooled methane enriched liquid bottoms stream in an expansion valve to a pressure less than or equal to about 100 psia; and
directing the cooled, expanded methane enriched stream to a hydrogen stripping column configured to strip hydrogen from the methane enriched stream and produce a hydrogen free methane bottom stream and a hydrogen enriched gaseous overhead.

11. The method of claim 10 , wherein the step of further processing the methane enriched liquid bottoms stream further comprises the step of recycling the hydrogen enriched gaseous overhead from the hydrogen stripping column back to the feed stream.

12. The method of claim 10 , wherein the step of further processing the methane enriched liquid bottoms stream further comprises the steps of compressing the hydrogen enriched gaseous overhead and recycling the compressed hydrogen enriched gaseous overhead back to the feed stream.

13. The method of claim 10 , wherein the step of further processing the methane enriched liquid bottoms stream further comprises the steps of warming the hydrogen enriched gaseous overhead, compressing the warmed hydrogen enriched gaseous overhead, and recycling the warmed, compressed hydrogen enriched gaseous stream back to the feed stream.

14. The method of claim 1 , wherein the step of vaporizing the methane-rich condensed phase stream produces the partially vaporized methane-rich stream, and the method further comprises the steps of:
phase separating the partially vaporized hydrogen free methane-rich stream into a vapor portion and a liquid portion; and
warming the vapor portion and the liquid portion of the hydrogen free methane-rich stream via indirect heat exchange with the feed stream to produce the methane fuel gas.

15. The method of claim 1 , wherein the nitrogen recovery system is a nitrogen liquefaction system and at least a portion of the warm gaseous nitrogen stream is directed to the nitrogen liquefaction system to produce a liquid nitrogen product stream.

16. The method of claim 15 , wherein a portion of the liquid nitrogen stream is directed to the nitrogen rectification column as the reflux stream.

17. The method of claim 1 , further comprising the steps of:
extracting an argon enriched stream from an intermediate location of the nitrogen rectification column at a location that is substantially free of methane;
directing the argon enriched stream to an argon rectification column;
separating the argon enriched stream in the argon rectification column to produce an argon bottoms liquid stream and a nitrogen enriched overhead stream;
returning the a nitrogen enriched overhead stream to the nitrogen rectification column; and
removing the argon bottoms liquid stream from the argon rectification column to produce an argon product stream.

18. The method of claim 17 , wherein the nitrogen recovery system is a nitrogen liquefaction system and at least a portion of the warm gaseous nitrogen stream is directed to the nitrogen liquefaction system to produce a purified liquid nitrogen product stream or a purified gaseous nitrogen product stream or both.

Assignees

• Howard Henry E
• Praxair Technology Inc

Inventors

• Howard Henry E

Classifications

• F25J2230/08

  Cold compressor, i.e. suction of the gas at cryogenic temperature and generally without afterstage-cooler · CPC title

• F25J2210/04

  Mixing or blending of fluids with the feed stream · CPC title

• F25J2270/42

  Quasi-closed internal or closed external nitrogen refrigeration cycle · CPC title

• F25J2200/94

  Details relating to the withdrawal point · CPC title

• F25J2205/60

  using adsorption on solid adsorbents, e.g. by temperature-swing adsorption [TSA] at the hot or cold end · CPC title