Process and a dissolving pulp manufactured by the process

Patent metadata

Field	Value
Publication number	US-10023995-B2
Application number	US-201314403889-A
Country	US
Kind code	B2
Filing date	May 28, 2013
Priority date	May 28, 2012
Publication date	Jul 17, 2018
Grant date	Jul 17, 2018

Abstract

The invention relates to processes for manufacturing pulp and more specifically to improved processes for manufacturing dissolving pulp. The processes have primarily been developed to be used in connection with large scale kraft processes, i.e. they have been designed to be incorporated into a plant. A liquor derivable from the process and comprising xylan, lignin, alkali and water is also disclosed as well as a dissolving pulp produced by the process.

First claim

The invention claimed is:

1. A process for manufacturing dissolving pulp comprising the steps of:
a) selecting a wood based raw material, said wood based raw material having a xylan content of from 12 weight % or more;
b) adding a cooking liquor comprising white and/or black liquor to the wood based raw material;
c) digesting the wood based raw material composition obtained from step b) in a kraft cooking process;
d) oxygen delignifying the pulp obtained from step c);
e) adding industrial white liquor comprising Na 2 CO 3 , NaHS and NaOH to the pulp obtained from step d) wherein said pulp has a xylan content of 8 weight % or more and wherein the temperature is lowered and kept from 50° C. to 65° C. from 5 minutes to 15 minutes and wherein the alkali concentration in the liquid phase of the obtained pulp suspension is in the range of 70 g/l to 100 g/l; and
f) removing a major part of the alkali and dissolved xylan as a liquor flow from the pulp obtained from step e) by directly dewatering the pulp without dilution, wherein the removed liquor flow has the same xylan and alkali content as the liquid phase in step e); and
g) after step f) subjecting the dewatered pulp to washing and pressing in a washing press device 1-5 times.

2. The process according to claim 1 , wherein said white liquor added in step e) has a suspended solids content of 20 mg/l or less.

3. The process according to claim 1 , wherein said white liquor has a combined Na + and K + concentration of from 3 to 5 mol/l, OH concentration of from 2.25 to 3.5 mol/l, HS − concentration of from 0.2 to 1.0 mol/l, and a CO 3 2− concentration of from 0.10 to 0.60 mol/l.

4. The process according to claim 1 , wherein the pulp obtained from step g) is filtered in a wash filter.

5. The process according to claim 1 , wherein the temperature in step e) is 60° C. or lower.

6. The process according to claim 1 , wherein the alkali concentration in step e) is in the range of from 85 to 100 g/l.

7. The process according to claim 1 , wherein said process comprises a washing step between step d) and step e), said washing step comprising washing the pulp obtained from step d) in a washing device.

8. The process according to claim 1 , wherein xylan and alkali removed in step f) are recirculated as a liquor flow and used as an alkali source in step e) and/or wherein xylan and alkali are removed as a liquor flow and used as an alkali/xylan source in another process for manufacturing pulp.

9. The process according to claim 1 , wherein xylan and alkali removed in step f) are recirculated as a liquor flow and used as an alkali source in step d).

10. The process according to claim 9 , wherein said liquor flow is oxidized before being used in step d).

11. The process according to claim 8 , wherein the alkali concentration of said liquor flow is in the range of from 60 to 90 g/l without any supplementary addition of alkali.

12. The process according to claim 11 , wherein said liquor flow is used as an alkali source in another process for manufacturing pulp.

13. The process according to claim 1 , wherein said process comprises a step before step b), which step comprises activation of the wood based raw material by using steam until a P-factor of from 25 to 200 has been reached.

14. The process according to claim 1 , wherein said process comprises a step after step g), which step is a combined depolymerization and bleaching step.

15. The process according to claim 14 , wherein said combined depolymerization and bleaching step is performed by adding ozone, or by adding hypochlorite or by adding chlorine dioxide and sulfuric acid.

16. The process according to claim 14 , wherein said combined depolymerization and bleaching step is performed at a temperature of from 80 to 99° C. and at an effective acid charge of from 5 to 20 kg H 2 SO 4 /air dried tons.

17. The process according to claim 14 , wherein the obtained pulp after the combined bleaching and depolymerization step comprises 6 weight % or less xylan.

18. The process according to claim 1 , wherein 90% or more of the alkali and dissolved xylan is removed from the pulp obtained from step e) after steps f) and g) are both performed.

Assignees

• Soedra Skogsaegarna Ekonomisk Foerening
• Chemiefaser Lenzing Ag
• Soedra Cell Ab Ab

Inventors

• Bogren Johannes
• Parkås Jim
• Schild Gabriele
• Borgards Andrea

Classifications

• D21C11/0007

  Recovery of by-products, i.e. compounds other than those necessary for pulping, for multiple uses or not otherwise provided for (volatile compounds obtained by decomposition of spent liquors in order to regenerate them D21C11/125; compounds obtained by fractionating the liquors in order to regenerate them D21C11/0042) · CPC title

• D21C3/022

  in presence of S-containing compounds · CPC title

• D21C3/02 Primary

  with inorganic bases or alkaline reacting compounds, e.g. sulfate processes · CPC title

• D21C3/045

  in presence of O2 or O3 · CPC title

• C08H8/00

  Macromolecular compounds derived from lignocellulosic materials {(pretreatment thereof B27N)} · CPC title