Composition which is suitable for producing polyurethane foams and contains at least one HFO blowing agent

Patent metadata

Field	Value
Publication number	US-10023679-B2
Application number	US-201415103015-A
Country	US
Kind code	B2
Filing date	Dec 5, 2014
Priority date	Dec 19, 2013
Publication date	Jul 17, 2018
Grant date	Jul 17, 2018

Abstract

The present invention relates to compositions which are suitable for producing polyurethane foams and contain at least one polyol component, at least one blowing agent, a catalyst which catalyzes the formation of a urethane or isocyanurate bond, a silicon-containing foam stabilizer and optionally further additives and optionally an isocyanate component, characterized in that they contain at least one unsaturated halogenated hydrocarbon as blowing agent and additionally at least one surfactant TD which does not have a silicon atom and has an HLB of less than 10, where the proportion of the sum of the surfactants TD in the composition is from 0.05 to 20 parts by mass per 100 parts by mass of polyol components, a process for producing polyurethane and polyisocyanurate foams, in particular rigid foams, starting out from these polyol compositions, the use of the foams, in particular as insulation material, and also the insulation materials themselves.

First claim

The invention claimed is:

1. A composition which is suitable for producing polyurethane foams and contains at least one polyol component, at least one blowing agent, a catalyst which catalyzes the formation of a urethane or isocyanurate bond, a silicon-containing foam stabilizer and optionally further additives and optionally an isocyanate component, wherein the composition comprises at least one unsaturated halogenated hydrocarbon as blowing agent and at least one surfactant TD which does not have a silicon atom and has an HLB of less than 10, where the proportion of the sum of the surfactants TD in the composition is from 0.05 to 20 parts by mass per 100 parts by mass of polyol component and wherein the surfactant TD is selected from the group consisting of cocamide diethanolamide (DEA), isotridecanol or isonomanol.

2. The composition according to claim 1 , wherein at least one compound selected from the group consisting of trans-1,3,3,3-tetrafluoro-1-propene (HFO-1234zeE), 2,3,3,3-tetrafluoro-1-propene (HFO-1234yf), cis-1,1,1,4,4,4-hexafluoro-2-butene (HFO-1336mzzZ), trans-1,1,1,4,4,4-hexafluoro-2-butene (HFO-1336mzzE) and trans-1-chloro-3,3,3-trifluoro-1-propene (HFO-1233zd-E) is present as unsaturated halogenated hydrocarbon.

3. The composition according to claim 1 , wherein the composition comprises at least one isocyanate component.

4. A process for producing polyurethane or polyisocyanurate foams by reaction of a composition according to claim 1 .

5. A process for producing polyurethane or polyisocyanurate foams (polyurethane foams) by reaction of a composition according to claim 2 .

6. A process for producing polyurethane or polyisocyanurate foams (polyurethane foams) by reaction of a composition according to claim 3 .

7. The composition according to claim 1 , wherein the catalyst is selected from the group consisting of an amine, a tin compound, or potassium salt.

8. The composition according to claim 1 , wherein the catalyst is selected from the group consisting of triethylamine, dimethylcyclohexylamine, tetramethylethylenediamine, tetramethylhexanediamine, pentamethyldiethylenetriamine, pentamethyldipropylenetriamine, triethylenediamine, dimethylpiperazine, 1,2-dimethylimidazole, N-ethylmorpholine, tris(dimethylaminopropyl)hexahydro-1,3,5-triazine, dimethylaminoethanol, dimethylaminoethoxyethanol, bis(dimethylaminoethyl) ether, dibutyltin dilaurate, potassium acetate or potassium 2-ethylhexanoate.

9. The composition according to claim 1 , wherein the catalyst is selected from the group consisting of triethylamine, dimethylcyclohexylamine, tetramethylethylenediamine, tetramethylhexanediamine, pentamethyldiethylenetriamine, pentamethyldipropylenetriamine, triethylenediamine, dimethylpiperazine, 1,2-dimethylimidazole, N-ethylmorpholine, tris(dimethylaminopropyl)hexahydro-1,3,5-triazine, dimethylaminoethanol, dimethylaminoethoxyethanol or bis(dimethylaminoethyl) ether.

10. The composition according to claim 1 , wherein the catalyst comprises dimethylcyclohexylamine.

11. The composition according to claim 1 , wherein the catalyst comprises a mixture of dimethylcyclohexylamine and pentamethyldiethylenetriamine.

12. The composition according to claim 1 , wherein the range of the catalyst is from 0.05 to 10 parts by mass based on 100 parts by mass of polyol (pphp).

13. The composition according to claim 1 , wherein the range of the catalyst is from 0.05 to 5 parts by mass based on 100 parts by mass of polyol (pphp).

14. The composition according to claim 1 , wherein the surfactant TD is selected from the group consisting of cocamide diethanolamide (DEA) or isotridecanol.

Assignees

• Evonik Degussa Gmbh

Inventors

• Klostermann Michael
• Venzmer Joachim
• Eilbracht Christian
• Glos Martin
• Schiller Carsten

Classifications

• C08G18/18

  containing secondary or tertiary amines or salts thereof · CPC title

• C08J2205/052

  Closed cells, i.e. more than 50% of the pores are closed · CPC title

• C08G2101/00

  Manufacture of cellular products · CPC title

• C08J9/146

  only fluorine as halogen atoms · CPC title

• C08J9/0061

  characterized by the use of several polymeric components · CPC title