Propylene homopolymer for high-tenacity fibers and nonwovens

Patent metadata

Field	Value
Publication number	US-10023667-B2
Application number	US-201314410982-A
Country	US
Kind code	B2
Filing date	Jun 27, 2013
Priority date	Jun 27, 2012
Publication date	Jul 17, 2018
Grant date	Jul 17, 2018

Abstract

Propylene homopolymers having a melt flow index in the range from 3.0 dg/min to 8.0 dg/min can be particularly suited for high-tenacity fibers and yarns and nonwovens. The propylene homopolymers can be produced by a process that can include polymerizing propylene in presence of a Ziegler-Natta polymerization catalyst, an aluminum alkyl, hydrogen and an optional external donor.

First claim

The invention claimed is:

1. A propylene homopolymer comprising at least two propylene homopolymer fractions of different melt flow index, wherein a ratio of the melt flow index of the fraction with the highest melt flow index and the melt-flow index of the fraction with the lowest melt flow index is in the range from 3 to 400, said propylene homopolymer having
a melt flow index in the range from 3.0 to 8.0 dg/min,
a xylene solubles content in the range from 1.5 wt % to 3.5 wt %,
a tacticity in the range from 97.0% to 99.0% of mmmm pentads (determined on the insoluble heptane fraction of the xylene insolubles fraction), and
a recovery compliance in the range from 4.0·10 −4 Pa −1 to 5.5·10 −4 Pa −1 ,
with melt flow index determined according to ISO 1133, condition L, at 230° C. and 2.16 kg,
wherein the propylene homopolymer is in a solid form.

2. The propylene homopolymer according to claim 1 , wherein the ratio of the melt flow index of the fraction with the highest melt flow index and the melt flow index of the fraction with the lowest melt flow index is in the range from 5 to 200.

3. The propylene homopolymer according to claim 1 , wherein the at least two propylene homopolymer fractions, when taken together, comprise at least 90.0 wt % of the propylene homopolymer.

4. The propylene homopolymer according to claim 1 , wherein the propylene homopolymer fraction with the lowest melt flow index has a melt flow index in the range from 1.0 dg/min to 2.5 dg/min.

5. The propylene homopolymer according to claim 1 , wherein the propylene homopolymer fraction with the lowest melt flow index comprises from 55 wt % to 65 wt % of the propylene homopolymer.

6. The propylene homopolymer according to claim 1 , having a polydispersity index in the range from 4.0 to 5.5.

7. Fibers or yarns comprising the propylene homopolymer of claim 1 .

8. Nonwovens comprising the fibers of claim 7 .

9. A process for the production of propylene homopolymer comprising
(a) polymerizing propylene in presence of a Ziegler-Natta polymerization catalyst, an aluminium alkyl, hydrogen and an optional external donor to produce a propylene homopolymer having a recovery compliance in the range from 4.0·10 −4 Pa −1 to 5.5·10 −4 Pa −1 ,
wherein the propylene homopolymer comprises at least two propylene homopolymer fractions of different melt flow index (measured according to ISO 1133, condition L, 230° C., 2.16 kg), wherein a ratio of the melt flow index of the fraction with the highest melt flow index and the melt flow index of the fraction with the lowest melt flow index is in the range from 3 to 400.

10. The process according to claim 9 , wherein the propylene homopolymer fraction with the lowest melt flow index has a melt flow index (measured according to ISO 1133, condition L, 230° C., 2.16 kg) in the range from 1.0 dg/min to 2.5 dg/min.

11. The process according to claim 9 , wherein the Ziegler-Natta polymerization catalyst has an internal electron donor that comprises at least 80 wt % of a diether.

12. The process according to claim 9 , wherein the external donor is a silane.

13. The process according to claim 9 , further comprising:
(b) melting the propylene homopolymer obtained in step (a) in an extruder,
(c) extruding the molten propylene homopolymer of step (b) from a number of fine capillaries of a spinneret, thus obtaining molten fibers, and
(d) subsequently solidifying the fibers of step (c).

14. The process according to claim 13 , further comprising:
(e) re-heating the solidified fibers of step (d) to a temperature of 130° C. or less,
(f) drawing said re-heated fibers of step (e) with a draw ratio of at least 3, and
(g) annealing said drawn fibers obtained in step (f).

15. The process according to claim 14 , further comprising (h) producing a nonwoven with the drawn fibers of step (g).

16. The process according to claim 9 , wherein the propylene homopolymer has
a melt flow index in the range from 3.0 to 8.0 dg/min,
a xylene solubles content in the range from 1.5 wt % to 3.5 wt %,
a tacticity in the range from 97.0% to 99.0% of mmmm pentads (determined on the insoluble heptane fraction of the xylene insolubles fraction), and
with melt flow index determined according to ISO 1133, condition L, at 230° C. and 2.16 kg.

17. The propylene homopolymer according to claim 1 , wherein the ratio of the melt flow index of the fraction with the highest melt flow index and the melt flow index of the fraction with the lowest melt flow index is in the range 10 to 50.

18. The propylene homopolymer according to claim 1 , wherein the propylene homopolymer fraction with the lowest melt flow index has a melt flow index in the range from 1.5 dg/min to 2.0 dg/min.

19. The propylene homopolymer according to claim 1 , wherein the propylene homopolymer comprises at least 95 wt. % of the at least two homopolymers.

20. The propylene homopolymer according to claim 9 , wherein the produced propylene homopolymer consists essentially of the at least two homopolymers.

21. The propylene homopolymer according to claim 9 , wherein the produced propylene homopolymer comprises at least 95 wt. % of the at least two propylene homopolymer fractions.

Assignees

• Total Res & Technology Feluy

Inventors

• Geeurickx Peter
• Standaert Alain
• Zuliani Jean-Luc

Classifications

• C08L23/12 Primary

  Polypropene · CPC title

• C08L2203/12

  used for fibers · CPC title

• B29C48/0018

  combined with shaping by orienting, stretching or shrinking, e.g. film blowing (B29C48/0017 takes precedence) · CPC title

• B29C48/05

  Filamentary, e.g. strands · CPC title

• B29K2023/12

  PP, i.e. polypropylene · CPC title