Use of peracetic acid/hydrogen peroxide and peroxide-reducing agents for treatment of drilling fluids, frac fluids, flowback water and disposal water

Patent metadata

Field	Value
Publication number	US-10023484-B2
Application number	US-201615005567-A
Country	US
Kind code	B2
Filing date	Jan 25, 2016
Priority date	Mar 30, 2012
Publication date	Jul 17, 2018
Grant date	Jul 17, 2018

Abstract

Methods for the use of peracid compositions having decreased hydrogen peroxide concentration and a UV-blocking agent for various water treatments, including oil- and gas-field operations, and/or other aseptic treatments are disclosed. In numerous aspects, peracetic acid is the preferred peracid and is treated with a peroxide-reducing agent to substantially reduce the hydrogen peroxide content. Methods for using the treated peracid compositions for treatment of drilling fluids, frac fluids, flow back waters and disposal waters are also disclosed for improving water condition, reducing oxidizing damage associated with hydrogen peroxide and/or reducing bacteria infestation.

First claim

What is claimed is:

1. A method of treating oil and gas operation water sources comprising:
treating a percarboxylic acid composition with a peroxide-reducing enzyme to generate an antimicrobial composition; wherein the peroxide-reducing enzyme is a catalase enzyme and wherein said percarboxylic acid composition comprises a percarboxylic acid and hydrogen peroxide;
treating an oil and gas operation water source in need of treatment with a UV-blocking agent;
providing the antimicrobial composition to the water source in need of treatment to form a treated water source, wherein the treated water source comprises (i) from about 0.5 ppm to about 1000 ppm catalase enzyme; (ii) substantially free of hydrogen peroxide; (iii) from about 0.0001 wt-% to about 10.0 wt-% of a C 1 -C 22 carboxylic acid; (iv) from about 0.0001 wt-% to about 10.0 wt-% of a C 1 -C 22 percarboxylic acid; and (v) the UV-block agent; and
directing the treated water source into a subterranean environment or disposing of the treated water source having a minimized environmental impact,
wherein the enzyme reduces hydrogen peroxide concentration in the percarboxylic acid composition or the water source; and
wherein said water source in need of treatment comprises fresh water, pond water, sea water, drilling fluid water, fracking water, produced water, or combination thereof from an oil and gas operation.

2. The method of claim 1 , wherein the UV-blocking agent is a natural or synthetic dye, and wherein the water source in need of treatment comprises a produced water.

3. The method of claim 2 , wherein the UV-blocking agent is a cationic dye, and wherein the water source is at least 1 wt-% produced water.

4. The method of claim 1 , wherein the step of treating the percarboxylic acid composition with the peroxide-reducing agent is not a pretreatment step and occurs within the water source in need of treatment.

5. The method of claim 1 , wherein the treated water reduces corrosion caused by hydrogen peroxide and reduces microbial-induced corrosion, and wherein the antimicrobial composition does not interfere with friction reducers, viscosity enhancers, other functional ingredients found in the water source, or combinations thereof.

6. The method of claim 1 , wherein the percarboxylic acid stability is improved by reducing hydrogen peroxide concentration within the percarboxylic acid composition, and wherein the concentration of the C 1 -C 22 carboxylic acid is from about 0.0001 wt-% to about 5.0 wt-%, and wherein the concentration of the C 1 -C 22 percarboxylic acid is from about 0.0001 wt-% to about 5.0 wt %.

7. The method of claim 1 , wherein the percarboxylic acid is peracetic acid, wherein the carboxylic acid is acetic acid, and wherein the UV-blocking agent is methylene blue.

8. The method of claim 1 , the method further comprises adding an acidulant to the water source in need of treatment before the addition of the antimicrobial composition to the water source.

9. A method of treating oil and gas operation water source comprising:
adding a percarboxylic acid composition, a peroxide-reducing agent and a UV-blocking agent to an oil and gas operation water source to form a treated water source, wherein the peroxide-reducing agent is a catalase enzyme, said treated water source comprises (i) from about 0.5 ppm to about 1000 ppm of the catalase enzyme; (ii) substantially free of hydrogen peroxide; (iii) from about 0.0001 wt-% to about 10.0 wt-% of a C 1 -C 22 carboxylic acid; (iv) from about 0.0001 wt-% to about 10.0 wt-% of a C 1 -C 22 percarboxylic acid; and (v) from about 0.00001 wt-% to about 5 wt-% of said UV-blocking agent, and
wherein the peroxide-reducing agent degrades hydrogen peroxide in the percarboxylic acid composition, the water source, or the treated water source, reduces corrosion caused by hydrogen peroxide, and reduces microbial-induced corrosion; and wherein the water source comprises fresh water, pond water, sea water, drilling fluid water, fracking water, produced water, or combination thereof from an oil and gas operation.

10. The method of claim 9 , wherein the UV-blocking agent is a natural or synthetic dye, the water source is produced water.

11. The method of claim 9 , further comprising contacting the percarboxylic acid composition by the peroxide-reducing agent to generate a pretreated antimicrobial composition.

12. The method of claim 9 , further comprising the step of directing the treated water source into a subterranean environment or disposing of the treated water source having a minimized environmental impact.

13. The method of claim 9 , wherein the percarboxylic acid stability is improved through the reduction of hydrogen peroxide concentration as a result of the addition of the peroxide-reducing agent.

14. The method of claim 9 , wherein the percarboxylic acid is peracetic acid, wherein the carboxylic acid is acetic acid, and wherein the UV-blocking agent is methylene blue.

15. The method of claim 9 , wherein the adding of the percarboxylic acid composition and the peroxide-reducing agent to the water source occurs on an at least every 5 day dosing cycle.

16. The method of claim 9 , the method further comprises adding an acidulant to the water source in need of treatment before the addition of the percarboxylic acid and peroxide-reducing agent to the water source.

17. A method of treating an oil and gas operation water source comprising:
treating a percarboxylic acid composition with a peroxide-reducing agent to a first oil and gas operation water source to generate an antimicrobial composition, wherein said peroxide-reducing agent is a catalase enzyme;
treating a second oil and gas operation water source in need of treatment with a UV-blocking agent;
forming a treated water source by adding the antimicrobial composition to the second water source, wherein the treated water source comprises (i) from about 0.5 ppm to about 1000 ppm of the peroxide-reducing agent; (ii) substantially free of hydrogen peroxide; (iii) from about 0.0001 wt-% to about 10.0 wt-% of a C 1 -C 22 carboxylic acid; (iv) from about 0.0001 wt-% to about 10.0 wt-% of a C 1 -C 22 percarboxylic acid; and (v) from about 0.00001 wt-% to about 5 wt-% of the UV-blocking agent; and
directing the treated water source into a subterranean environment or disposing of the treated water source having a minimized environmental impact,
wherein the peroxide-reducing agent degrades hydrogen peroxide in the percarboxylic acid composition, first water source, or the second water source,
the treated water source reduces corrosion caused by hydrogen peroxide, reduces microbial-induced corrosion, and
the first water source or the second water source comprises fresh water, pond water, sea water, drilling fluid water, fracking water, produced water, or combination thereof from an oil and gas operation.

18. The method of claim 17 , wherein the UV-blocking agent is a cationic dye.

19. The method of claim 17 , wherein the UV-blocking agent is methylene blue, the method further comprises adding an inorganic peroxide-reducing agent together with the enzyme, and wherein the inorganic peroxide-reducing agent is a hypohalite.

Assignees

• Ecolab Usa Inc

Inventors

• Keasler Victor
• De Paula Renato
• Li Junzhong
• Mcsherry David D
• Herdt Brandon
• Staub Richard
• Ryther Robert J

Classifications

• A01N63/00

  Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates (containing compounds of determined constitution A01N27/00 - A01N59/00; unicellular algae A01N65/03) · CPC title

• C02F2303/08

  Corrosion inhibition · CPC title

• C09K8/605

  containing biocides · CPC title

• C02F1/50 Primary

  by addition or application of a germicide or by oligodynamic treatment {(C02F1/4606, C02F1/467, C02F1/76 take precedence)} · CPC title

• C02F1/722

  Oxidation by peroxides · CPC title