Silver powder and method for producing same

Patent metadata

Field	Value
Publication number	US-10022799-B2
Application number	US-201314380828-A
Country	US
Kind code	B2
Filing date	Feb 22, 2013
Priority date	Feb 24, 2012
Publication date	Jul 17, 2018
Grant date	Jul 17, 2018

Abstract

The present invention provides a method for producing a silver powder, the method being capable of producing a silver powder with high productivity and at low cost, the silver powder having an average particle diameter of 0.3 to 2.0 μm and a narrow particle size distribution, and provides a silver powder produced by the production method. According to the present invention, the method for producing a silver powder includes: quantitatively and continuously supplying each of a silver solution containing a silver complex and a reductant solution to a flow path; and quantitatively and continuously reducing a silver complex in a reaction solution obtained by mixing the silver solution with the reductant solution in the flow path, wherein the reaction solution is made to contain a dispersant, and also a silver concentration in the reaction solution is adjusted to be in a range of 5 to 75 g/L.

First claim

The invention claimed is:

1. A method for producing a silver powder, the method comprising:
quantitatively and continuously supplying each of a silver solution containing a silver complex and a reductant solution to a flow path; and
quantitatively and continuously reducing a silver complex in a reaction solution obtained by mixing the silver solution with the reductant solution in the flow path,
wherein the silver solution is obtained by dissolving silver chloride in ammonia water, and
the reaction solution is made to contain a dispersant, and a silver concentration in the reaction solution is adjusted to be in a range of 5 to 75 g/L.

2. The method for producing a silver powder according to claim 1 , wherein a particle size of silver particles formed by reduction is controlled by adjusting a silver concentration in the reaction solution.

3. The method for producing a silver powder according to claim 1 , wherein the reductant is ascorbic acid, and a mixing ratio of the reductant with respect to 1 mol of silver at a time of mixing the reductant solution with the silver solution is 0.25 to 0.50 mol.

4. The method for producing a silver powder according to claim 1 , wherein, as a dispersant, at least one selected from the group consisting of polyvinyl alcohol, polyvinyl pyrrolidone, a denatured silicone oil surface active agent, and a polyether surface active agent is added to the reductant solution.

5. The method for producing a silver powder according to claim 1 , wherein mixing is performed while an angle which a supply direction of the reductant solution forms with a supply direction of the silver solution in the flow path is not less than 0 degrees and not more than 90 degrees in a plane including the supply directions of both of the solutions.

6. The method for producing a silver powder according to claim 5 , wherein piping configured to supply the reductant solution is arranged inside and on the same axis as piping configured to supply the silver solution, and the silver solution and the reductant solution are made to flow in a same direction.

7. The method for producing a silver powder according to claim 5 , wherein a reaction solution obtained by mixing the silver solution with the reductant solution in the flow path is homogenized by using a static mixer.

8. The method for producing a silver powder according to claim 5 , wherein a supply pipe of silver solution and a supply pipe of reductant solution are arranged in an upper part of a pipe inclined with respect to a horizontal plane, whereby the silver solution and the reductant solution are supplied in such a way that a flow of the silver solution and a flow of the reductant solution intersect each other.

9. The method for producing a silver powder according to claim 1 , wherein mixing is performed while an angle which a supply direction of the reductant solution forms with a supply direction of the silver solution in the flow path is more than 90 degrees and not more than 180 degrees in a plane including the supply directions of both of the solutions.

10. The method for producing a silver powder according to claim 9 , wherein piping configured to supply the reductant solution is installed inside and on the same axis as piping configured to supply the silver solution, and the silver solution and the reductant solution are made to flow in opposite directions facing each other.

11. The method for producing a silver powder according to claim 1 , wherein a time elapsed from mixing of the silver solution with the reductant solution in the flow path until a mixed solution flows down through the flow path and reaches an outlet is not less than 15 seconds and not more than 60 seconds.

12. The method for producing a silver powder according to claim 1 , wherein a reaction solution obtained by mixing in the flow path is kept and stirred in a receiving tank arranged at an end of the flow path.

Assignees

• Sumitomo Metal Mining Co

Inventors

• Okabe Yoshihiro
• Ito Kenya
• Okada Shuuji
• Nishimoto Masamu
• Murakami Akihiro
• Ishikawa Shintaro

Classifications

• B22F9/24 Primary

  starting from liquid metal compounds, e.g. solutions · CPC title

• C22C5/06

  Alloys based on silver · CPC title

• H01B1/02

  mainly consisting of metals or alloys · CPC title

• Y10T428/12181

  Composite powder [e.g., coated, etc.] · CPC title

• B22F1/0014

  Operations & Transport · mapped topic