Method of forming a catalyst with an ion-modified binder

Patent metadata

Field	Value
Publication number	US-10022710-B2
Application number	US-201414525456-A
Country	US
Kind code	B2
Filing date	Oct 28, 2014
Priority date	Dec 29, 2008
Publication date	Jul 17, 2018
Grant date	Jul 17, 2018

Abstract

An alkylation catalyst having a zeolite catalyst component and a binder component providing mechanical support for the zeolite catalyst component is disclosed. The binder component is an ion-modified binder that can include metal ions selected from the group consisting of Co, Mn, Ti, Zr, V, Nb, K, Cs, Ga, B, P, Rb, Ag, Na, Cu, Mg, Fe, Mo, Ce, and combinations thereof. The metal ions reduce the number of acid sites on the zeolite catalyst component. The metal ions can range from 0.1 to 50 wt % based on the total weight of the ion-modified binder. Optionally, the ion-modified binder is present in amounts ranging from 1 to 80 wt % based on the total weight of the catalyst.

First claim

What is claimed:

1. A method for preparing a zeolite alkylation catalyst, comprising:
adding metal ions to a binder to form an ion-modified binder;
combining said ion-modified binder with a zeolite to form a zeolite aggregate, wherein the zeolite comprises faujasite, mordenite, chabazite, offretite, clinoptilolite, erionite, or sihealite; and
processing the zeolite aggregate to form a zeolite alkylation catalyst;
wherein the ion-modified binder reduces a number of acid sites on the zeolite alkylation catalyst; and
wherein the metal ions on the ion-modified binder alter structural dimensions of the zeolite alkylation catalyst.

2. The method of claim 1 , wherein the metal ions are selected from the group consisting of Ce, Cu, P, Cs, B, Co, Ga, and combinations thereof.

3. The method of claim 1 , wherein the ion-modified binder comprises cesium silicate, and wherein the ion-modified binder alters the shape selectivity of the zeolite alkylation catalyst.

4. The method of claim 1 , wherein the metal ions are selected from the group consisting of Mn, K, Cs, Ga, Rb, Ag, Na, Cu, Mg, and combinations thereof.

5. The method of claim 1 , wherein the metal ions are added to the binder by incipient wetness.

6. The method of claim 1 , wherein the metal ions are added to the binder by:
adding a metal ion precursor to an aqueous solution;
pouring the aqueous solution over the binder; and
drying and calcining the binder to remove water, wherein the metal ions are deposited on a surface of the binder.

7. The method of claim 5 , wherein combining said ion-modified binder with the zeolite comprises mixing the ion-modified binder with the zeolite, shaping the mixture, and drying and calcining the shaped mixture.

8. The method of claim 1 , wherein the metal ions comprise a cesium promoter that is combined with the binder in the form of cesium silicate.

9. The method of claim 8 , wherein the cesium silicate is Cs 6 Si 10 O 23 .

10. The method of claim 8 , wherein the cesium silicate comprises is in the form of crystals that are prepared upon crystallization of Cs 2 O 4 SiO 2 .

11. The method of claim 8 , wherein the binder is a silica-alumina material, and wherein crystals of the cesium silicate are added to a silica portion of the silica-alumina material.

12. A method for preparing a zeolite alkylation catalyst, comprising:
adding metal ions to a binder to form an ion-modified binder;
combining said ion-modified binder with a zeolite to form a zeolite aggregate, wherein the zeolite comprises zeolite A, zeolite L, zeolite beta, zeolite X, zeolite Y, ZSM-5, MCM-22, or MCM-41; and
processing the zeolite aggregate to form a zeolite alkylation catalyst;
wherein the ion-modified binder reduces a number of acid sites on the zeolite alkylation catalyst; and
wherein the metal ions on the ion-modified binder alter structural dimensions of the zeolite alkylation catalyst.

13. The method of claim 12 , wherein the metal ions are selected from the group consisting of Mn, K, Cs, Ga, Rb, Ag, Na, Cu, Mg, and combinations thereof.

14. The method of claim 12 , wherein the metal ions are added to the binder by incipient wetness.

15. The method of claim 12 , wherein the metal ions comprise a cesium promoter that is combined with the binder in the form of cesium silicate.

Assignees

• Fina Technology

Inventors

• Chinta Sivadinarayana
• Pelati Joseph E

Classifications

• B01J29/06

  Crystalline aluminosilicate zeolites; Isomorphous compounds thereof · CPC title

• B01J29/83

  Aluminophosphates [APO compounds] · CPC title

• B01J37/0009

  Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst · CPC title

• B01J29/7615

  Zeolite Beta · CPC title

• C07C2523/14

  of germanium, tin or lead · CPC title