Process for the production of non-sintered transition metal carbide and nitride nanoparticles

Patent metadata

Field	Value
Publication number	US-10022709-B2
Application number	US-201414453454-A
Country	US
Kind code	B2
Filing date	Aug 6, 2014
Priority date	Aug 6, 2013
Publication date	Jul 17, 2018
Grant date	Jul 17, 2018

Abstract

Transition metal carbide, nitride, phosphide, sulfide, or boride nanoparticles can be made by transforming metal oxide materials coated in a ceramic material in a controlled environment. The coating prevents sintering while allowing the diffusion of reactive gases through the inorganic matrix that can then alter the metal nanoparticle oxidation state, remove oxygen, or intercalate into the lattice to form a carbide, nitride, phosphide, sulfide, or boride.

First claim

What is claimed is:

1. A method of producing a plurality of transition metal nanoparticles comprising:
preparing a water-in-oil reverse microemulsion including metal oxide nanoparticles or metal nanoparticles,
encapsulating the nanoparticles within an inorganic matrix shell to form encapsulated nanoparticles,
calcining the encapsulated nanoparticles in an oxidizing atmosphere or vacuum,
heating the encapsulated nanoparticles in the presence of a reducing agent; and
converting the encapsulated metal oxide nanoparticles to non-sintered nanoparticles including C, N, S, B, or P encapsulated in the inorganic matrix shell, removing the inorganic matrix shell encapsulated on the non-sintered nanoparticles including C, N, S, B or P, and dispersing a plurality of the non-sintered nanoparticles including C, N, S, B or P onto a support.

2. The method of claim 1 , wherein converting the nanoparticles includes carburizing the nanoparticles in a methane atmosphere.

3. The method of claim 1 , wherein the inorganic matrix include silicon oxide, aluminum oxide, germanium oxide, zirconium oxide, cerium oxide, hafnium oxide, gallium oxide or titanium oxide.

4. The method of any of the claims 1 and 2 - 3 , wherein the nanoparticle includes a tungsten carbide nanoparticle, a molybdenum carbide nanoparticle, or heterometallic carbide nanoparticle.

5. The method of claim 4 , wherein the heterometallic carbide nanoparticle includes a molybdenum tungsten carbide.

6. The method of claim 1 , wherein the percentage of the transition metal content of the inorganic matrix shell is 20% or higher.

7. The method of claim 1 , wherein converting the nanoparticles includes nitridizing the nanoparticles.

8. The method of claim 1 , wherein converting the nanoparticles includes phosphidizing the nanoparticles.

9. The method of claim 1 , wherein converting the nanoparticles includes sulfidizing the nanoparticles.

10. The method of claim 1 , wherein converting the nanoparticles includes boridizing the nanoparticles.

11. The method of claim 1 , wherein the support is carbon black, graphene, carbon nanotubes, high-surface area carbide, a metal oxide including silica, alumina, titania, zirconia, ceria, or zeolites.

12. The method of claim 1 , wherein the heating the nanoparticles includes heating the nanoparticles to less than 850° C.

13. The method of claim 4 , wherein the tungsten carbide is in a single phase.

14. The method of claim 3 , wherein the tungsten carbide is in a β phase, an α phase or a semicarbide phase.

Assignees

• Massachusetts Inst Technology

Inventors

• Roman-Leshkov Yuriy
• Hunt Sean

Classifications

• B01J27/22

  Carbides · CPC title

• H01M4/362

  Composites · CPC title

• B01J37/16

  Reducing · CPC title

• B01J37/28

  Phosphorising · CPC title

• B01J27/24 Primary

  Nitrogen compounds · CPC title