Metal air battery and cathode current collector included therein

Patent metadata

Field	Value
Publication number	US-10020552-B2
Application number	US-201615149317-A
Country	US
Kind code	B2
Filing date	May 9, 2016
Priority date	Jul 27, 2015
Publication date	Jul 10, 2018
Grant date	Jul 10, 2018

Abstract

A metal air battery includes: at least one gas diffusion layer including a first surface and a second surface facing the first surface; at least one cathode layer disposed on the first surface and on the second surface of the gas diffusion layer and configured to use oxygen as an active material; an electrolyte membrane disposed on the cathode layer; an metal anode layer disposed on the electrolyte membrane; and a cathode current collector including at least one blade, wherein the gas diffusion layer is electrically conductive, and wherein the at least one blade of the cathode current collector contacts and is at least partially embedded in the gas diffusion layer.

First claim

What is claimed is:

1. A metal air battery comprising:
at least one gas diffusion layer comprising a first surface and a second surface facing the first surface;
at least one cathode layer disposed on the first surface and on the second surface of the gas diffusion layer and configured to use oxygen as an active material;
an electrolyte membrane disposed on the cathode layer;
a metal anode layer disposed on the electrolyte membrane; and
a cathode current collector comprising at least one blade,
wherein the gas diffusion layer is electrically conductive, and wherein the at least one blade of the cathode current collector contacts and is at least partially embedded in the gas diffusion layer.

2. The metal air battery of claim 1 , wherein a width of the gas diffusion layer is greater than a width of the metal anode layer.

3. The metal air battery of claim 2 , wherein the cathode current collector comprises two or more blades spaced apart from each other at an interval of greater than 0 millimeters to less than about 20 millimeters.

4. The metal air battery of claim 1 , wherein the cathode current collector has a network structure comprising a plurality of rod-shaped supports and a plurality of blades which intersect the plurality of rod-shaped supports.

5. The metal air battery of claim 1 , wherein the at least one blade of the cathode current collector is at least partially embedded in the gas diffusion layer in a direction transverse to a longitudinal direction of the gas diffusion layer.

6. The metal air battery of claim 1 , wherein a width of the gas diffusion layer is equal to a width of the metal anode layer.

7. The metal air battery of claim 6 , wherein the cathode current collector is disposed such that the at least one blade is at least partially embedded in a body of the gas diffusion layer.

8. The metal air battery of claim 6 , wherein the metal air battery comprises at least two adjacent gas diffusion layers and at least two blades, and
wherein the at least two blades are disposed side by side on a surface of the support and are spaced apart from each other, and at least one of the two or more blades is embedded in a gap between the at least two adjacent gas diffusion layers.

9. The metal air battery of claim 8 , wherein the at least two blades are spaced apart from each other at an interval of greater 0 millimeters to less than 50 millimeters.

10. The metal air battery of claim 6 , wherein
a width of the plate-shaped support is equal to about 2% or less of a length of the gas diffusion layer,
a length of the blade is equal to about 50% or less of the width of the gas diffusion layer, and
a greatest thickness of the blade is equal to about 75% or less of a thickness of the gas diffusion layer.

11. The metal air battery of claim 1 , wherein the cathode current collector comprises a plate-shaped support and the at least one blade is disposed on a surface of the plate-shaped support, and
wherein the at least one blade is at least partially embedded in the gas diffusion layer in a direction parallel to a longitudinal direction of the gas diffusion layer.

12. The metal air battery of claim 1 , wherein the cathode layer comprises a bend and surrounds the first surface, the second surface, and a first side surface of the gas diffusion layer.

13. The metal air battery of claim 1 , wherein a thickness of the at least one blade decreases from an outer surface of the gas diffusion layer toward an inside of the metal air battery.

14. The metal air battery of claim 13 , wherein a ratio of a smallest thickness to a greatest thickness of the at least one blade is in a range of about 0.1:1 to about 0.5:1.

15. The metal air battery of claim 1 , wherein the at least one blade comprises at least one of stainless steel, copper, stainless steel plated with gold to a thickness of 10 micrometers or less, and copper plated with gold to a thickness of 10 micrometers or less.

16. A cathode current collector for a metal air battery, the cathode current collector comprising a network structure comprising a plurality of rod-shaped supports and a plurality of blades which intersect the plurality of rod-shaped supports.

17. The cathode current collector of claim 16 , wherein the network structure comprises a plurality of holes, and
wherein a ratio of a total volume of the plurality of the holes to a total volume of the cathode current collector is at least about 50%.

18. A method of preparing a metal air battery, comprising:
disposing at least one cathode layer on a first surface and on a second surface of at least one gas diffusion layer;
disposing an electrolyte membrane on the cathode layer;
disposing a metal anode layer on the electrolyte membrane;
providing a cathode current collector comprising at least one blade; and
at least partially embedding the at least one blade in the gas diffusion layer to prepare the metal air battery, wherein the cathode current collector contacts the gas diffusion layer.

Assignees

• Samsung Electronics Co Ltd

Inventors

• Kim Joonhee
• Choi Kyounghwan
• Park Jungock

Classifications

• H01M2004/8689

  Positive electrodes · CPC title

• H01M4/8807

  Gas diffusion layers · CPC title

• H01M12/065 Primary

  with plate-like electrodes or stacks of plate-like electrodes · CPC title

• H01M4/8657

  layered · CPC title

• H01M4/0407

  by coating on an electrolyte layer · CPC title